Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(18)
Published: Jan. 27, 2022
Abstract
The
passivation
effect
of
inorganic
perovskite
quantum
dots
(PQDs)
is
a
promising
method
to
attain
outstanding
performance
in
solar
cells
(PSCs),
which
has
ignited
widespread
interest
recently.
Lanthanides
(Ln)
doped
PQDs
demonstrate
unique
properties,
but
nevertheless,
are
not
explored
PSCs.
In
this
work,
four
kinds
Ln
3+
CsPbBrCl
2
(Ln
=
Yb
,
Ce
Eu
Sm
)
firstly
introduced
into
PSCs,
displays
the
synergistic
composition
engineering
and
defect
engineering.
results
indicate
that
introduction
:
can
only
improve
crystallinity
passivate
intrinsic
surface
defects
MAPbI
3
layer
through
ion
ligand
passivation,
also
form
stronger
LnI
bond
than
PbI,
adjust
work
function
(
W
F
),
optimize
band
alignments.
:Sm
possess
best
exhibit
remarkable
promotions
open‐circuit
voltage
V
oc
from
1.13
1.20
power
conversion
efficiency
18.54%
22.52%.
humid‐resist,
thermal‐resist
abilities,
long‐term
stability
PSCs
energetically
improved
due
enhanced
structure
by
doping
hydrophobic
characteristic.
strategy
applied
provide
an
approach
achieve
high‐performance
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(18)
Published: Jan. 27, 2022
Abstract
The
passivation
effect
of
inorganic
perovskite
quantum
dots
(PQDs)
is
a
promising
method
to
attain
outstanding
performance
in
solar
cells
(PSCs),
which
has
ignited
widespread
interest
recently.
Lanthanides
(Ln)
doped
PQDs
demonstrate
unique
properties,
but
nevertheless,
are
not
explored
PSCs.
In
this
work,
four
kinds
Ln
3+
CsPbBrCl
2
(Ln
=
Yb
,
Ce
Eu
Sm
)
firstly
introduced
into
PSCs,
displays
the
synergistic
composition
engineering
and
defect
engineering.
results
indicate
that
introduction
:
can
only
improve
crystallinity
passivate
intrinsic
surface
defects
MAPbI
3
layer
through
ion
ligand
passivation,
also
form
stronger
LnI
bond
than
PbI,
adjust
work
function
(
W
F
),
optimize
band
alignments.
:Sm
possess
best
exhibit
remarkable
promotions
open‐circuit
voltage
V
oc
from
1.13
1.20
power
conversion
efficiency
18.54%
22.52%.
humid‐resist,
thermal‐resist
abilities,
long‐term
stability
PSCs
energetically
improved
due
enhanced
structure
by
doping
hydrophobic
characteristic.
strategy
applied
provide
an
approach
achieve
high‐performance