Unveiling the potential of emergent nanoscale composite polymer electrolytes for safe and efficient all solid-state lithium-ion batteries DOI Creative Commons
Adhigan Murali,

R. Ramesh,

M. Sakar

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(42), P. 30618 - 30629

Published: Jan. 1, 2024

Solid polymer electrolytes provide excellent safety by replacing liquid electrolytes. Three types-solid, composite and gel-based are widely used, improving battery life-span preventing lithium dendrite growth.

Language: Английский

Design Strategies, Characterization Mechanisms, and Applications of MOFs in Polymer Composite Electrolytes for Solid‐State Lithium Metal Batteries DOI Open Access
Haiping He, Nanping Deng, Xiaoyin Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract Solid composite electrolytes (SCEs) composed of functional fillers and solid polymer (SPEs) can overcome some shortcomings single‐phase combine advantages each component, are considered as high‐performance solid‐state (SSEs) candidates for assembling lithium metal batteries (SSLMBs) with high safety energy density. In recent years, due to designability metal–organic frameworks (MOFs), MOFs/polymer (MPCEs) have become a highly promising novel type SCEs. Based on the above content, this article first describes composition mechanism action MPCEs, followed by discussion typical fabrication methods MPCEs. addition, mechanisms unmodified neat MOFs in improving performance SSEs enhancing interface stability presented detail, focus design strategies their applications including dimensional design, ligand IL@MOFs hybrid design. Finally, thorough analysis is conducted current challenges faced corresponding future development directions proposed. This review presents comprehensive, systematic, easily understandable application different designs providing new perspective researchers study SSEs.

Language: Английский

Citations

1

Stabilizing Free Radical Crosslinked Dielectric Polymers with Metal-Organic Frameworks: An Efficient Approach to Mitigating Dielectric Deterioration DOI
Zeru Wang,

Wang Xie,

H.S. Ren

et al.

Composites Science and Technology, Journal Year: 2025, Volume and Issue: unknown, P. 111109 - 111109

Published: Feb. 1, 2025

Language: Английский

Citations

1

Design and application of novel multifunctional flame retardants for high-safety solid-state electrolytes in lithium metal batteries DOI
Xiaotao Zhu, Zeru Wang, Zhuang Xu

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162812 - 162812

Published: April 1, 2025

Language: Английский

Citations

1

Design of advanced composite battery materials based on nanoporous functional materials with different dimensionality DOI
Saz Muhammad, Zeru Wang,

Jieyan Li

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: 130, P. 110161 - 110161

Published: Aug. 24, 2024

Language: Английский

Citations

6

Defect-Tailoring Metal–Organic Frameworks for Highly Fast-Charging Quasi-Solid-State Electrolytes Lithium Metal Batteries DOI
Zeru Wang, Zhuang Xu, Yongbiao Mu

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 15, 2025

Metal-organic frameworks (MOFs) show revolutionary potential in quasi-solid-state electrolytes (QSSEs) designed for high-energy-density batteries, owing to their tunable nanoporous structures and open metal sites (OMSs). However, application is hindered by insufficient Li+ dissociation low ionic conductivity, attributed limited active sites. This study employed defect engineering modulate hafnium-based MOFs, increasing OMS density while optimizing the pore microenvironment. The engineered defects improve Lewis acid strength of OMSs, driving lithium salt establishing strong chemisorption TFSI- anions. By synergistically density, acidity, structural stability, defect-engineered Hf-MOF-QSSE achieved an conductivity 1.0 mS cm-1 at 30 °C delivered a critical current 2 mA cm-2, surpassing previously reported MOF-QSSEs, underscoring pivotal role electrolyte optimization. Furthermore, Li||LiFePO4 cells exhibited excellent cycling stability ultrahigh rate capability, retaining 93% capacity after 1500 cycles 10C, Li||NCM811 maintained specific 85 mAh g-1 600 5C.

Language: Английский

Citations

0

Zirconium-based metal–organic frameworks for electrochemical energy storage DOI

Chung-Huan Wu,

Kuan-Chu Wu,

Cheng‐Hui Shen

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 538, P. 216704 - 216704

Published: April 19, 2025

Language: Английский

Citations

0

Flexible lithium-ion batteries: innovations in polymer electrolyte synthesis and structural engineering DOI

Hafiz Talha Hasnain Rana,

Lukuan Cheng,

Jingyi Yang

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101902 - 101902

Published: April 1, 2025

Language: Английский

Citations

0

Induction Effect of Fluorine-Grafted Polymer-Based Electrolytes for High-Performance Lithium Metal Batteries DOI Creative Commons
Haiman Hu, Jiajia Li, Fei Lin

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: May 13, 2025

Abstract Quasi-solid-state composite electrolytes (QSCEs) show promise for high-performance solid-state batteries, while they still struggle with interfacial stability and cycling performance. Herein, a F-grafted QSCE (F-QSCE) was developed via copolymerizing the F monomers ionic liquid monomers. The F-QSCE demonstrates better overall performance, such as high conductivity of 1.21 mS cm –1 at 25 °C, wide electrochemical windows 5.20 V, stable Li//Li symmetric cells over 4000 h. This is attributed to significant electronegativity difference between C in fluorinated chain (‒CF 2 ‒CF‒CF 3 ), which causes electron cloud shift toward atom, surrounding it negative charge producing inductive effect. Furthermore, interactions Li + F, TFSI ‒ , are enhanced, reducing ion pair aggregation (Li ‒TFSI ‒Li ) promoting transport. Besides, ‒CF decomposes form LiF preferentially – resulting F-QSCE. work provides pathway enable development metal batteries.

Language: Английский

Citations

0

Engineering 3D Lattice Oxygen Metal–Organic Frameworks for Fast‐Charging Quasi‐Solid‐State Lithium Metal Batteries DOI
Zhuang Xu, Zeru Wang,

Jieyan Li

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: May 28, 2025

Abstract Metal–organic frameworks (MOFs) show great promise in composite solid polymer electrolytes by simultaneously immobilizing anions and facilitating cation transport, yet the synergy between these mechanisms remains unclear. To elucidate this interplay, a series of isoreticular indium‐based MOFs (InOF‐1, MIL‐60, MIL‐68(In)) are designed, all featuring identical In‐O6 coordination centers while exhibiting systematically varies pore architectures. Among them, MIL‐60 stands out achieving an optimal balance physical size exclusion chemical mediation ion transport. It's precisely engineered 6.5 Å pores effectively block bulky TFSI − allowing diffusion lithium (Li + )–solvent complexes. Concurrently, its exceptionally high lattice oxygen density (19.97 nm −3 , confirmed functional theory calculations) forms 3D fast Li conduction network, enabling barrier‐free hopping. This dual mechanism results superior electrochemical performance, including ultrahigh room‐temperature conductivity 1.11 × 10 S cm −1 at 30 °C, unprecedented transference number 0.54, outstanding cycling stability with 95.2% capacity retention after 1800 cycles C LiFePO 4 ||Li cells. study proposes new design strategy aligning transport sites to optimize conduction. exemplifies promising model for single‐ion conductors guides next‐generation solid‐state batteries.

Language: Английский

Citations

0

Unveiling the potential of emergent nanoscale composite polymer electrolytes for safe and efficient all solid-state lithium-ion batteries DOI Creative Commons
Adhigan Murali,

R. Ramesh,

M. Sakar

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(42), P. 30618 - 30629

Published: Jan. 1, 2024

Solid polymer electrolytes provide excellent safety by replacing liquid electrolytes. Three types-solid, composite and gel-based are widely used, improving battery life-span preventing lithium dendrite growth.

Language: Английский

Citations

2