Design Strategies, Characterization Mechanisms, and Applications of MOFs in Polymer Composite Electrolytes for Solid‐State Lithium Metal Batteries
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 16, 2025
Abstract
Solid
composite
electrolytes
(SCEs)
composed
of
functional
fillers
and
solid
polymer
(SPEs)
can
overcome
some
shortcomings
single‐phase
combine
advantages
each
component,
are
considered
as
high‐performance
solid‐state
(SSEs)
candidates
for
assembling
lithium
metal
batteries
(SSLMBs)
with
high
safety
energy
density.
In
recent
years,
due
to
designability
metal–organic
frameworks
(MOFs),
MOFs/polymer
(MPCEs)
have
become
a
highly
promising
novel
type
SCEs.
Based
on
the
above
content,
this
article
first
describes
composition
mechanism
action
MPCEs,
followed
by
discussion
typical
fabrication
methods
MPCEs.
addition,
mechanisms
unmodified
neat
MOFs
in
improving
performance
SSEs
enhancing
interface
stability
presented
detail,
focus
design
strategies
their
applications
including
dimensional
design,
ligand
IL@MOFs
hybrid
design.
Finally,
thorough
analysis
is
conducted
current
challenges
faced
corresponding
future
development
directions
proposed.
This
review
presents
comprehensive,
systematic,
easily
understandable
application
different
designs
providing
new
perspective
researchers
study
SSEs.
Language: Английский
Stabilizing Free Radical Crosslinked Dielectric Polymers with Metal-Organic Frameworks: An Efficient Approach to Mitigating Dielectric Deterioration
Zeru Wang,
No information about this author
Wang Xie,
No information about this author
H.S. Ren
No information about this author
et al.
Composites Science and Technology,
Journal Year:
2025,
Volume and Issue:
unknown, P. 111109 - 111109
Published: Feb. 1, 2025
Language: Английский
Design and application of novel multifunctional flame retardants for high-safety solid-state electrolytes in lithium metal batteries
Chemical Engineering Journal,
Journal Year:
2025,
Volume and Issue:
unknown, P. 162812 - 162812
Published: April 1, 2025
Language: Английский
Design of advanced composite battery materials based on nanoporous functional materials with different dimensionality
Saz Muhammad,
No information about this author
Zeru Wang,
No information about this author
Jieyan Li
No information about this author
et al.
Nano Energy,
Journal Year:
2024,
Volume and Issue:
130, P. 110161 - 110161
Published: Aug. 24, 2024
Language: Английский
Defect-Tailoring Metal–Organic Frameworks for Highly Fast-Charging Quasi-Solid-State Electrolytes Lithium Metal Batteries
ACS Applied Materials & Interfaces,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 15, 2025
Metal-organic
frameworks
(MOFs)
show
revolutionary
potential
in
quasi-solid-state
electrolytes
(QSSEs)
designed
for
high-energy-density
batteries,
owing
to
their
tunable
nanoporous
structures
and
open
metal
sites
(OMSs).
However,
application
is
hindered
by
insufficient
Li+
dissociation
low
ionic
conductivity,
attributed
limited
active
sites.
This
study
employed
defect
engineering
modulate
hafnium-based
MOFs,
increasing
OMS
density
while
optimizing
the
pore
microenvironment.
The
engineered
defects
improve
Lewis
acid
strength
of
OMSs,
driving
lithium
salt
establishing
strong
chemisorption
TFSI-
anions.
By
synergistically
density,
acidity,
structural
stability,
defect-engineered
Hf-MOF-QSSE
achieved
an
conductivity
1.0
mS
cm-1
at
30
°C
delivered
a
critical
current
2
mA
cm-2,
surpassing
previously
reported
MOF-QSSEs,
underscoring
pivotal
role
electrolyte
optimization.
Furthermore,
Li||LiFePO4
cells
exhibited
excellent
cycling
stability
ultrahigh
rate
capability,
retaining
93%
capacity
after
1500
cycles
10C,
Li||NCM811
maintained
specific
85
mAh
g-1
600
5C.
Language: Английский
Zirconium-based metal–organic frameworks for electrochemical energy storage
Chung-Huan Wu,
No information about this author
Kuan-Chu Wu,
No information about this author
Cheng‐Hui Shen
No information about this author
et al.
Coordination Chemistry Reviews,
Journal Year:
2025,
Volume and Issue:
538, P. 216704 - 216704
Published: April 19, 2025
Language: Английский
Flexible lithium-ion batteries: innovations in polymer electrolyte synthesis and structural engineering
Hafiz Talha Hasnain Rana,
No information about this author
Lukuan Cheng,
No information about this author
Jingyi Yang
No information about this author
et al.
Materials Today Energy,
Journal Year:
2025,
Volume and Issue:
unknown, P. 101902 - 101902
Published: April 1, 2025
Language: Английский
Induction Effect of Fluorine-Grafted Polymer-Based Electrolytes for High-Performance Lithium Metal Batteries
Haiman Hu,
No information about this author
Jiajia Li,
No information about this author
Fei Lin
No information about this author
et al.
Nano-Micro Letters,
Journal Year:
2025,
Volume and Issue:
17(1)
Published: May 13, 2025
Abstract
Quasi-solid-state
composite
electrolytes
(QSCEs)
show
promise
for
high-performance
solid-state
batteries,
while
they
still
struggle
with
interfacial
stability
and
cycling
performance.
Herein,
a
F-grafted
QSCE
(F-QSCE)
was
developed
via
copolymerizing
the
F
monomers
ionic
liquid
monomers.
The
F-QSCE
demonstrates
better
overall
performance,
such
as
high
conductivity
of
1.21
mS
cm
–1
at
25
°C,
wide
electrochemical
windows
5.20
V,
stable
Li//Li
symmetric
cells
over
4000
h.
This
is
attributed
to
significant
electronegativity
difference
between
C
in
fluorinated
chain
(‒CF
2
‒CF‒CF
3
),
which
causes
electron
cloud
shift
toward
atom,
surrounding
it
negative
charge
producing
inductive
effect.
Furthermore,
interactions
Li
+
F,
TFSI
‒
,
are
enhanced,
reducing
ion
pair
aggregation
(Li
‒TFSI
‒Li
)
promoting
transport.
Besides,
‒CF
decomposes
form
LiF
preferentially
–
resulting
F-QSCE.
work
provides
pathway
enable
development
metal
batteries.
Language: Английский
Engineering 3D Lattice Oxygen Metal–Organic Frameworks for Fast‐Charging Quasi‐Solid‐State Lithium Metal Batteries
Zhuang Xu,
No information about this author
Zeru Wang,
No information about this author
Jieyan Li
No information about this author
et al.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 28, 2025
Abstract
Metal–organic
frameworks
(MOFs)
show
great
promise
in
composite
solid
polymer
electrolytes
by
simultaneously
immobilizing
anions
and
facilitating
cation
transport,
yet
the
synergy
between
these
mechanisms
remains
unclear.
To
elucidate
this
interplay,
a
series
of
isoreticular
indium‐based
MOFs
(InOF‐1,
MIL‐60,
MIL‐68(In))
are
designed,
all
featuring
identical
In‐O6
coordination
centers
while
exhibiting
systematically
varies
pore
architectures.
Among
them,
MIL‐60
stands
out
achieving
an
optimal
balance
physical
size
exclusion
chemical
mediation
ion
transport.
It's
precisely
engineered
6.5
Å
pores
effectively
block
bulky
TFSI
−
allowing
diffusion
lithium
(Li
+
)–solvent
complexes.
Concurrently,
its
exceptionally
high
lattice
oxygen
density
(19.97
nm
−3
,
confirmed
functional
theory
calculations)
forms
3D
fast
Li
conduction
network,
enabling
barrier‐free
hopping.
This
dual
mechanism
results
superior
electrochemical
performance,
including
ultrahigh
room‐temperature
conductivity
1.11
×
10
S
cm
−1
at
30
°C,
unprecedented
transference
number
0.54,
outstanding
cycling
stability
with
95.2%
capacity
retention
after
1800
cycles
C
LiFePO
4
||Li
cells.
study
proposes
new
design
strategy
aligning
transport
sites
to
optimize
conduction.
exemplifies
promising
model
for
single‐ion
conductors
guides
next‐generation
solid‐state
batteries.
Language: Английский
Unveiling the potential of emergent nanoscale composite polymer electrolytes for safe and efficient all solid-state lithium-ion batteries
Adhigan Murali,
No information about this author
R. Ramesh,
No information about this author
M. Sakar
No information about this author
et al.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(42), P. 30618 - 30629
Published: Jan. 1, 2024
Solid
polymer
electrolytes
provide
excellent
safety
by
replacing
liquid
electrolytes.
Three
types-solid,
composite
and
gel-based
are
widely
used,
improving
battery
life-span
preventing
lithium
dendrite
growth.
Language: Английский