Evolutionary Abilities of Minimalistic Physicochemical Models of Life Processes DOI Creative Commons
Robert Pascal

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(46)

Published: July 29, 2024

The ability of living organisms to persist, grow, evolve and invade environments seemingly challenges physical laws. Emerging Autonomous Systems representing autocatalytic cycles constituted energized components in a state Dynamic Kinetic Stability feature some these properties. These simple theoretical models can be transferred but need an initiation emerge collapse. Moreover, they undergo kinetic selection way consistent with Darwinian behaviour, though lack the change. mere existence systems their open-ended growth potential are proposed constitute transmissible factor non-coded kind. onset epigenetic factors may therefore have preceded that genetic polymers. Here is addressed question how arise from diversity exhibited by abiotic organic matter, sometimes associated intractable mixtures, which actually useful providing initiators. description evolution merged without critical discontinuity within origin scenario. Accordingly, such theory would rests solely on physicochemical laws beginning emerging autonomous compete space dimension, further develop along other available dimensions including variability and, possibly, cognition.

Language: Английский

Organic Reactivity Matters for the Emergence of Life: Kinetic Barriers and Molecular Diversity Are Suggested as Crucial Factors by Emerging Autonomous System Models DOI Creative Commons
Robert Pascal

ChemSystemsChem, Journal Year: 2025, Volume and Issue: unknown

Published: March 13, 2025

Abstract The idea that organic chemistry can gradually self‐organize towards the emergence of life has been challenged by views considering most important driver should be existence a crucial thermodynamic disequilibrium. In this work, past are critically addressed and mechanism through which disequilibrium promote development organized systems is suggested. This analysis based on propensity carbon to form covalent bonds with other elements, usually corresponds deep energy wells generating high kinetic barriers hindering reactions. Potential associated considered as storing prepaid entropy loss within potential surface therefore constitute giving room for subsequent self‐organization processes. notion Kinetically Stable Thermodynamically Activated (KSTA) compounds gives rise possibility alternative pathways non‐linear autocatalytic As working in far‐from‐equilibrium context, like molecular machines, parameters determining how they proceed change, suggests interactions between fields machines could mutually beneficial.

Language: Английский

Citations

0
Evolutionary Abilities of Minimalistic Physicochemical Models of Life Processes DOI Creative Commons
Robert Pascal

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(46)

Published: July 29, 2024

The ability of living organisms to persist, grow, evolve and invade environments seemingly challenges physical laws. Emerging Autonomous Systems representing autocatalytic cycles constituted energized components in a state Dynamic Kinetic Stability feature some these properties. These simple theoretical models can be transferred but need an initiation emerge collapse. Moreover, they undergo kinetic selection way consistent with Darwinian behaviour, though lack the change. mere existence systems their open-ended growth potential are proposed constitute transmissible factor non-coded kind. onset epigenetic factors may therefore have preceded that genetic polymers. Here is addressed question how arise from diversity exhibited by abiotic organic matter, sometimes associated intractable mixtures, which actually useful providing initiators. description evolution merged without critical discontinuity within origin scenario. Accordingly, such theory would rests solely on physicochemical laws beginning emerging autonomous compete space dimension, further develop along other available dimensions including variability and, possibly, cognition.

Language: Английский

Citations

1