Batch synthesis of 2,4,6‐trinitro‐3‐bromoanisole and its thermolysis and combustion performance DOI
Xiaolan Song, Yi Wang, Kanghui Jia

et al.

Propellants Explosives Pyrotechnics, Journal Year: 2024, Volume and Issue: 49(7)

Published: May 30, 2024

Abstract A new carrier explosive TNBA was batch synthesized by a chemical method. The prepared samples were characterized using SEM, EDS, XRD, IR, XPS, nuclear magnetic resonance, and elemental analysis techniques. enthalpy of formation measured specialized calorimeter that is specially used in testing explosives powders. thermal decomposition performance tested DSC technology. Meanwhile, the combustion also tested. results characterizations showed sample indeed TNBA. determined as Δ H f,TNBA =+48.5 kJ/mol. At heating rate 20 °C/min, peak at T P =285.3 °C, activation energy E K =91 kJ/mol, which higher than p values TNT. This indicates relatively easy to decompose explosive, but not fast. critical temperature for explosion reached b =247 value TNT, slightly lower DNAN, significantly DNTF, TNAZ, MTNP. test has highest pressure pressurization rate; temperature; however, due high oxygen balance, heat excess pure highest.

Language: Английский

Investigation of dislocation and twinning behavior in HMX under high-velocity impact employing molecular dynamics simulations DOI

Can-shu Yang,

Shuhai Zhang

Journal of Molecular Modeling, Journal Year: 2024, Volume and Issue: 30(2)

Published: Jan. 25, 2024

Language: Английский

Citations

4
Molecular dynamics simulations of irradiation on microstructural and mechanical properties of 1,3,5-trinitro-1,3,5-triazacyclohexane DOI

Xiyao Yun,

Tao Wang, Weiyi Li

et al.

Computational and Theoretical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 115219 - 115219

Published: March 1, 2025

Language: Английский

Citations

0
A high density and low sensitivity carrier explosive promising to replace TNT: 3-Bromo-5-fluoro-2,4,6-trinitroanisole DOI Creative Commons
Yi Wang, Xiaolan Song, Zhihong Yu

et al.

Energetic Materials Frontiers, Journal Year: 2024, Volume and Issue: 5(2), P. 131 - 140

Published: June 1, 2024

To address the issues of high saturated vapor pressure, toxicity, and viscosity TNT, this article used a chemical method to synthesize new carrier explosive BFTNAN. The prepared samples were characterized using scanning electron microscope(SEM), energy spectrum(EDS), x-ray diffraction(XRD), infrared spectrum(IR), photoelectron spectroscopy(XPS), nuclear magnetic resonance, elemental analysis techniques. enthalpy formation BFTNAN was measured specialized calorimeter that is specially in testing explosives powders. thermal decomposition performance tested by DSC technology. Meanwhile, mechanical sensitivity, detonation based melt-cast also tested. results characterizations showed sample indeed determined as ΔHf,BFTNAN = −72.6 kJ·mol−1. At heating rate 20 °C·min−1, peak at TP 250.6 °C, activation EK 80 kJ·mol−1, which closed Tp values TNT. This indicates relatively easy decompose explosive, but not fast. critical temperature for explosion reached Tb 216 value impact friction sensitivity lower than those DNAN. velocity heat distinctly higher TNT explosive. Especially, advantages storage, work capacity, brisance, ability acceleration metals.

Language: Английский

Citations

2
Batch synthesis of 2,4,6‐trinitro‐3‐bromoanisole and its thermolysis and combustion performance DOI
Xiaolan Song, Yi Wang, Kanghui Jia

et al.

Propellants Explosives Pyrotechnics, Journal Year: 2024, Volume and Issue: 49(7)

Published: May 30, 2024

Abstract A new carrier explosive TNBA was batch synthesized by a chemical method. The prepared samples were characterized using SEM, EDS, XRD, IR, XPS, nuclear magnetic resonance, and elemental analysis techniques. enthalpy of formation measured specialized calorimeter that is specially used in testing explosives powders. thermal decomposition performance tested DSC technology. Meanwhile, the combustion also tested. results characterizations showed sample indeed TNBA. determined as Δ H f,TNBA =+48.5 kJ/mol. At heating rate 20 °C/min, peak at T P =285.3 °C, activation energy E K =91 kJ/mol, which higher than p values TNT. This indicates relatively easy to decompose explosive, but not fast. critical temperature for explosion reached b =247 value TNT, slightly lower DNAN, significantly DNTF, TNAZ, MTNP. test has highest pressure pressurization rate; temperature; however, due high oxygen balance, heat excess pure highest.

Language: Английский

Citations

1