Monte Carlo Modeling of Particle Agglomeration During Polymer Pyrolysis in Bubbling Fluidized Bed DOI
Kaicheng Chen, Zhongyi Li, Serap Akbas

et al.

Published: Jan. 1, 2023

During the bubbling fluidized bed polymer pyrolysis process, agglomeration of inert materials frequently leads to defluidization. To simulate this phenomenon, a novel time-driven Monte Carlo model is presented, which comprises two main stages: layering period and period. The simulation results are then compared with experimental data from literature. From qualitative analysis perspective, effectively replicate trends in defluidization times under various operating conditions. In terms quantitative analysis, predicted exhibit good consistency measured values (R2=0.804). Furthermore, information extracted simulation, hard obtain experimentally, applied for further discussion. It allows explore composition at moment different Additionally, comparison particle size distributions same operational time conditions performed. general, developed provides robust foundation extending its application other processes as well co-pyrolysis processes.

Language: Английский

Bioplastic films from starch of Colocasia esculenta and its waste: A smart template for sensing applications DOI
Savita Chaudhary,

Manmeet Kour,

Rajeev Kumar

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 281, P. 136218 - 136218

Published: Oct. 2, 2024

Language: Английский

Citations

3

Photothermal Upcycling of Waste Polyvinyl Chloride Plastics DOI
Hao Han,

Penglei Yan,

Qingye Li

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Upgrading the most difficult-to-recycle waste polyvinyl chloride remains a significant challenge due to potential formation of highly toxic substances, such as polychlorinated biphenyls. Here, we introduce paradigm shift with mild photothermal dechlorination–carbonization process that converts plastics into valuable carbon materials. Through detailed techno-economic assessment (TEA) modeling, based on recycling 96,000 tons plastics, demonstrate utilizing clean solar energy for conversion can save approximately 2.34 × 1012 kJ electricity and reduce footprint by 261,912.2 compared traditional thermal-driven methods, offering clear environmental benefits. Notably, this method more than 10 types postconsumer mixed yielding materials exhibit excellent performance components in sodium-ion storage batteries. Photothermal catalytic thus emerges green sustainable technology promising applications.

Language: Английский

Citations

3

Monte Carlo modeling of particle agglomeration during polymer pyrolysis in bubbling fluidized bed DOI Creative Commons
Kaicheng Chen, Zhongyi Li, Serap Akbas

et al.

Fuel, Journal Year: 2024, Volume and Issue: 367, P. 131487 - 131487

Published: March 19, 2024

During the bubbling fluidized bed polymer pyrolysis process, agglomeration of inert materials frequently leads to defluidization. To simulate this phenomenon, a novel time-driven Monte Carlo model is presented, which comprises two main stages: layering period and period. The simulation results are then compared with experimental data from literature. From qualitative analysis perspective, effectively replicate trends in defluidization times under various operating conditions. In terms quantitative analysis, predicted exhibit good consistency measured values (R2=0.804). Furthermore, information extracted simulation, hard obtain experimentally, applied for further discussion. It allows explore composition at moment different Additionally, comparison particle size distributions same operational time conditions performed. general, developed provides robust foundation extending its application other processes as well co-pyrolysis processes.

Language: Английский

Citations

2

Waste plastic management: Recycling and the environmental health nexus DOI Creative Commons
Sodiq Adeyeye Nafiu,

Musa O. Azeez,

Khaled M. AlAqad

et al.

Cleaner Materials, Journal Year: 2024, Volume and Issue: unknown, P. 100291 - 100291

Published: Dec. 1, 2024

Language: Английский

Citations

2

Reducing Plastic Waste and Generating Bioelectricity Simultaneously through Fuel Cells Using the Fungus Pleurotus ostreatus DOI Open Access
Segundo Rojas-Flores, Magaly De La Cruz-Noriega, Luis Cabanillas-Chirinos

et al.

Sustainability, Journal Year: 2024, Volume and Issue: 16(18), P. 7909 - 7909

Published: Sept. 10, 2024

Plastic waste, a persistent and escalating issue, the high costs of installing electric power, particularly in remote areas, have become pressing concerns for governments. This research proposes novel method generating power from sugarcane bagasse waste reducing plastic waste. The key to this is use fungus Pleurotus ostreatus microbial fuel cells. Microbial cells (MFCs) demonstrated their effectiveness by peaks current (4.325 ± 0.261 mA) voltage (0.427 0.031 V) on day twenty-six, with pH 5.539 0.278. peak electrical conductivity substrate was 130.574 4.981 mS/cm. MFCs were able reduce chemical oxygen demand 83%, showing maximum density 86.316 4.724 mW/cm2 an internal resistance 37.384 62.522 Ω. infrared spectra samples showed decrease 2850–2920, 1470, 720 cm−1, which are more characteristic plastic, demonstrating action samples. Also, micrographs taken SEM reduction thickness film 54.06 µm formation microstructures surface, such as pores raised layers sample used.

Language: Английский

Citations

1

2Supercritical CO2-promoted Degradation of Polystyrene to Aromatic Oils with NiO@C Catalyst DOI
Yanbing Liu, Jinwen Shi,

Zitong Zhuang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114164 - 114164

Published: Sept. 1, 2024

Language: Английский

Citations

1

Supercritical water co-gasification of waste R134a and plastics to produce valuable chemicals and fuels: ReaxFF reactive molecular dynamic simulation DOI
Mengna Bai, Erguang Huo, Shukun Wang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(6), P. 114407 - 114407

Published: Oct. 11, 2024

Language: Английский

Citations

1

Chemical recycling: comprehensive overview of methods and technologies DOI Creative Commons
Ivanna Harasymchuk, Vladimír Kočí, Monika Vitvarová

et al.

International Journal of Sustainable Engineering, Journal Year: 2024, Volume and Issue: 17(1), P. 124 - 148

Published: Oct. 28, 2024

Plastic pollution has emerged as a global environmental crisis, prompting the search for innovative solutions to manage and repurpose plastic waste sustainably. Chemical recycling garnered attention promising strategy address this challenge by converting discarded plastics into valuable feedstocks products. Drawing upon statistical data thorough review of literature, paper examines diverse methodologies technologies employed in chemical recycling, highlighting key advancements their potential economic impacts. The aim article is provide comprehensive overview various methods plastics. In article, reader offered detailed processing methods, including hydrolysis, glycolysis, enzymatic degradation, acid supercritical fluid depolymerisation, catalytic pyrolysis, fast microwave fluidised bed plasma gasification, steam oxidative hydrothermal liquefaction, biological electrochemical processing. literature cited allows gain an in-depth understanding processes at Technology Readiness Levels (TRL) 4 TRL 9, depending on chosen technology.

Language: Английский

Citations

1

Recent advances in chemical recycling of polyoxymethylene waste DOI

Doeun Choi,

Jechan Lee

Energy & Environment, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 10, 2024

The demand for engineering plastics, such as polyoxymethylene (POM), used in the electronics and automotive industries is increasing rapidly. It becoming increasingly important to reduce adverse effects of waste plastics on environment ecosystem achieve goals circular economy. Pyrolysis, gasification, hydrothermal conversion, solvolysis, electrochemical depolymerization have been widely studied chemical methods manage plastic waste. Chemical recycling a representative effective approach recover monomers or syngas from This paper reviews properties POM waste, various reaction mechanisms options with major studies. In addition, economic feasibility discussed. Finally, opportunities future challenges regarding are suggested.

Language: Английский

Citations

0

Chemical upcycling of poly(bisphenol a carbonate) via sequential diamino-/methanolysis: A phosgeneless one-pot route to dimethyl dicarbamate esters DOI
Eugenio Quaranta

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 484, P. 136700 - 136700

Published: Nov. 28, 2024

Language: Английский

Citations

0