Research Square (Research Square),
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 30, 2024
Abstract
The
conversion
of
discarded
polyethylene
terephthalate
(PET)
into
bioplastics
polyglycolic
acid
(PGA)
represents
a
pivotal
step
in
promoting
the
reuse
PET
and
bolstering
adoption
PGA.
However,
this
promising
pathway
is
currently
hindered
by
(i)
low
rate
PET-derived
ethylene
glycol
(EG)
glycolate
(ii)
high
cost
associated
with
purifying
glycolic
(GA).
Herein,
we
designed
novel
Pd-CoCr2O4/NF
catalyst
for
continuous
electrosynthesis
glycolate,
achieving
75%
EG
at
current
density
~280
mA
cm–2.
Furthermore,
devised
cost-effective
purification
process
that
circumvents
unnecessary
acidification
steps.
A
scale-up
experiment
involving
20
kg
waste
was
conducted
resulted
an
87%
PGA
yield.
Techno-economic
analysis
confirmed
competitiveness
produced
through
environmental-friendly
method.
This
study
shows
sustainable
route
to
mitigate
environmental
impact
plastics
reduce
production
costs
bioplastics.
Research Square (Research Square),
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 30, 2024
Abstract
The
conversion
of
discarded
polyethylene
terephthalate
(PET)
into
bioplastics
polyglycolic
acid
(PGA)
represents
a
pivotal
step
in
promoting
the
reuse
PET
and
bolstering
adoption
PGA.
However,
this
promising
pathway
is
currently
hindered
by
(i)
low
rate
PET-derived
ethylene
glycol
(EG)
glycolate
(ii)
high
cost
associated
with
purifying
glycolic
(GA).
Herein,
we
designed
novel
Pd-CoCr2O4/NF
catalyst
for
continuous
electrosynthesis
glycolate,
achieving
75%
EG
at
current
density
~280
mA
cm–2.
Furthermore,
devised
cost-effective
purification
process
that
circumvents
unnecessary
acidification
steps.
A
scale-up
experiment
involving
20
kg
waste
was
conducted
resulted
an
87%
PGA
yield.
Techno-economic
analysis
confirmed
competitiveness
produced
through
environmental-friendly
method.
This
study
shows
sustainable
route
to
mitigate
environmental
impact
plastics
reduce
production
costs
bioplastics.