Visible-light photocatalysed Synthesis of Bioactive Benzo[b]thiophenes via Intramolecular C−S Bond Formation DOI Creative Commons

Mangla Mishra,

Vishal Srivast,

Shraddha Tivari

et al.

Research Square (Research Square), Journal Year: 2023, Volume and Issue: unknown

Published: May 22, 2023

Abstract Visible light driven synthesis of substituted benzo[ b ]thiophenes from phenylethenethiol under an air atmosphere at room temperature is reported, using eosin Y as organophotoredox catalyst by intramolecular C−S bond formation. This process accepts a wide range functional groups tolerance and generates highly environmentally benign conditions via transition-metal-free organic photoredox catalysis.

Language: Английский

Recent advances of decatungstate photocatalyst in HAT process DOI
Praveen P. Singh, Surabhi Sinha, Prashant Gahtori

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(13), P. 2523 - 2538

Published: Jan. 1, 2024

The decatungstate anion (W

Language: Английский

Citations

28

Novel applications of photobiocatalysts in chemical transformations DOI Creative Commons
Praveen P. Singh, Surabhi Sinha, Pankaj Nainwal

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(4), P. 2590 - 2601

Published: Jan. 1, 2024

Photocatalysis has proven to be an effective approach for the production of reactive intermediates under moderate reaction conditions.

Language: Английский

Citations

13

Recent advancement in photosensitizers for photodynamic therapy DOI
Praveen P. Singh, Surabhi Sinha, Prashant Gahtori

et al.

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 229, P. 112262 - 112262

Published: June 6, 2024

Language: Английский

Citations

12

Visible light‐mediated photocatalyzed synthesis of oxazole via intermolecular CN and CO bond formation DOI

Mohd. Zaheeruddin Beg,

Shraddha Tivari,

Akanksha Kashyap

et al.

Journal of Heterocyclic Chemistry, Journal Year: 2024, Volume and Issue: 61(3), P. 458 - 465

Published: Jan. 3, 2024

Abstract An efficient visible light‐mediated, eosin Y‐catalyzed synthesis of oxazole has been developed from benzil with primary amines, that providing a straightforward, green, and environmentally benign access to wide variety substituted oxazole‐2‐amines under mild reaction conditions.

Language: Английский

Citations

10

Light-driven photocatalysis as an effective tool for degradation of antibiotics DOI Creative Commons
Praveen P. Singh,

Geetika Pandey,

Yogesh Murti

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(29), P. 20492 - 20515

Published: Jan. 1, 2024

Antibiotic contamination has become a severe issue and dangerous concern to the environment because of large release antibiotic effluent into terrestrial aquatic ecosystems. To try solve these issues, plethora research on withdrawal been carried out. Recently photocatalysis received tremendous attention due its ability remove antibiotics from aqueous solutions in cost-effective environmentally friendly manner with few drawbacks compared traditional photocatalysts. Considerable focused developing advanced visible light-driven photocatalysts order address problems. This review provides an overview recent developments field photocatalytic degradation antibiotics, including doping metals non-metals ultraviolet photocatalysts, formation new semiconductor advancement heterojunction building surface plasmon resonance-enhanced systems.

Language: Английский

Citations

9

Neoteric chemical transformation involving gold based photocatalysis DOI Creative Commons
Vishal Srivastava, Surabhi Sinha, Deepak Kumar

et al.

Tetrahedron Green Chem, Journal Year: 2023, Volume and Issue: 1, P. 100009 - 100009

Published: Jan. 1, 2023

Gold photocatalysis includes a diverse set of gold-catalyzed processes with essentially distinctive fundamental stages. When and gold catalysis are combined, then it results to change the valence centre by electron transfer radical addition without usage exogenous oxidants that stoichiometrically sacrificed. A number significant organic transformations made possible radicals' exceptional compatibility catalysts. The using complexes opens up new opportunities for chemistry complements existing photoredox techniques admirably. In this review, achieved mononuclear gold(I) catalysts (both those photosensitizer) dinuclear photocatalysts discussed fascinating techniques, as well their significance chemists.

Language: Английский

Citations

14

Visible-light induced acridinium catalysed synthesis of biologically active dihydropyranopyrazoles scaffolds via HAT DOI

Mangla Mishra,

Praveen P. Singh, Pankaj Nainwal

et al.

Tetrahedron Letters, Journal Year: 2023, Volume and Issue: 129, P. 154749 - 154749

Published: Sept. 9, 2023

Language: Английский

Citations

14

Visible light mediated metal free photocatalytic synthesis of 2,4- disubstituted quinoline DOI Creative Commons
Shraddha Tivari,

Mohd. Zaheeruddin Beg,

Akanksha Kashyap

et al.

Results in Chemistry, Journal Year: 2023, Volume and Issue: 7, P. 101249 - 101249

Published: Dec. 8, 2023

A visible light-induced, photoredox catalyzed, eco-friendly one pot method for the synthesis of 2,4-disubsitituted quinoline has been proposed. This novel strategy utilizes light to produce 2,4-disubstituted through tandem reactions involving formation C-N and C-C bonds with high yield product under relatively mild reaction conditions. synthetic protocol many important benefits, including a cost-effective catalyst, short time, excellent atom economy, simple work-up an extensive substrate scope.

Language: Английский

Citations

12

Visible-light photocatalysed synthesis of coumarin derivatives DOI

Akanksha Kashyap,

Praveen P. Singh, Yogesh Murti

et al.

Tetrahedron Letters, Journal Year: 2024, Volume and Issue: 142, P. 155099 - 155099

Published: May 7, 2024

Language: Английский

Citations

4

Iron Photoredox Catalysis as an Effective Tool for Organic Synthesis via Visible‐Light‐Induced Homolysis (VLIH) DOI
Vishal Srivastava, Praveen P. Singh, Surabhi Sinha

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(4)

Published: Jan. 1, 2025

Abstract Owing to its possible advantages for the environment and economy, photoredox catalysis of organic processes fueled by iron has garnered a lot interest recently. The potential photo‐induced single‐electron transfer (SET) events occurring outside sphere is now well acknowledged. Currently, focus shifted newly discovered photoactivation method that based on an inner‐sphere mode reactivity caused population visible‐light‐induced homolysis (VLIH) states. VLIH activation, in contrast photoredox, specific complexes, offers distinct profiles, does not require redox potentials coincide. These attractive properties have prompted development strategies use this blueprint manufacture highly reactive open‐shell species mild environments. purpose contribution promote novel synthetic techniques sustainable chemical transformations offer educational instrument understanding evolving idea.

Language: Английский

Citations

0