Covalent organic frameworks and metal–organic frameworks for sustainable adsorptive removal/extraction of dirty dozen chemicals: A review

Journal of the Chinese Chemical Society, Journal Year: 2024, Volume and Issue: 71(9), P. 978 - 1007

Published: July 24, 2024

Abstract Dirty dozen chemicals (DDCs) are a group of 12 extremely toxic that were recognized at the Stockholm convention in 2001 for their severe impact on ecosystem and human health. Despite embargo restraint placed DDCs usage, these continue to find way into because they still secretly or openly applied by many nations, especially African regions. Moreover, can be perceived where have been employed previously before treaty due persistent profile. This study aimed critically review original works directed toward removal various dirty using covalent metal–organic frameworks (COFs MOFs). Specifically, this study, COFs/MOFs composites with remarkably tailored adsorptive profiles evaluated adsorption efficiency different DDCs. In addition, effect operating parameters importance environmentalists stakeholders optimization purposes was empirically discussed. also fills knowledge vacuums about COF/MOF‐DDCs process, offers insights reusability potential, fundamental mechanism, isotherm, kinetic modeling, framework future studies. Findings from revealed COF MOF high DDC capacity potential attributed admirable porosity existence plethora oxygen‐rich functional groups allow better interactions through chelation, halogen bonding, H‐bonding, π‐π stacking. points upscaling remediation technique. Future researchers need direct more efforts use density theory mechanism interpretation, exploration hybrid technology, cost analysis, scalability, thermodynamics, adsorption, desorption modeling.

Language: Английский

Aunps-Mab Probe Based Immunochromatographic Strip for Rapid And Sensitive Detection of P,P`-Dda

Published: Jan. 1, 2024

Language: Английский