Advanced Electronic Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 12, 2024
Abstract
Black
phosphorus
(bP)
is
one
of
the
more
recently
discovered
layered
materials.
Utilizing
hysteresis
in
transfer
characteristics
bP
field‐effect
transistors
(FETs),
several
approaches
to
realize
non‐volatile
memory
devices
are
successfully
demonstrated.
This
commonly
attributed
charge
trapping
and
detrapping
impurities
defects
whose
nature
location
device
however
unclear.
In
this
work,
deliberately
introduced
into
FETs
by
irradiating
with
highly
charged
Xe
30
+
at
a
kinetic
energy
180
20
keV
manipulate
their
electrical
properties.
The
results
show
for
ion
higher
an
increase
conductance
p‐doping
up
1.2
·
10
12
cm
−2
increasing
fluence,
while
carrier
mobility
degrades
fluences.
Most
notably,
hysteresis'
width
window
observed
due
irradiation.
By
controlling
ions,
it
can
be
demonstrated,
that
modifications
electronic
properties
arise
from
underlying
SiO
2
substrate.
However,
changes
hysteretic
exclusively
irradiation‐induced
substrate,
so
irradiation
significantly
improve
based
devices.
Materials Horizons,
Journal Year:
2024,
Volume and Issue:
11(10), P. 2397 - 2405
Published: Jan. 1, 2024
Black
phosphorus
(BP)
field-effect
transistors
with
ultrathin
channels
exhibit
unipolar
p-type
electrical
conduction
over
a
wide
range
of
temperatures
and
pressures.
Journal of Physics and Chemistry of Solids,
Journal Year:
2023,
Volume and Issue:
179, P. 111406 - 111406
Published: April 25, 2023
2D
layered
materials
with
their
tunable
bandgap
and
unique
crystal
structures
are
excellent
candidates
for
optoelectronic
memories.
In
this
work,
we
present
a
simple
approach
the
realization
of
nonvolatile
memory
device
based
on
MoS2
transistor
light
induced
charge
storage
capability.
The
shows
108
on/off
current
ratio
hysteresis
width
modulation
by
air
pressure
under
normal
quiet
measurement
conditions.
Moreover,
persistent
photoconductivity
exhibits
photo
responsive
performance
switching
two
orders
magnitude
photocurrent
that
increases
linearly
incident
power.
We
show
combination
gate
voltage
can
be
used
to
control
increase
window
magnitude.
obtained
results
significant
step
toward
improvement
devices,
showing
enable
multilevel
device.
ACS Applied Nano Materials,
Journal Year:
2023,
Volume and Issue:
6(6), P. 4573 - 4583
Published: March 3, 2023
Bi2O2Se
nanosheets,
an
emerging
ternary
non-van
der
Waals
two-dimensional
(2D)
material,
have
garnered
considerable
research
attention
in
recent
years
owing
to
their
robust
air
stability,
narrow
indirect
bandgap,
high
mobility,
and
diverse
intriguing
properties.
However,
most
of
them
show
dark
current
relatively
low
light
on/off
ratio
slow
response
speed
because
the
large
charge
carrier
concentration
bolometric
effect,
hindering
further
application
low-energy-consuming
optoelectronics.
Herein,
a
homotype
van
heterostructure
based
on
exfoliated
n-InSe
integrated
with
chemical
vapor
deposition
(CVD)-grown
n-Bi2O2Se
nanosheets
that
type
II
band
alignment
was
fabricated.
The
efficient
interfacial
separation,
strong
interlayer
coupling,
effective
built-in
electric
field
across
heterointerface
demonstrated
excellent,
stable,
broadband
self-driven
photodetection
range
400–1064
nm.
Specifically,
responsivity
(R)
75.2
mA·W–1
specific
detectivity
(D*)
1.08
×
1012
jones
were
achieved
under
405
nm
illumination.
Additionally,
R
13.3
D*
2.06
1011
980
Meanwhile,
ultrahigh
Ilight/Idark
over
105
fast
time
5.8/15
ms
illumination
confirmed
excellent
photosensitivity
behavior.
Furthermore,
could
be
enhanced
13.6
791
at
drain–source
voltage
(Vds)
1
V,
respectively,
originating
from
lower
potential
barrier.
This
study
suggested
nanosheet/InSe
nanoflake
heterojunction
can
offer
applications
next-generation
photodetectors
consume
energy
exhibit
performance.
Next Materials,
Journal Year:
2024,
Volume and Issue:
4, P. 100217 - 100217
Published: May 3, 2024
Few
layers
Black
phosphorus
(BP)
and
phosphorene
are
two-dimensional
(2D)
materials
renowned
for
their
adjustable
bandgaps,
high
carrier
mobility,
anisotropic
conductivity,
which
make
them
highly
promising
applications
in
the
visible
infrared
spectrum.
The
incorporation
of
these
into
polymer
matrices
has
led
to
significant
advancements
material
science,
resulting
nanocomposites
with
enhanced
mechanical,
electrical,
optical
properties.
This
article
provides
a
thorough
analysis
BP/phosphorene
nanocomposites,
including
synthesis
techniques
(such
as
exfoliation
methods)
manufacturing
approaches.
Advanced
characterisation
utilised
assess
structure,
morphology,
properties
composites.
highlights
potential
energy
storage
(e.g.,
high-capacity
batteries),
flexible
electronics
bendable
displays),
environmental
sensing,
emerging
biomedical
fields
such
targeted
drug
delivery.
Furthermore,
discusses
solutions
tackle
challenges
associated
scalable,
cost-effective
production
ambient
stability
BP/phosphorene,
leveraging
recent
engineering
research.
conclusion
outlines
future
research
directions,
emphasising
importance
addressing
persistent
through
technological
breakthroughs
exploring
avenues
further
advancement.
Surfaces and Interfaces,
Journal Year:
2024,
Volume and Issue:
49, P. 104445 - 104445
Published: May 6, 2024
In
recent
years,
van
der
Waals
heterojunctions
between
two-dimensional
(2D)
materials
have
garnered
significant
attention
for
their
unique
electronic
and
optoelectronic
properties
opened
avenues
innovative
device
architectures
applications.
Among
them,
the
heterojunction
formed
by
black
phosphorus
(BP)
molybdenum
disulfide
(MoS2)
stands
out
as
a
promising
candidate
advanced
devices.
This
study
unravels
interplay
BP,
MoS2,
Cr
contacts
to
explain
electrical
behavior
of
BP/MoS2
showing
rectifying
with
dominant
n-type
conduction,
high
ON/OFF
current
ratio
around
104
at
±
20
V.
The
higher
unexpected
observed
when
applying
negative
bias
either
MoS2
or
BP
side
is
elucidated
an
energy
band
model
incorporating
type
II
interface
forming
Schottky
contact
ohmic
BP.
shows
pronounced
photoresponse,
linearly
dependent
on
incident
laser
power,
responsivity
100
µA/W
under
white
light
50
µW
power.
Time-resolved
photocurrent
measurements
reveal
relatively
fast
response
characteristic
rise
times
less
than
200
ms.
work
demonstrates
that
photoresponse
characteristics
are
Applied Physics Express,
Journal Year:
2025,
Volume and Issue:
18(1), P. 015003 - 015003
Published: Jan. 1, 2025
Abstract
Graphene
photodetectors
face
challenges
like
weak
absorption
and
narrow
spectral
range.
To
overcome
these
weakness,
we
proposed
a
novel
photodetector
based
on
Gold
(Au)/Graphene/Chalcogenide
(Sb
2
S
3
)
hetero-junction,
leveraging
surface
plasmonic
phase-transition
effects.
Simulations
show
that
optimizing
Au
Sb
nanoantenna
thicknesses
diameters
can
achieve
an
efficiency
of
0.9
for
both
amorphous
crystalline
states,
with
adjustable
wavelength
range
200
nm.
The
device
demonstrates
superior
performance,
including
responsivity
125
A
W
−1
,
quantum
1.36
×
10
4
%,
detectivity
2.25
9
Jones,
offering
pathway
to
next-generation
optoelectronic
chips.
Heliyon,
Journal Year:
2025,
Volume and Issue:
11(3), P. e42443 - e42443
Published: Feb. 1, 2025
Highlights•Pressure-dependence
electrical
properties
of
vertical
BP/MoS2
heterostructures.•Gate-tunable
rectification
(ratio
103)
with
thermionic
and
tunneling
mechanisms•n-type
conduction,
ON/OFF
ratio
106,
mobility
1.6
cm2
V-1
s-1•Promising
for
low-power
electronics,
high-performance
transistors,
sensorsAbstractVan
der
Waals
heterostructures
between
two-dimensional
(2D)
materials
offer
versatile
platforms
innovative
device
architectures
applications.
Black
phosphorus
(BP)
molybdenum
disulfide
(MoS2)
emerge
as
promising
candidates
heterostructures,
owing
to
their
exceptional
electronic
gate-tunable
capabilities.
In
this
work,
we
study
the
a
heterostructure
fabricated
onto
SiO2/Si
substrate
in
back-gate
configuration.
We
focus
on
effect
air
pressure,
from
atmospheric
pressure
10-4
mbar,
show
that
best
performances
are
enabled
at
lower
pressure.
The
exhibits
rectifying
current-voltage
characteristics,
close
103.
characteristics
present
kink
forward
region
revealing
different
conduction
mechanisms,
namely
drift-diffusion
band-to-band
tunnelling.
Furthermore,
when
used
transistor,
shows
n-type
high
gate
modulation
of,
low
off-state
current
s-1.
results
work
highlight
potential
applications
sensitive
sensors.Graphical
abstract
Heliyon,
Journal Year:
2024,
Volume and Issue:
10(2), P. e24427 - e24427
Published: Jan. 1, 2024
The
discovery
of
graphene
ignites
a
great
deal
interest
in
the
research
and
advancement
two-dimensional
(2D)
layered
materials.
Within
it,
semiconducting
transition
metal
dichalcogenides
(TMDCs)
are
highly
regarded
due
to
their
exceptional
electrical
optoelectronic
properties.
Tungsten
disulfide
(WS
Molecules,
Journal Year:
2023,
Volume and Issue:
28(13), P. 5062 - 5062
Published: June 28, 2023
The
usage
of
flame
retardants
in
flammable
polymers
has
been
an
effective
way
to
protect
both
lives
and
material
goods
from
accidental
fires.
Phosphorus
have
the
potential
be
follow-on
after
halogenated
variants,
because
their
low
toxicity,
high
efficiency
compatibility.
Recently,
emerging
allotrope
phosphorus,
two-dimensional
black
as
a
retardant
developed.
To
further
understand
its
performance
flame-retardant
among
phosphorus
retardants,
this
work,
we
built
model
materials
compare
performances
few-layer
red
nanoparticles,
triphenyl
phosphate
additives
cellulose
polyacrylonitrile.
Aside
superior
retardancy
polyacrylonitrile,
showed
self-extinguishing,
~1.8
~4.4
times
that
nanoparticles
with
similar
lateral
size
mass
load
(2.5~4.8
wt%),
respectively.
char
layer
coated
combustion
was
more
continuous
smoother
than
blank,
amount
residues
thermogravimetric
analysis
were
10
wt%,
14
wt%
In
addition,
although
exothermic
reactions,
enthalpy
changes
(−127.1
kJ
mol−1)
are
one
third
(−381.3
mol−1).
Based
on
joint
thermodynamic,
spectroscopic,
microscopic
analysis,
attributed
reaction
suppression
structure
thermal
nature
phosphorus.