Enhancements of Triethanolamine CO2 Absorption Rate and Degradation in the Presence of Nickel Nanoparticles Catalysts DOI Creative Commons

Harold W. Orendi,

Kevin Joby,

Lidija Šiller

et al.

Atmosphere, Journal Year: 2024, Volume and Issue: 15(12), P. 1479 - 1479

Published: Dec. 11, 2024

Here, the catalytic and degradation effect of nickel nanoparticles (NiNPs) on triethanolamine (TEA) with CO2 at 20 °C 50 a range TEA concentrations (3–30 wt%) was studied. We show that absorption rate can be enhanced NiNPs, maximum enhancement 8.3% when compared to control solution found 30 wt% alone. Additionally, time for fully loaded is reduced; control, NiNPs solutions were up 26.3% faster. Also, best our knowledge, this first has been subject both oxygen (30 wt%, 55 °C, 0.35 L/min air, 0.4 molCO2/molTEA, 7.5 mL/min CO2) thermal without 0.5 135 °C). In experiments, surprisingly, there no significant difference in presence NiNPs. At high temperature (135 °C), lost 19.2% 20.3% original TEA, respectively. oxygen, 30.5% 33.6% This indicates or its mixture other amines could improve post-combustion capture.

Language: Английский

Partial Oxidation of CH4 in Plasma: The Effects of Oxidant and Catalyst Addition DOI Creative Commons
O. V. Golubev, A. L. Maximov

Molecules, Journal Year: 2025, Volume and Issue: 30(9), P. 1958 - 1958

Published: April 28, 2025

The partial oxidation of methane in cold atmospheric plasma represents an innovative and promising approach to energy conversion sustainable chemical processes for obtaining various chemicals fuels. In present work, dielectric barrier discharge is applied the CH4 combined with Cu-containing catalysts. catalysts different porous acidic properties were obtained, characterized by physico-chemical methods used plasma-catalytic reaction. influence oxidizing agent (oxygen vs. air) on products’ selectivity yield was studied. It found that using air as oxidizer beneficial terms gaseous products yield, N2 aided denser microdischarge formation. Using pure O2 resulted enhanced oxygenate (mainly CH3OH) generation. Furthermore, methanol compared plasma-only process, well efficiency process.

Language: Английский

Citations

0
Enhancements of Triethanolamine CO2 Absorption Rate and Degradation in the Presence of Nickel Nanoparticles Catalysts DOI Creative Commons

Harold W. Orendi,

Kevin Joby,

Lidija Šiller

et al.

Atmosphere, Journal Year: 2024, Volume and Issue: 15(12), P. 1479 - 1479

Published: Dec. 11, 2024

Here, the catalytic and degradation effect of nickel nanoparticles (NiNPs) on triethanolamine (TEA) with CO2 at 20 °C 50 a range TEA concentrations (3–30 wt%) was studied. We show that absorption rate can be enhanced NiNPs, maximum enhancement 8.3% when compared to control solution found 30 wt% alone. Additionally, time for fully loaded is reduced; control, NiNPs solutions were up 26.3% faster. Also, best our knowledge, this first has been subject both oxygen (30 wt%, 55 °C, 0.35 L/min air, 0.4 molCO2/molTEA, 7.5 mL/min CO2) thermal without 0.5 135 °C). In experiments, surprisingly, there no significant difference in presence NiNPs. At high temperature (135 °C), lost 19.2% 20.3% original TEA, respectively. oxygen, 30.5% 33.6% This indicates or its mixture other amines could improve post-combustion capture.

Language: Английский

Citations

0