Reduction of Trinitrobenzene to Amines with Molecular Hydrogen over Chrysocolla-like Catalysts DOI Open Access
O. A. Kirichenko, Elena V. Shuvalova, Г. И. Капустин

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(10), P. 686 - 686

Published: Oct. 2, 2024

The cheap non-noble Cu–SiO2-based nanocatalysts are under intensive study in different reactions resulting useful chemicals, yet their application environment protection is poorly studied. In the present work, influence of Cu loading (3–15 wt%) on catalytic behavior Cu/SiO2 materials was first precisely studied hydrogenation hazardous trinitrobenzene to valuable aromatic amines with molecular hydrogen. catalysts have been synthesized by method deposition–precipitation using urea. catalyst characterization XRD, TPR-H2, SEM, TEM, and N2 adsorption methods confirmed that they include nanoparticles micro-mesoporous chrysocolla-like phase supported mesopores a commercial SiO2 carrier, as well revealed formation highly dispersed CuO sample highest loading. Variation reaction conditions showed optimal ones (170 °C, 1.3 MPa H2) complete conversion triaminobenzene yield 65% for 15% loading, best 82% obtained over 10% calcined at 600 °C. results show potential phyllosilicate-based utilization trinitroaromatic compounds via possible applications remediation treatment system.

Language: Английский

Green and efficient one-pot three-component synthesis of novel drug-like furo[2,3-d]pyrimidines as potential active site inhibitors and putative allosteric hotspots modulators of both SARS-CoV-2 MPro and PLPro DOI Open Access
Hossein Mousavi, Behzad Zeynizadeh, Mehdi Rimaz

et al.

Bioorganic Chemistry, Journal Year: 2023, Volume and Issue: 135, P. 106390 - 106390

Published: Jan. 28, 2023

Language: Английский

Citations

27
A comprehensive survey upon diverse and prolific applications of chitosan-based catalytic systems in one-pot multi-component synthesis of heterocyclic rings DOI
Hossein Mousavi

International Journal of Biological Macromolecules, Journal Year: 2021, Volume and Issue: 186, P. 1003 - 1166

Published: June 24, 2021

Language: Английский

Citations

52
Fabrication of CuFe2O4 decorated Ni-BTC MOF for boosting the reduction of nitroaromatic pollutants DOI
Mayuri Dutta, Jyotismita Bora, Tikendrajit Chetia

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 141939 - 141939

Published: March 1, 2025

Language: Английский

Citations

1
Diverse and efficient catalytic applications of new cockscomb flower-like Fe3O4@SiO2@KCC-1@MPTMS@CuIImesoporous nanocomposite in the environmentally benign reduction and reductive acetylation of nitroarenes and one-pot synthesis of some coumarin compounds DOI Creative Commons
Morteza Hasanpour Galehban, Behzad Zeynizadeh, Hossein Mousavi

et al.

RSC Advances, Journal Year: 2022, Volume and Issue: 12(18), P. 11164 - 11189

Published: Jan. 1, 2022

In this research, Fe

Language: Английский

Citations

22
NiIINPs entrapped within a matrix ofl-glutamic acid cross-linked chitosan supported on magnetic carboxylic acid-functionalized multi-walled carbon nanotube: a new and efficient multi-task catalytic system for the green one-pot synthesis of diverse heterocyclic frameworks DOI Creative Commons
Morteza Hasanpour Galehban, Behzad Zeynizadeh, Hossein Mousavi

et al.

RSC Advances, Journal Year: 2022, Volume and Issue: 12(26), P. 16454 - 16478

Published: Jan. 1, 2022

In the present study, a new l-glutamic acid cross-linked chitosan supported on magnetic carboxylic acid-functionalized multi-walled carbon nanotube (Fe

Language: Английский

Citations

22
Immobilized nickel boride nanoparticles on magnetic functionalized multi-walled carbon nanotubes: a new nanocomposite for the efficient one-pot synthesis of 1,4-benzodiazepines DOI Creative Commons

Farkhondeh Mohammad Aminzadeh,

Behzad Zeynizadeh

Nanoscale Advances, Journal Year: 2023, Volume and Issue: 5(17), P. 4499 - 4520

Published: Jan. 1, 2023

In this study, a new magnetic nanocomposite consisting of Ni2B nanoparticles anchored on functionalized multi-walled carbon nanotubes (Fe3O4/f-MWCNT/Ni2B) was synthesized and characterized using various techniques such as FT-IR, XRD, FESEM, SEM-based EDX, elemental mapping, HRTEM, DLS, SAED, XPS, BET, TGA, VSM. The as-prepared successfully employed for the preparation bioactive 1,4-benzodiazepines from three-component reaction o-phenylenediamine (1), dimedone (2), different aldehydes (3), in polyethylene glycol 400 (PEG-400) solvent at 60 °C. obtained results demonstrated that current one-pot protocol offers many advantages, good-to-excellent yields within acceptable times, favorable TONs TOFs, eco-friendliness procedure, easy nanocomposite, mild conditions, broad range products, excellent catalytic activity, green solvent, reusability nanocomposite.

Language: Английский

Citations

13
Highly efficient synthesis of isoxazolones and pyrazolones using g-C3N4·OH nanocomposite with their in silico molecular docking, pharmacokinetics and simulation studies DOI Creative Commons
Shivani Soni, Sunita Teli, Pankaj Teli

et al.

Scientific Reports, Journal Year: 2024, Volume and Issue: 14(1)

Published: Aug. 18, 2024

An environmentally friendly, versatile multicomponent reaction for synthesizing isoxazol-5-one and pyrazol-3-one derivatives has been developed, utilizing a freshly prepared g-C

Language: Английский

Citations

5
A concise and focused overview upon arylglyoxal monohydrates-based one-pot multi-component synthesis of fascinating potentially biologically active pyridazines DOI
Hossein Mousavi

Journal of Molecular Structure, Journal Year: 2021, Volume and Issue: 1251, P. 131742 - 131742

Published: Oct. 19, 2021

Language: Английский

Citations

24
Introducing Fe3O4@SiO2@KCC-1@MPTMS@CuII catalytic applications for the green one-pot syntheses of 2-aryl(or heteroaryl)-2,3-dihydroquinazolin-4(1H)-ones and 9-aryl-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-diones DOI
Morteza Hasanpour Galehban, Behzad Zeynizadeh, Hossein Mousavi

et al.

Journal of Molecular Structure, Journal Year: 2022, Volume and Issue: 1271, P. 134017 - 134017

Published: Aug. 28, 2022

Language: Английский

Citations

17
NiII-containing l-glutamic acid cross-linked chitosan anchored on Fe3O4/f-MWCNT: a sustainable catalyst for the green reduction and one-pot two-step reductive Schotten–Baumann-type acetylation of nitroarenes DOI Creative Commons
Hossein Mousavi, Behzad Zeynizadeh, Morteza Hasanpour Galehban

et al.

Nanoscale Advances, Journal Year: 2024, Volume and Issue: 6(15), P. 3961 - 3977

Published: Jan. 1, 2024

In this research, new catalytic applications of the Fe 3 O 4 / f -MWCNT-CS-Glu/Ni II nanocomposite have been introduced for efficient reduction and one-pot two-step reductive Schotten–Baumann-type acetylation nitroarenes in water.

Language: Английский

Citations

3