The electrochemical coupling reactions of organic halides compound in a valuable and practical manner for C C and C–heteroatom formation: An overview
Arabian Journal of Chemistry,
Journal Year:
2024,
Volume and Issue:
17(8), P. 105822 - 105822
Published: May 24, 2024
Owing
to
the
environmental
and
energy
problems
nowadays,
one
of
enormous
challenges
is
expanding
clean,
renewable
reduce
destructive
ecological
effects
chemical
industries.
Compared
with
other
traditional
processes,
electrochemical
method
has
some
benefits,
such
as
being
selective,
causing
minor
waste,
working
under
mild
conditions
no
external
oxidizing
or
reducing
reagents,
making
this
approach
more
economical
eco-friendly.
Electrochemistry
represents
a
powerful
tool
within
synthetic
organic
chemistry.
The
development
part
chemistry
intends
performance
reactions
employing
electrons,
including
adding
removing
electrons.
Using
electric
current
reagent
advantages,
simplicity
reactions,
accessibility
materials,
replacing
toxic
applying
an
eco-friendly
environment.
During
last
decades,
there
been
much
effort
decrease
usage
fossil
fuels,
electricity
emerged
common
source.
conversion
into
leads
new
paths,
naturally
safe
environmentally
friendly.
Developing
electrochemistry
approaches
for
performing
high-performance
essential
reaction
green
strategy
because
utilization
instead
stoichiometric
oxidants
reductants.
Due
its
helpful
friendly
ability
produce
reactive
intermediates,
advanced
considerably
in
oxidative
hydrogen
evolution
coupling
sacrificial
anode
electroreduction.
New
developments
focus
on
developing
electrolytic
catalysts,photoelectrocatalysis,
bioelectrosynthesis,
optimizing
electrode
paired
electrolysis,
artificial
intelligence-assisted
electrosynthesis.
Thus,
daily
significant
number
construction
projects
possibilities
electrochemistry.
Electrochemical
methods
constructing
compounds
have
tolerated
renewal
past
decades.
Organic
wealthy
background
synthesis.
We
hope
review
helps
attract
attention
from
researchers
by
using
processes
laboratory
industrial
centers,
which
pollution
create
In
review,
organohalides
synthesizing
various
products
summarized
discussed
since
2000.
Language: Английский
Microwave-assisted preparation of polysubstituted imidazoles using Zingiber extract synthesized green Cr2O3 nanoparticles
Scientific Reports,
Journal Year:
2022,
Volume and Issue:
12(1)
Published: Nov. 19, 2022
Abstract
Cr
2
O
3
nanoparticles
were
prepared
using
Zingiber
officinal
extract
which
used
as
an
efficient
and
reusable
catalyst
in
the
practical
synthesis
of
polysubstituted
imidazoles
by
means
a
convenient
reaction
aromatic
aldehydes
with
ammonium
acetate
benzil
under
microwave
irradiation
H
solvent.
The
structure
compounds
was
studied
IR
1
H-NMR
spectrum.
most
important
benefits
this
process
are
operational
simplicity,
reasonable
times,
excellent
yield
products.
results
show
that
optimal
conditions
for
formation
imidazole
derivatives
follow:
power
400
W,
time
4–9
min,
solvent,
15
mmol
amount.
Language: Английский