Chiral Porous Frameworks for Enantioselective Separation and Asymmetric Catalysis DOI Open Access
Bing Yan, Jinhui Song, Deqi Zhang

et al.

Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Comprehensive Summary The preparation and resolution of chiral molecules hold significant importance in scientific industrial domains, such as drug development manufacturing. In recent years, porous frameworks have attracted increasing attention asymmetric catalysis enantiomer due to their excellent performance. metal‐organic (MOFs), covalent organic (COFs), cages (POCs), coordination (PCCs) are important representative the framework family. Significantly, chirality can be easily introduced into these materials through simple bottom‐up or post‐modification methods, thereby promoting applications related chirality. this review, we systematically summarize synthesis strategies four classes enantiomeric resolution. Finally, present some perspectives on future frameworks. Key Scientists Significant progress has been made frameworks, primarily driven by application molecules. This area research seen contributions from many distinguished scientists. A particularly milestone was reached 2000, when Kimoon Kim reported first catalytic Chiral Metal‐Organic Framework (CMOF). 2001, Lin et al . a new generation recyclable CMOF capable separation heterogeneous catalysis. Simultaneously, researchers Cui Duan substantial contributions, advancing field considerably. Furthermore, notable developments Covalent Organic Frameworks (CCOFs), with pioneering work like Jiang, Wang, Cui. Meanwhile, groups Su Li strides cages. These remarkable accomplishments drawn considerable interest.

Language: Английский

Chiral Porous Frameworks for Enantioselective Separation and Asymmetric Catalysis DOI Open Access
Bing Yan, Jinhui Song, Deqi Zhang

et al.

Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Comprehensive Summary The preparation and resolution of chiral molecules hold significant importance in scientific industrial domains, such as drug development manufacturing. In recent years, porous frameworks have attracted increasing attention asymmetric catalysis enantiomer due to their excellent performance. metal‐organic (MOFs), covalent organic (COFs), cages (POCs), coordination (PCCs) are important representative the framework family. Significantly, chirality can be easily introduced into these materials through simple bottom‐up or post‐modification methods, thereby promoting applications related chirality. this review, we systematically summarize synthesis strategies four classes enantiomeric resolution. Finally, present some perspectives on future frameworks. Key Scientists Significant progress has been made frameworks, primarily driven by application molecules. This area research seen contributions from many distinguished scientists. A particularly milestone was reached 2000, when Kimoon Kim reported first catalytic Chiral Metal‐Organic Framework (CMOF). 2001, Lin et al . a new generation recyclable CMOF capable separation heterogeneous catalysis. Simultaneously, researchers Cui Duan substantial contributions, advancing field considerably. Furthermore, notable developments Covalent Organic Frameworks (CCOFs), with pioneering work like Jiang, Wang, Cui. Meanwhile, groups Su Li strides cages. These remarkable accomplishments drawn considerable interest.

Language: Английский

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