International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 110, P. 421 - 429
Published: March 1, 2024
Language: Английский
International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 110, P. 421 - 429
Published: March 1, 2024
Language: Английский
Chemical Engineering Science, Journal Year: 2025, Volume and Issue: unknown, P. 121327 - 121327
Published: Feb. 1, 2025
Language: Английский
Citations
2ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 14665 - 14677
Published: Sept. 18, 2024
Language: Английский
Citations
9Desalination, Journal Year: 2024, Volume and Issue: 594, P. 118293 - 118293
Published: Nov. 8, 2024
Language: Английский
Citations
9Composites Part B Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 112112 - 112112
Published: Jan. 1, 2025
Language: Английский
Citations
1Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 2, 2025
Language: Английский
Citations
1Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 16, 2025
Abstract Direct hydrogenolysis of cellulose to produce ethanol is a promising way efficiently utilize biomass resources, contributing significantly low‐carbon energy development and greenhouse gas reduction. However, this process challenging due intricate cascading reactions. In study, PdZn@S‐1 catalysts featuring metal‐acid “restricted adjacency” structures for direct conversion are developed. This unique structure allows acidic sites metal nanoparticles be in close proximity microscopic space, leading changes the electronic states sites, an increase number sites. configuration fosters synergistic balanced interaction between two types As result, PdZn 0.5 @S‐1 catalyst demonstrates exceptional performance, achieving yield 69.2% at 245 °C 4.5 MPa H 2 within 4 h. The remarkable catalytic activity selectivity attributed formation Lewis acid through Pd δ+ ─O(H)─Si coordination, which facilitates cleavage C─C bonds, while adjacent alloy provides effective site hydrogenation C─O bonds. work introduces novel approach by successfully integrating metal@zeolite into macromolecules, offering new insights utilization resources.
Language: Английский
Citations
1Angewandte Chemie, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Abstract Transition metal‐catalyzed transfer hydrogenation (TH) with in situ negative hydrogen (H − ) has received extensive attention as an alternative to conventional high‐pressure processes. However, the insufficient activity of production and unclear conversion process remain a great challenge. In this work, brand new bimetallic ternary‐structured catalysts (Ru 1+n M 1 ‐TiO 2 , M=Co, Cu, Fe, Ni) were synthesized efficiently generate H donors from ammonia borane (AB, NH 3 BH for nitrobenzene under moderate conditions. The Ru Co exhibited highest form AB hydrolysis TOF value 2716 min −1 . achieved >90 % yields within 3–4 hours converting anilines using AB. Mechanistic studies revealed that high was due SA sites bimetallic‐ternary‐structured catalyst required lowest energy activation O, respectively. Remarkably, clusters obvious synergistic effect TH process, which promoted tandem nitroaromatics. This work demonstrated efficient approach donor further provided inspiration on development multifunctional catalysts.
Language: Английский
Citations
1Fuel, Journal Year: 2025, Volume and Issue: 386, P. 134279 - 134279
Published: Jan. 4, 2025
Language: Английский
Citations
0International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 115, P. 93 - 100
Published: March 9, 2025
Citations
0Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106242 - 106242
Published: March 1, 2025
Language: Английский
Citations
0