CsBO(OH)2: a New Hydroxyborate with the Rare [BO(OH)2] Group and deep ultraviolet cutoff edge DOI
Jintu Fan, Luyong Zhang, Zilong Chen

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The hydroxylation of [BO 3 ] groups into [BO(OH) 2 regulates the arrangement groups, thereby enhancing birefringence and increasing bandgap.

Language: Английский

Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution DOI
Muhammad Arif, Xu Liu,

Hangwei Jia

et al.

Materials Horizons, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Aminopyrazine forms low-dimensional structures with enhanced birefringence, driven by optimal coplanarity among birefringent active units regulated [N–H⋯X] hydrogen bonds.

Language: Английский

Citations

1
Unveiling Charge Dependent Law to Enhance Birefringence in 2‐Aminopyrimidine Family DOI
Muhammad Arif, Xu Liu, Zi‐Jian Li

et al.

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

Abstract Salts and co‐crystals composed of planar π ‐conjugated functional units represent a fascinating class materials, featuring both enlarged birefringence strong SHG effect. Herein, the optical properties (C 4 H 7 N 3 ) 2+ unit within 2‐aminopyrimidine (2‐AP) family are investigated for first time. Furthermore, twelve novel compounds successfully synthesized by applying four different strategies. In these strategies, , 6 + 5 introduced into crystal structure, solely in combination, to analyze alteration birefringence. Remarkably, rule with < ), stating that an increase net charge over leads reduced birefringence, is discovered. Consequently, inclusion charge‐neutral structure along coplanar arrangement promising approach enhance D‐2 [(C )(H C O )] realizes Δn calc = 0.412 maximum family. Notably, A‐1 )(CF SO 2 ] B‐1 (IO (H O)] crystalize non‐centrosymmetric space groups, exhibiting efficiency ≈1.4 × KDP @ 1064 nm, shortest λ PM at 384 nm. This work provides new insight discovering birefringent non‐linear materials high performances wide chemical space.

Language: Английский

Citations

4
CsBO(OH)2: a New Hydroxyborate with the Rare [BO(OH)2] Group and deep ultraviolet cutoff edge DOI
Jintu Fan, Luyong Zhang, Zilong Chen

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The hydroxylation of [BO 3 ] groups into [BO(OH) 2 regulates the arrangement groups, thereby enhancing birefringence and increasing bandgap.

Language: Английский

Citations

0