Catalytic Pyrolysis Characteristics of Potassium Chloride on Ash Branch Wood and Its Kinetic Study DOI Open Access
Lanxin Zhang, Jingjing Gao,

Tinghuan Wang

et al.

Forests, Journal Year: 2024, Volume and Issue: 16(1), P. 57 - 57

Published: Dec. 31, 2024

Branch wood, as a renewable biomass resource, presents certain challenges due to its high volume, complex physical properties, difficulty in handling, and relatively production costs. Potassium chloride (KCl) treatments were applied ash branch wood (ABW) using solutions with concentrations of 5%, 10%, 15% via immersion. Pyrolysis tests performed at different pyrolysis temperatures (450 °C, 600 750 °C) times (2 h, 3 4 h). The thermal degradation behavior was meticulously examined through Thermogravimetric Analysis (TGA). Furthermore, the kinetics assessed Flynn–Wall–Ozawa (FWO) model, which allowed for determination kinetic parameters exploration catalytic influence KCl on process. morphology adsorption properties biochar evaluated employing SEM-EDS BET characterization methods, respectively. results show that higher impregnation concentration ABW, greater shift TG DTG curves, lower initial temperature maximum weight loss devolatilization stage. calculation indicates adding ABW activation energy volatile phase ABW. At same time, leads an increased yield; under single-factor conditions, yield up 35.81% can be achieved 15%. A is more conducive reaction, throughout stage compared raw Additionally, treated low specific surface area pore volume biochar. values are when solution 4.2 m2/g 0.00914 cm3/g. Based these results, this paper explores patterns waste, providing theoretical guidance effective utilization preparation process

Language: Английский

Pyrolysis and gasification of energy crops for phytoremediation in Romania’s coal mining region DOI Creative Commons

Antoaneta Roman,

Felicia Bucura,

Oana Romina Botoran

et al.

International Journal of Green Energy, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 18

Published: Feb. 27, 2025

Language: Английский

Citations

0

Analytical pyrolysis of fir sawdust, olive stone and sewage sludge in molten carbonate salts DOI Creative Commons
Elahe Ahmadi, Irene Coralli, Cristian Torri

et al.

Journal of Analytical and Applied Pyrolysis, Journal Year: 2025, Volume and Issue: unknown, P. 107144 - 107144

Published: April 1, 2025

Language: Английский

Citations

0

Machine Learning Optimization of Waste Salt Pyrolysis: Predicting Organic Pollutant Removal and Mass Loss DOI Open Access
Run Zhou,

Qing Gao,

Qiuju Wang

et al.

Sustainability, Journal Year: 2025, Volume and Issue: 17(7), P. 3216 - 3216

Published: April 4, 2025

Pyrolysis presents a promising solution for the complete purification and recycling of waste salt. However, presence organic pollutants in salts significantly hinders their practical application, owing to diverse sources strong resistance degradation. This study developed predictive models removal from salt using three machine learning techniques: Random Forest (RF), Support Vector Machine, Artificial Neural Network. The were evaluated based on total carbon (TOC) rate mass loss rate, with RF model demonstrating high accuracy, achieving R2 values 0.97 0.99, respectively. Feature engineering revealed that contribution components was minimal, rendering them redundant. importance analysis identified temperature as most critical factor TOC removal, while moisture content nitrogen key determinants loss. Partial dependence plots further elucidated individual interactive effects these variables. validated both literature data laboratory experiments, user interface Python GUI library. provides novel insights into pyrolysis process establishes foundation optimizing its application.

Language: Английский

Citations

0

Effects of potassium salt on cellulose pyrolysis: biochar production, kinetic triplet, and thermodynamic properties DOI

Oyepeju R. Oyeleke,

Yulin Hu, G.F. Naterer

et al.

Chemical Engineering Science, Journal Year: 2025, Volume and Issue: unknown, P. 121787 - 121787

Published: May 1, 2025

Language: Английский

Citations

0

Strengthening cracking reactions via introducing nickel species in activation of poplar for enhancing production of mesopores DOI
Linghui Kong,

Yunyu Guo,

Baihong Li

et al.

Biomass and Bioenergy, Journal Year: 2024, Volume and Issue: 193, P. 107513 - 107513

Published: Dec. 2, 2024

Language: Английский

Citations

0

Catalytic Pyrolysis Characteristics of Potassium Chloride on Ash Branch Wood and Its Kinetic Study DOI Open Access
Lanxin Zhang, Jingjing Gao,

Tinghuan Wang

et al.

Forests, Journal Year: 2024, Volume and Issue: 16(1), P. 57 - 57

Published: Dec. 31, 2024

Branch wood, as a renewable biomass resource, presents certain challenges due to its high volume, complex physical properties, difficulty in handling, and relatively production costs. Potassium chloride (KCl) treatments were applied ash branch wood (ABW) using solutions with concentrations of 5%, 10%, 15% via immersion. Pyrolysis tests performed at different pyrolysis temperatures (450 °C, 600 750 °C) times (2 h, 3 4 h). The thermal degradation behavior was meticulously examined through Thermogravimetric Analysis (TGA). Furthermore, the kinetics assessed Flynn–Wall–Ozawa (FWO) model, which allowed for determination kinetic parameters exploration catalytic influence KCl on process. morphology adsorption properties biochar evaluated employing SEM-EDS BET characterization methods, respectively. results show that higher impregnation concentration ABW, greater shift TG DTG curves, lower initial temperature maximum weight loss devolatilization stage. calculation indicates adding ABW activation energy volatile phase ABW. At same time, leads an increased yield; under single-factor conditions, yield up 35.81% can be achieved 15%. A is more conducive reaction, throughout stage compared raw Additionally, treated low specific surface area pore volume biochar. values are when solution 4.2 m2/g 0.00914 cm3/g. Based these results, this paper explores patterns waste, providing theoretical guidance effective utilization preparation process

Language: Английский

Citations

0