Tunable Heterogeneous FeCo Alloy-Mo0.82N Bifunctional Electrocatalysts for Temperature-Adapted Zn–Air Batteries DOI
Wenxian Liu,

Xinxin Niu,

Jinxiu Feng

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(12), P. 15344 - 15352

Published: March 15, 2023

The practical applications of temperature-tolerant Zn-air batteries (ZABs) rely on highly active and stable bifunctional catalysts that accelerate cathodic oxygen reduction (ORR) evolution (OER) reactions. Herein, we successfully integrated fascinating transition metal nitrides FeCo alloys through a simple coordination assembly pyrolysis process. Importantly, the alloy-to-nitride ratio in heterogeneous catalyst can be carefully regulated subsequent etching Moreover, composition-dependent ORR/OER performance FeCo-Mo0.82N was revealed. Aqueous ZABs using optimized FeCo-Mo0.82N-60 as cathode exhibit high peak power density 149.7 mW cm-2 an impressive stability 600 h with low charge-discharge voltage gap decay rate 0.025 mV h-1, which exceeds those most recent reports. Furthermore, FeCo-Mo0.82N-60-based flexible display small specific capacity degradation (3%) from 40 to -10 °C, demonstrating excellent temperature tolerance.

Language: Английский

High entropy alloy nanoparticles as efficient catalysts for alkaline overall seawater splitting and Zn-air batteries DOI
Quan Zhang,

Kang Lian,

Qian Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 646, P. 844 - 854

Published: May 17, 2023

Language: Английский

Citations

107
Single atomic cerium sites anchored on nitrogen-doped hollow carbon spheres for highly selective electroreduction of nitric oxide to ammonia DOI
Weiqing Zhang,

Xuhui Qin,

Tianran Wei

et al.

Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 638, P. 650 - 657

Published: Feb. 9, 2023

Language: Английский

Citations

78
Constructing asymmetric double-atomic sites for synergistic catalysis of electrochemical CO2 reduction DOI Creative Commons
Jiqing Jiao, Qingxi Yuan,

Meijie Tan

et al.

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: Oct. 3, 2023

Elucidating the synergistic catalytic mechanism between multiple active centers is of great significance for heterogeneous catalysis; however, finding corresponding experimental evidence remains challenging owing to complexity catalyst structures and interface environment. Here we construct an asymmetric TeN2-CuN3 double-atomic site catalyst, which analyzed via full-range synchrotron pair distribution function. In electrochemical CO2 reduction, features a with activating two key molecules: operando spectroscopy confirms that Te center activates CO2, Cu helps dissociate H2O. The theoretical results reveal could cooperatively lower energy barriers rate-determining step, promoting proton transfer kinetics. Therefore, displays broad potential range high CO selectivity, improved kinetics good stability. This work presents synthesis characterization strategies catalysts, experimentally unveils underpinning catalysis.

Language: Английский

Citations

75
Heterogeneous Ni-MoN nanosheet-assembled microspheres for urea-assisted hydrogen production DOI
Hui Shen, Tianran Wei, Qian Liu

et al.

Journal of Colloid and Interface Science, Journal Year: 2022, Volume and Issue: 634, P. 730 - 736

Published: Dec. 17, 2022

Language: Английский

Citations

71
Electrocatalytic reduction of carbon dioxide in confined microspace utilizing single nickel atom decorated nitrogen-doped carbon nanospheres DOI

Chunmei Lv,

Kai Huang, Yu Fan

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 111, P. 108384 - 108384

Published: March 24, 2023

Language: Английский

Citations

65
Interfacial engineering of platinum group metals electrocatalysts for advanced electrocatalysis DOI
Jie Li,

Yuhua Xu,

Cheng Wang

et al.

Surfaces and Interfaces, Journal Year: 2023, Volume and Issue: 42, P. 103360 - 103360

Published: Sept. 1, 2023

Language: Английский

Citations

63
Recent Progress in Metal Phosphorous Chalcogenides: Potential High‐Performance Electrocatalysts DOI
Hao Zhang, Tianran Wei, Yuan Qiu

et al.

Small, Journal Year: 2023, Volume and Issue: 19(16)

Published: Jan. 5, 2023

Abstract Since the discovery of graphene, research on family 2D materials has been a thriving field. Metal phosphorous chalcogenides (MPX 3 ) have attracted renewed attention due to their distinctive physical and chemical properties. The advantages MPX , such as tunable layered structures, unique electronic properties, thermodynamically appropriate band alignments abundant catalytic active sites surface, make material great potential in electrocatalysis. In this review, applications electrocatalysts recent years, including hydrogen evolution reaction, oxygen reduction are summarized. Structural regulation, doping multi‐material composite that often effective practical methods further optimize properties these materials, introduced. Finally, challenges opportunities for electrocatalytic discussed. This report aims advance future efforts develop related

Language: Английский

Citations

62
Review and Perspective on Transition Metal Electrocatalysts Toward Carbon-Neutral Energy DOI
Denis Johnson, Eugenie Pranada,

Ray Yoo

et al.

Energy & Fuels, Journal Year: 2023, Volume and Issue: 37(3), P. 1545 - 1576

Published: Jan. 13, 2023

Decarbonizing the chemical industry and achieving carbon-neutral energy is paramount to sustainability of human species on earth. Electrocatalysis using transition metal-based catalysts plays a major role in this task. In work, we present an overview application electrocatalytic reactions. We particularly focus advancement hydrogen evolution reaction (HER), oxygen (OER), reduction (ORR), nitrogen (NRR), carbon dioxide (CO2RR) metal electrocatalysts. also aim highlight achievements these fields limitations their large-scale industrial applications. Different are discussed, from 3-dimensional 1- 0-dimensional structures. place special attention emerging such as 2-dimensional carbide nitride MXenes single atom catalysts. Lastly, offer recommendation for future research directions aforementioned electrocatalysis This work will ultimately help both existing incoming researchers providing state-of-the-art findings identifying challenges that must be addressed order attain energy.

Language: Английский

Citations

61
Au nanoclusters anchored on TiO2 nanosheets for high-efficiency electroreduction of nitrate to ammonia DOI
Miaosen Yang, Tianran Wei,

Jia He

et al.

Nano Research, Journal Year: 2023, Volume and Issue: 17(3), P. 1209 - 1216

Published: Aug. 14, 2023

Language: Английский

Citations

58
Increasing CO Binding Energy and Defects by Preserving Cu Oxidation State via O2-Plasma-Assisted N Doping on CuO Enables High C2+ Selectivity and Long-Term Stability in Electrochemical CO2 Reduction DOI
Dong Gyu Park, Jae Won Choi, Hoje Chun

et al.

ACS Catalysis, Journal Year: 2023, Volume and Issue: 13(13), P. 9222 - 9233

Published: June 26, 2023

Cu is considered as the most promising catalyst for electrochemical carbon dioxide reduction reaction (CO2RR) to produce C2+ hydrocarbons, but achieving high product selectivity and efficiency with long-term stability remains one of great challenges. Herein, we report a strategy realize CO2RR allowing stable catalytic properties by utilizing benefits oxygen-plasma-assisted nitrogen doping on CuO. It exhibited that defects such oxygen vacancies grain boundaries suitable are generated N2 plasma radicals Also, oxidation state maintained without O2 plasma. Indeed, ON–CuO synthesized through demonstrated enable 77% (including C2H4 56%) current density −34.6 mA/cm2 at −1.1 V vs RHE, well 22 h performance degradation. High performances ascribed increased CO binding energy sites in N-doped Furthermore, an situ X-ray absorption near-edge structure analysis reveals favorable C–C coupling leading products.

Language: Английский

Citations

56