In Situ Constructing Heterogeneous Mn(Vo3)2/Navo3 Nanoribbons as High-Performance Cathodes for Aqueous Zinc-Ion Batteries DOI
Jie Lü, Huiling Du, Huan Liu

et al.

Published: Jan. 1, 2023

Aqueous zinc-ion batteries (AZIBs) are emerging as a promising candidate, enjoying accolades for their safety, low cost, and ease of operation. However, some challenges like the slow kinetics structural collapse cathode materials hamper rate capability cyclability. To address these limitations, heterogeneous Mn(VO3)2/NaVO3 (MNVO) nanoribbon hybrid was designed high-performance cathodes zinc storage. Owing to heterointerface between Mn(VO3)2 NaVO3 boosting charge-transfer leading enhanced diffusion kinetics, MNVO exhibits high specific capacity 381.2 mAh g-1 at 0.2 A g-1, (286.7 5 g-1), excellent electrochemical kinetics. Additionally, stable cyclability (a high-capacity retention 95.7 % 1 after 200 cycles) long-term 83.0 2000 cycles). Moreover, storage mechanism co-intercalation Zn2+ H2O into host were investigated by ex situ XRD XPS characterizations. Our work offers new insight understanding development through constructing structure.

Language: Английский

Large interlayer spacing enabling long life vanadium-based aqueous zinc battery in zinc sulfate electrolyte DOI
Zhe Wang, Xinyu Wang,

Yihong Huang

et al.

Journal of Alloys and Compounds, Journal Year: 2023, Volume and Issue: 973, P. 172829 - 172829

Published: Nov. 10, 2023

Language: Английский

Citations

1
Large Interlayer Spacing Enabling Long Life Vanadium-Based Aqueous Zinc Battery in Zinc Sulfate Electrolyte DOI
Zhe Wang, Xinyu Wang, Jianan Zhao

et al.

Published: Jan. 1, 2023

Layered vanadium oxides (V2O5) severed as cathode material for aqueous zinc-ion batteries (ZIBs) have attracted a lot of interest due to their large theoretical capacity. However, V2O5 suffers from the collapse layered structure after long cycles in ZnSO4 electrolyte repeated intercalation/deintercalation large-size hydrated Zn2+. Herein, we design V2O5@Phenylbutylamine (V2O5@PBA) with interlayer spacing inexpensive electrolytes. Between V-O layers, remarkable increase distance (16.4 Å) can be constructed, providing path facile Zn2+ diffusion. The V2O5@PBA exhibits high specific capacity (387 mAh g-1), superior rate performance and cycle life (retention 64% 3000 cycles) electrolytes, which is much better than that (interlayer distance: 11.5 Å). These results show increasing strategy an effective way improve electrochemical oxide electrolyte.

Language: Английский

Citations

0
In Situ Constructing Heterogeneous Mn(Vo3)2/Navo3 Nanoribbons as High-Performance Cathodes for Aqueous Zinc-Ion Batteries DOI
Jie Lü, Huiling Du, Huan Liu

et al.

Published: Jan. 1, 2023

Aqueous zinc-ion batteries (AZIBs) are emerging as a promising candidate, enjoying accolades for their safety, low cost, and ease of operation. However, some challenges like the slow kinetics structural collapse cathode materials hamper rate capability cyclability. To address these limitations, heterogeneous Mn(VO3)2/NaVO3 (MNVO) nanoribbon hybrid was designed high-performance cathodes zinc storage. Owing to heterointerface between Mn(VO3)2 NaVO3 boosting charge-transfer leading enhanced diffusion kinetics, MNVO exhibits high specific capacity 381.2 mAh g-1 at 0.2 A g-1, (286.7 5 g-1), excellent electrochemical kinetics. Additionally, stable cyclability (a high-capacity retention 95.7 % 1 after 200 cycles) long-term 83.0 2000 cycles). Moreover, storage mechanism co-intercalation Zn2+ H2O into host were investigated by ex situ XRD XPS characterizations. Our work offers new insight understanding development through constructing structure.

Language: Английский

Citations

0