Deactivation Mechanism and Mitigation Strategies of Single‐Atom Site Electrocatalysts
Jingjing Liu,
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Jiarui Yang,
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Yuhai Dou
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et al.
Advanced Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 14, 2025
Abstract
Single‐atom
site
electrocatalysts
(SACs),
with
maximum
atom
efficiency,
fine‐tuned
coordination
structure,
and
exceptional
reactivity
toward
catalysis,
energy,
environmental
purification,
have
become
the
emerging
frontier
in
recent
decade.
Along
significant
breakthroughs
activity
selectivity,
limited
stability
durability
of
SACs
are
often
underemphasized,
posing
a
grand
challenge
meeting
practical
requirements.
One
pivotal
obstacle
to
construction
highly
stable
is
heavy
reliance
on
empirical
rather
than
rational
design
methods.
A
comprehensive
review
urgently
needed
offer
concise
overview
progress
stability/durability,
encompassing
both
deactivation
mechanism
mitigation
strategies.
Herein,
this
first
critically
summarizes
degradation
induction
factors
at
atomic‐,
meso‐
nanoscale,
mainly
based
but
not
oxygen
reduction
reaction.
Subsequently,
potential
stability/durability
improvement
strategies
by
tuning
catalyst
composition,
morphology
surface
delineated,
including
robust
substrate
metal‐support
interaction,
optimization
active
stability,
fabrication
porosity
modification.
Finally,
challenges
prospects
for
discussed.
This
facilitates
fundamental
understanding
provides
efficient
principles
aimed
overcoming
difficulties
beyond.
Language: Английский
Carbon nanotube-supported Co-N-C with enriched mesopores for hydrogenation of nitro compounds
Chongqing Wang,
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Jianfei Dang,
No information about this author
Yajing Han
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et al.
Journal of Catalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 116152 - 116152
Published: April 1, 2025
Language: Английский
Bucket effect of Cobalt Nanoparticles and Single Atoms in Nitroarenes Transfer Hydrogenation
Applied Catalysis B Environment and Energy,
Journal Year:
2024,
Volume and Issue:
unknown, P. 124903 - 124903
Published: Dec. 1, 2024
Language: Английский
Protein–metal ion networks coated carbon matrix as a precursor: to construct carbon-supported Mo-based catalysts with highly exposed active sites for hydrogenation of nitro compounds
Lizhen Lian,
No information about this author
Guangji Zhang,
No information about this author
Xiaojun Zhao
No information about this author
et al.
New Journal of Chemistry,
Journal Year:
2024,
Volume and Issue:
48(18), P. 8331 - 8337
Published: Jan. 1, 2024
Protein–metal
ion
networks
coated
carbon
matrices
were
employed
as
a
precursor
for
preparing
carbon-supported
Mo-based
catalysts
with
highly
exposed
active
sites
nitro
hydrogenation.
Language: Английский