Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 528, P. 216426 - 216426
Published: Jan. 10, 2025
Language: Английский
Citations
6
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 2, 2025
Abstract Catalysis remains a cornerstone of chemical research, with the active sites catalysts being crucial for their functionality. Identifying sites, particularly during reaction process, is elucidating relationship between catalyst's structure and its catalytic property. However, dynamic evolution within heterogeneous metal presents substantial challenge accurately pinpointing real sites. The advent in situ operando characterization techniques has illuminated path toward understanding changes offering robust scientific evidence to support rational design catalysts. There pressing need comprehensive review that systematically explores among single atoms, clusters, nanoparticles as utilizing techniques. This aims delineate effects various factors on nanoparticles. Moreover, several are elaborated emphases tracking linking them properties. Finally, it discusses challenges future perspectives identifying process advancing
Language: Английский
Citations
1
Nano Research, Journal Year: 2025, Volume and Issue: 18(2), P. 94907125 - 94907125
Published: Jan. 7, 2025
Language: Английский
Citations
0
ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1347 - 1356
Published: Feb. 23, 2025
Plasmonic metal/semiconductor hetero-nanostructures have attracted tremendous research interests in optoelectronic devices, photocatalysis and photothermal therapy, related fields. Among various mechanisms of localized surface plasmon resonance (LSPR) induced enhancements, the mechanism LSPR-induced hot carrier injection has emerged as a particularly powerful efficient process for modulating charge dynamics, especially photocatalysis. The efficiency these injections relies on robust metal–semiconductor interfaces, with performance heavily influenced by composition, crystallinity, atomic structure multi-interfaces involved. This letter explores injection, highlighting recent advances emphasis multi-interfacial engineering to optimize dynamics utilization. These interface-regulated processes, combined enhanced photocatalytic performance, provide new opportunities further advanced wide range photoelectric conversion applications.
Language: Английский
Citations
0
Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 7, 2025
Constructing patterned film photoanodes with economizing raw chemicals but enhancing photoelectrochemical (PEC) performance is attractive for practical applications. However, simultaneously optimizing light scattering and interfacial charge transfer through plasmonic enhancement remains challenging. Herein, we developed a novel photoanode featuring Au grids nanometer-thick CdSe layer (Au grid-CdSe) well-organized heterointerfaces, fabricated via facile colloidal topochemical strategy. This design leverages the synergistic coupling between plasmons excitons in heteropatterned films. The underlying serve dual functions: as an electron collector reflector. Their highly ordered Bragg structure effectively scatters incident into ultrathin layer. Furthermore, CdCl2 surface passivation of Au(grid)-CdSe photoanode, based on this unique absorption/reflector architecture, yielded photocurrent density 4.51 mA cm-2, representing significant enhancement. Compared to similarly prepared Au-CdSe heterofilms, passivated films exhibited 2.0-fold higher PEC hydrogen evolution performance, maintained excellent stability over 26 h, reduced consumption by 32%. strategy offers pathway improving semiconductor-based optoelectronic devices.
Language: Английский
Citations
0
Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
Citations
0