Nanoscale Horizons,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
This
review
comprehensively
summarizes
all
available
strategies
for
predicting
phonon
transport
properties
and
explores
how
AI-based
approaches
can
enhance
traditional
methods.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(31), P. 19950 - 20000
Published: July 29, 2024
On
the
basis
of
sustainable
concept,
organic
compounds
and
carbon
materials
both
mainly
composed
light
C
element
have
been
regarded
as
powerful
candidates
for
advanced
electrochemical
energy
storage
(EES)
systems,
due
to
theie
merits
low
cost,
eco-friendliness,
renewability,
structural
versatility.
It
is
investigated
that
carbonyl
functionality
most
common
constituent
part
serves
a
crucial
role,
which
manifests
respective
different
mechanisms
in
various
aspects
EES
systems.
Notably,
systematical
review
about
concept
progress
chemistry
beneficial
ensuring
in-depth
comprehending
functionality.
Hence,
comprehensive
has
summarized
based
on
state-of-the-art
developments.
Moreover,
working
principles
fundamental
properties
unit
discussed,
generalized
three
aspects,
including
redox
activity,
interaction
effect,
compensation
characteristic.
Meanwhile,
pivotal
characterization
technologies
also
illustrated
purposefully
studying
related
structure,
mechanism,
performance
profitably
understand
chemistry.
Finally,
current
challenges
promising
directions
are
concluded,
aiming
afford
significant
guidance
optimal
utilization
moiety
propel
practicality
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(40)
Published: July 19, 2024
Abstract
As
the
“star
of
hope”
for
next‐generation
high‐energy‐density
batteries,
lithium–sulfur
batteries
(Li–S
batteries)
face
severe
challenges
such
as
reserves,
costs,
and
safety,
which
seriously
restrict
their
practical
application.
Alternatively,
research
on
multivalent
metals
(e.g.,
Mg,
Ca,
Al,
Zn,
etc.)
anodes,
characterized
by
less
reactivity
higher
natural
abundance,
is
gaining
increasing
attention
urgent
demand.
However,
metal–sulfur
(M–S)
battery
technology
based
metal
anodes
still
in
its
infancy
not
yet
mature
This
review
provides
insights
into
prospects
M–S
covering
fundamental
mechanisms,
key
issues,
response
strategies,
latest
advancements
flexible/micro
energy
storage
devices.
Furthermore,
a
general
perspective
future
directions
are
also
presented
this
review.
aims
to
explore
opportunities
emerging
support
development
systems.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(41)
Published: Aug. 16, 2024
Abstract
Heterogeneous
single‐metal‐site
catalysts
(SMSCs),
often
referred
to
as
single‐atom
(SACs),
demonstrate
promising
catalytic
activity,
selectivity,
and
stability
across
a
wide
spectrum
of
reactions
due
their
rationally
designed
microenvironments
encompassing
coordination
geometry,
binding
ligands,
electronic
configurations.
However,
the
inherent
disorderliness
SMSCs
at
both
atomic
scale
nanoscale
poses
challenges
in
deciphering
working
principles
establishing
correlations
between
performances
SMSCs.
The
rearrangement
randomly
dispersed
single
metals
into
homogeneous
atomic‐precisely
structured
periodic
single‐metal
site
(PSMSCs)
not
only
simplifies
chaos
systems
but
also
unveils
new
opportunities
for
manipulating
performance
gaining
profound
insights
reaction
mechanisms.
Moreover,
synergistic
effects
adjacent
integration
arrangement
further
broaden
industrial
application
scope
This
perspective
offers
comprehensive
overview
recent
advancements
outlines
prospective
avenues
research
design
characterizations
PSMSCs,
while
acknowledging
formidable
encountered
prospects
that
lie
ahead.
Energy & Fuels,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 9, 2025
Most
nonaqueous
redox
flow
batteries
(RFBs)
encounter
the
issue
of
irreversible
capacity
loss
due
to
crossover
redox-active
materials.
To
mitigate
this,
an
innovative
approach
is
construct
symmetric
RFBs
with
bipolar
molecules
(BRMs).
Merging
established
p-
and
n-type
moieties
within
a
single
molecule
through
fused
conjugation
has
proven
be
practical
effective
strategy
for
preparation
BRMs.
Nonetheless,
this
presents
significant
challenges,
primarily
involving
destabilization
intermediates
caused
by
direct
excessive
electronic
perturbation
as
well
inherently
deleterious
interactions
between
two
types
centers.
This
study
proposes
robust
design
BRMs
that
incorporate
additional
same
conjugated
structure
enhance
stability.
As
demonstrator,
we
designed
synthesized
novel
class
BRMs,
merging
sets
pyrrolic
nitrogen
ketone
moieties.
The
potential
efficacy
these
were
evaluated
in
static
cells
proof
concept.
A
cell
based
on
one
achieves
voltage
2.6
V
demonstrates
satisfactory
Coulombic
energy
efficiencies
retention
over
long-term
charge–discharge
cycles.
Our
provides
structures
developing
high-performance