(Hf)PCN-224(Co) as an efficient ppm-level sensor for toxic SO2 DOI
Sergio Carrasco, Marcela Martı́nez, Yoarhy A. Amador‐Sánchez

et al.

Materials Today Advances, Journal Year: 2025, Volume and Issue: 26, P. 100579 - 100579

Published: May 2, 2025

Language: Английский

Unraveling the Plasmonic Effect of Au in Promoting Photocatalytic H2 Generation and Organic Synthesis DOI Creative Commons

Wenyao Cheng,

Lele Wang,

Hongxin Lao

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(46), P. 17026 - 17034

Published: Nov. 7, 2024

Incorporating plasmonic nanostructures into photocatalysts significantly enhances catalytic efficiency due to effects. In this study, we successfully developed a heterojunction between organic semiconductor zinc porphyrin (Zn-TCPP) and colloidal gold (Au) nanoparticles connected via Au–O bonds. The formation of bonds Zn-TCPP Au facilitates charge transfer by reducing the Schottky barrier at interface. Finite-difference time-domain simulations, in situ XPS measurements, infrared thermal imaging confirm that strong localized surface plasmon resonance effect local electric field photothermal effect, promoting separation electron–hole pairs Zn-TCPP/Au sample improving reaction kinetics. optimal Zn-TCPP/Au-2% composite demonstrates an impressive H2 generation rate 1610 μmol·g–1·h–1, which is 2.7 8.6 times greater than TCPP samples, respectively. Additionally, shows high C–N coupling benzylamine imine, achieving yield 45.1 mmol·g–1 24 h. This study provides comprehensive understanding how activity photocatalysts.

Language: Английский

Citations

9
Boosted charge separation in porphyrin-based MOFs/CdS photocatalyst via interfacial −N−Cd− bridge bond construction DOI
Jing Xu,

Wenyao Cheng,

Xubing Liang

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1003, P. 175610 - 175610

Published: July 17, 2024

Language: Английский

Citations

4
Charge Transfer of Acridine Based Hybrid Metal Halide for Light-Emitting Diode DOI

Xin-Ya Zhang,

Pei-Pei Yin,

Shu-Yao Yang

et al.

Published: Jan. 1, 2025

The development of charge transfer materials have been extensively studied in recent years owing to their potential applications the field photodetector, photocatalytic and solid-state lighting. Herein, assembly acridine (AD) organic cations [ZnCl4]2- anions afforded one organic–inorganic hybrid complex [(AD)2(ZnCl4)] (1), which can be facilely synthesized ethanol solution at room temperature for a few minutes. alternately arranged AD cation π-conjugated chains inorganic anion tetrahedrons enable this characteristic. It shows bright green light emission with long lifetime 16.31 ns quantum yield 53%. Theoretical calculations provided detailed energy level, band gap distribution information 1, further certified its behavior. Successful fabrication light-emitting diode (LED) device making perfect candidate lighting material.

Language: Английский

Citations

0
Recent Advances in Transition Metal‐Based Metal‐Organic Frameworks for Hydrogen Production DOI Creative Commons
Ting Yang, Hua Zhang, Bo Pang

et al.

Small Science, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 17, 2025

The escalating global energy demand and the imperative to mitigate carbon emissions have intensified pursuit for sustainable solutions, with hydrogen emerging as a pivotal clean carrier. Transition metal‐based metal‐organic frameworks (MOFs) garnered significant attention their potential in efficient production due high surface area, tunable porosity, versatile catalytic properties. Despite notable advancements MOF synthesis, critical challenges related stability, electrical conductivity, scalability continue hinder widespread application. This review provides comprehensive analysis of recent progress design synthesis transition MOFs, emphasizing role electrocatalytic photocatalytic production. Key synthetic strategies influence on performance are systematically discussed, alongside identification existing limitations knowledge gaps. By highlighting these areas proposing pathways future research, this aims accelerate practical integration MOFs into economy.

Language: Английский

Citations

0
Charge transfer of acridine based hybrid metal halide for light-emitting diode DOI

Xin-Ya Zhang,

Pei-Pei Yin,

Shu-Yao Yang

et al.

Journal of Solid State Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 125292 - 125292

Published: Feb. 1, 2025

Language: Английский

Citations

0
Review on the synthesis, construction and photocatalytic applications of double-ligand MOFs DOI
Haixia Tong,

Ai‐Xin Zhu,

Gao Chen

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161068 - 161068

Published: Feb. 1, 2025

Language: Английский

Citations

0
Copper-doped metal–organic framework-74 solid-state electrolytes for high performance all-solid-state sodium metal batteries DOI
Hao Zhang, Zhiyuan Zhou,

Xinyao Sun

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 689, P. 137241 - 137241

Published: March 4, 2025

Language: Английский

Citations

0
Regulated synthesis of 3D Mn2O3 hollow microspheres derived from Mn-BTC for concentrating solar-driven photothermal ethyl acetate oxidation DOI

Zichao Chen,

Jiaxi Zheng,

Shengmei Huang

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116679 - 116679

Published: April 1, 2025

Language: Английский

Citations

0
MOFs as platforms for multiscale structural regulation: new frontiers in photocatalyst design DOI Open Access
Jianqiao Liu,

Zili Gong,

Di Wu

et al.

Microstructures, Journal Year: 2025, Volume and Issue: 5(3)

Published: April 25, 2025

Photocatalysis plays a pivotal role in sustainable technology, driving pollutant degradation and energy conversion through solar-driven chemical reactions. However, conventional photocatalysts are limited by their structural tunability, hindering adaptability to evolving photocatalytic applications. This underscores the urgent need for innovative approaches overcome these challenges. Metal-organic frameworks (MOFs), with tunable structures, offer promising solution overcoming limitations. Here, we demonstrate comprehensive overview of regulation strategies MOFs, emphasizing evolution across multiple scales enhance performance. review begins detailing photoelectric characteristics MOFs development effectiveness. An in-depth analysis is undertaken into - macroscale, mesoscale, atomic-scale, electronic-scale. The synergistic interactions among levels further explored, revealing collective contribution improved efficiency. These insights emphasize that adaptable design serve as pathways advancements photocatalyst engineering. Finally, examine current applications structures provide perspectives on future challenges this field. offers critical MOF regulation, highlighting its innovations expanding technologies.

Language: Английский

Citations

0
(Hf)PCN-224(Co) as an efficient ppm-level sensor for toxic SO2 DOI
Sergio Carrasco, Marcela Martı́nez, Yoarhy A. Amador‐Sánchez

et al.

Materials Today Advances, Journal Year: 2025, Volume and Issue: 26, P. 100579 - 100579

Published: May 2, 2025

Language: Английский

Citations

0