Catalytic Application of Biochar Functionalized Copper-l-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines DOI Creative Commons

Mahrokh Farrokh,

Maryam Hajjami, Mohammad Ali Zolfigol

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47811 - 47821

Published: Nov. 19, 2024

In our study, we aimed to use olive pomace, food industry waste, as biomass produce biochar nanoparticles. The surface of the was functionalized with l-histidine ligand, and then cupric acetate added prepare Cu-l-histidine@biochar a final catalyst for chemo- homoselective synthesis amide aniline derivatives. To characterize novel catalyst, employed various techniques. Another notable feature this is its reusability, which maintained significant efficiency even after multiple uses in reactions.

Language: Английский

A novel Cu complex coated on hercynite magnetic nanoparticles as an efficient and recoverable nanocatalyst for the selective synthesis of tetrazoles DOI

Motahare Ghasemirad,

Masoomeh Norouzi, Parisa Moradi

et al.

Journal of Nanoparticle Research, Journal Year: 2024, Volume and Issue: 26(1)

Published: Jan. 1, 2024

Language: Английский

Citations

13
Multidentate copper complex on magnetic biochar nanoparticles as a practical and recoverable nanocatalyst for the selective synthesis of tetrazole derivatives DOI Creative Commons

Marwan Majeed Maseer,

Tavan Kikhavani, Bahman Tahmasbi

et al.

Nanoscale Advances, Journal Year: 2024, Volume and Issue: 6(15), P. 3948 - 3960

Published: Jan. 1, 2024

Waste recycling, novel and easy methods of recycling catalysts, use green solvents, selective catalysts preventing the production by-products are most important principles chemistry modern technology. Therefore, in this work, biochar nanoparticles (B-NPs) were synthesized by pyrolysis chicken manure as a method for waste recycling. Subsequently, B-NPs magnetized Fe(0) to improve recovery biochar. Then, surface magnetic (FeB-MNPs) was modified (3-chloropropyl)trimethoxysilane (3Cl-PTMS). Finally, multidentate copper complex 2,2'-(propane-1,3-diylbis(oxy))dianiline (P.bis(OA)) immobilized on FeB-MNPs, which labeled Cu-P.bis(OA)@FeB-MNPs. Cu-P.bis(OA)@FeB-MNPs investigated commercial, homoselective, practical, recyclable nanocatalyst synthesis 5-substituted-1

Language: Английский

Citations

12
Advances of carbon-based materials for activating peracetic acid in advanced oxidation processes: A review DOI
Chenghuan Qiao, Wenrui Jia,

J. Tang

et al.

Environmental Research, Journal Year: 2024, Volume and Issue: 263, P. 120058 - 120058

Published: Sept. 24, 2024

Language: Английский

Citations

6
Construction of novel Mg Fe2O4/MgO composite: A high performer Photocatalyst for the cyclization of 1,3,4-oxadiazoles under Sunlight Irradiation DOI
Md. Afroz Bakht, Abdulrahman I. Alharthi, Mshari A. Alotaibi

et al.

Journal of the Indian Chemical Society, Journal Year: 2025, Volume and Issue: unknown, P. 101688 - 101688

Published: March 1, 2025

Language: Английский

Citations

0
Synthesis and Characterization of Fe3O4@L‐Arginine Magnetic Nanocatalyst Immobilized on Nickel Oxide for One‐Pot Ultrasound‐Assisted Synthesis of 3,4‐Dihydropyrimidin‐2(1H)‐ones DOI
Shinichiro Fuse, Somnath C. Dhawale,

Akash K. Tapre

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(14)

Published: April 1, 2025

Abstract In this work, we synthesized a heterogeneous magnetic nanocatalyst using iron oxide (Fe 3 O 4 ) surface‐modified with L‐arginine@NiO @L‐Arg@NiO). Several characterization techniques such as fourier transform infrared (FT‐IR), field emission scanning electron microscopy (FE‐SEM), X‐ray diffraction (XRD), high‐resolution transmission (HR‐TEM), dispersion spectra (EDS) and thermogravimetric analysis (TGA) were used to extensively analyze its structural morphological properties. The Fe @L‐Arg@NiO was subjected the one‐pot multi‐component synthesis of 3,4‐dihydropyrimidin‐2‐(1 H )‐ones derivatives under solvent‐free conditions. It determined that demonstrating desired product 85%–95% yield, in shorter reaction time. Furthermore, simple work‐up, reusability catalyst up five cycles sustainability are characteristic features environment friendly protocol.

Language: Английский

Citations

0
Catalytic Application of Biochar Functionalized Copper-l-histidine for the Chemo and Homoselective Conversion of Cyanides to Amides and Reduction of Nitroarenes to anilines DOI Creative Commons

Mahrokh Farrokh,

Maryam Hajjami, Mohammad Ali Zolfigol

et al.

ACS Omega, Journal Year: 2024, Volume and Issue: 9(48), P. 47811 - 47821

Published: Nov. 19, 2024

In our study, we aimed to use olive pomace, food industry waste, as biomass produce biochar nanoparticles. The surface of the was functionalized with l-histidine ligand, and then cupric acetate added prepare Cu-l-histidine@biochar a final catalyst for chemo- homoselective synthesis amide aniline derivatives. To characterize novel catalyst, employed various techniques. Another notable feature this is its reusability, which maintained significant efficiency even after multiple uses in reactions.

Language: Английский

Citations

1