Energy & Environmental Science,
Journal Year:
2024,
Volume and Issue:
17(12), P. 4090 - 4103
Published: Jan. 1, 2024
The
major
challenges
of
vanadium-based
layered
materials
are
their
dissolution
tendency
and
the
instability
bulk-phase
structure,
resulting
in
unsatisfactory
cyclability,
particularly
at
lower
current
densities.
Nano-Micro Letters,
Journal Year:
2021,
Volume and Issue:
14(1)
Published: Dec. 2, 2021
Due
to
their
high
safety
and
low
cost,
rechargeable
aqueous
Zn-ion
batteries
(RAZIBs)
have
been
receiving
increased
attention
are
expected
be
the
next
generation
of
energy
storage
systems.
However,
metal
Zn
anodes
exhibit
a
limited-service
life
inferior
reversibility
owing
issues
dendrites
side
reactions,
which
severely
hinder
further
development
RAZIBs.
Researchers
attempted
design
high-performance
by
interfacial
engineering,
including
surface
modification
addition
electrolyte
additives,
stabilize
anodes.
The
purpose
is
achieve
uniform
nucleation
flat
deposition
regulating
behavior
ions,
effectively
improves
cycling
stability
anode.
This
review
comprehensively
summarizes
reaction
mechanisms
for
inhibiting
growth
occurrence
reactions.
In
addition,
research
progress
engineering
strategies
RAZIBs
summarized
classified.
Finally,
prospects
suggestions
provided
highly
reversible
ACS Nano,
Journal Year:
2022,
Volume and Issue:
16(3), P. 4588 - 4598
Published: March 8, 2022
Vanadium-based
materials
have
been
extensively
studied
as
promising
cathode
for
zinc-ion
batteries
because
of
their
multiple
valences
and
adjustable
ion-diffusion
channels.
However,
the
sluggish
kinetics
Zn-ion
intercalation
less
stable
layered
structure
remain
bottlenecks
that
limit
further
development.
The
present
work
introduces
potassium
ions
to
partially
substitute
ammonium
in
vanadate,
leading
a
subtle
shrinkage
lattice
distance
increased
oxygen
vacancies.
resulting
vanadate
exhibits
high
discharge
capacity
(464
mAh
g-1
at
0.1
A
g-1)
excellent
cycling
stability
(90%
retention
over
3000
cycles
5
g-1).
electrochemical
properties
battery
performances
are
attributed
rich
introduction
K+
replace
NH4+
appears
alleviate
irreversible
deammoniation
prevent
structural
collapse
during
ion
insertion/extraction.
Density
functional
theory
calculations
show
has
modulated
electron
better
diffusion
path
with
lower
migration
barrier.
Advanced Energy Materials,
Journal Year:
2022,
Volume and Issue:
12(40)
Published: Aug. 26, 2022
Abstract
Aqueous
zinc–ion
batteries
(ZIBs)
have
been
promptly
developed
as
a
competitive
and
promising
system
for
future
large‐scale
energy
storage.
In
recent
years,
vanadium
(V)‐based
compounds,
with
diversity
of
valences
high
electrochemical‐activity,
widely
studied
cathodes
aqueous
ZIBs
because
their
rich
reserves
theoretical
capacity.
However,
the
stubborn
issues
including
low
conductivity
sluggish
kinetics,
plague
smooth
application
in
ZIBs.
Among
various
countermeasures,
defect
engineering
is
believed
an
effective
method
to
alleviate
above
limitations.
This
review
highlights
challenges
different
V‐based
cathode
materials
(e.g.,
oxides
vanadates)
summarizes
advances
strategies
types
effects
defects,
designed
strategies,
characterization
techniques
high‐energy
Finally,
several
sound
prospects
this
fervent
field
are
also
rationally
proposed
fundamental
research
practical
application.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(12)
Published: Jan. 22, 2023
Aqueous
zinc-ion
batteries
(AZIBs)
stand
out
among
many
monovalent/multivalent
metal-ion
as
promising
new
energy
storage
devices
because
of
their
good
safety,
low
cost,
and
environmental
friendliness.
Nevertheless,
there
are
still
great
challenges
to
exploring
new-type
cathode
materials
that
suitable
for
Zn
Nano-Micro Letters,
Journal Year:
2021,
Volume and Issue:
14(1)
Published: Dec. 2, 2021
High-energy-density
lithium-ion
batteries
(LIBs)
that
can
be
safely
fast-charged
are
desirable
for
electric
vehicles.
However,
sub-optimal
lithiation
potential
and
low
capacity
of
commonly
used
LIBs
anode
cause
safety
issues
energy
density.
Here
we
hypothesize
a
cobalt
vanadate
oxide,
Co2VO4,
attractive
material
fast-charging
due
to
its
high
(~
1000
mAh
g-1)
safe
0.65
V
vs.
Li+/Li).
The
Li+
diffusion
coefficient
Co2VO4
is
evaluated
by
theoretical
calculation
as
3.15
×
10-10
cm2
s-1,
proving
promising
in
LIBs.
A
hexagonal
porous
nanodisk
(PCVO
ND)
structure
designed
accordingly,
featuring
specific
surface
area
74.57
m2
g-1
numerous
pores
with
pore
size
14
nm.
This
unique
succeeds
enhancing
electron
transfer,
leading
superior
performance
than
current
commercial
anodes.
As
result,
the
PCVO
ND
shows
initial
reversible
911.0
at
0.4
C,
excellent
(344.3
10
C
cycles),
outstanding
long-term
cycling
stability
(only
0.024%
loss
per
cycle
confirming
feasibility