Bulk-to-surface co-modification of layered hydrated vanadate cathode for aqueous zinc ion batteries DOI
Chen Zhang, Yan Huang, Xueer Xu

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(12), P. 4090 - 4103

Published: Jan. 1, 2024

The major challenges of vanadium-based layered materials are their dissolution tendency and the instability bulk-phase structure, resulting in unsatisfactory cyclability, particularly at lower current densities.

Language: Английский

Interfacial Engineering Strategy for High-Performance Zn Metal Anodes DOI Creative Commons
Bin Li,

Xiaotan Zhang,

Tingting Wang

et al.

Nano-Micro Letters, Journal Year: 2021, Volume and Issue: 14(1)

Published: Dec. 2, 2021

Due to their high safety and low cost, rechargeable aqueous Zn-ion batteries (RAZIBs) have been receiving increased attention are expected be the next generation of energy storage systems. However, metal Zn anodes exhibit a limited-service life inferior reversibility owing issues dendrites side reactions, which severely hinder further development RAZIBs. Researchers attempted design high-performance by interfacial engineering, including surface modification addition electrolyte additives, stabilize anodes. The purpose is achieve uniform nucleation flat deposition regulating behavior ions, effectively improves cycling stability anode. This review comprehensively summarizes reaction mechanisms for inhibiting growth occurrence reactions. In addition, research progress engineering strategies RAZIBs summarized classified. Finally, prospects suggestions provided highly reversible

Language: Английский

Citations

289

Potassium Ammonium Vanadate with Rich Oxygen Vacancies for Fast and Highly Stable Zn-Ion Storage DOI
Quan Zong, Qianqian Wang, Chaofeng Liu

et al.

ACS Nano, Journal Year: 2022, Volume and Issue: 16(3), P. 4588 - 4598

Published: March 8, 2022

Vanadium-based materials have been extensively studied as promising cathode for zinc-ion batteries because of their multiple valences and adjustable ion-diffusion channels. However, the sluggish kinetics Zn-ion intercalation less stable layered structure remain bottlenecks that limit further development. The present work introduces potassium ions to partially substitute ammonium in vanadate, leading a subtle shrinkage lattice distance increased oxygen vacancies. resulting vanadate exhibits high discharge capacity (464 mAh g-1 at 0.1 A g-1) excellent cycling stability (90% retention over 3000 cycles 5 g-1). electrochemical properties battery performances are attributed rich introduction K+ replace NH4+ appears alleviate irreversible deammoniation prevent structural collapse during ion insertion/extraction. Density functional theory calculations show has modulated electron better diffusion path with lower migration barrier.

Language: Английский

Citations

216

Vanadium-based cathodes for aqueous zinc-ion batteries: Mechanism, design strategies and challenges DOI
Xiudong Chen, Hang Zhang,

Jin‐Hang Liu

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 50, P. 21 - 46

Published: May 1, 2022

Language: Английский

Citations

187

Cathode materials for aqueous zinc-ion batteries: A mini review DOI
Tao Zhou,

Limin Zhu,

Lingling Xie

et al.

Journal of Colloid and Interface Science, Journal Year: 2021, Volume and Issue: 605, P. 828 - 850

Published: July 31, 2021

Language: Английский

Citations

169

Advances on Defect Engineering of Vanadium‐Based Compounds for High‐Energy Aqueous Zinc–Ion Batteries DOI
Cong Guo,

Shanjun Yi,

Rui Si

et al.

Advanced Energy Materials, Journal Year: 2022, Volume and Issue: 12(40)

Published: Aug. 26, 2022

Abstract Aqueous zinc–ion batteries (ZIBs) have been promptly developed as a competitive and promising system for future large‐scale energy storage. In recent years, vanadium (V)‐based compounds, with diversity of valences high electrochemical‐activity, widely studied cathodes aqueous ZIBs because their rich reserves theoretical capacity. However, the stubborn issues including low conductivity sluggish kinetics, plague smooth application in ZIBs. Among various countermeasures, defect engineering is believed an effective method to alleviate above limitations. This review highlights challenges different V‐based cathode materials (e.g., oxides vanadates) summarizes advances strategies types effects defects, designed strategies, characterization techniques high‐energy Finally, several sound prospects this fervent field are also rationally proposed fundamental research practical application.

Language: Английский

Citations

164

How About Vanadium‐Based Compounds as Cathode Materials for Aqueous Zinc Ion Batteries? DOI Creative Commons
Tingting Lv, Yi Peng, Guangxun Zhang

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(12)

Published: Jan. 22, 2023

Aqueous zinc-ion batteries (AZIBs) stand out among many monovalent/multivalent metal-ion as promising new energy storage devices because of their good safety, low cost, and environmental friendliness. Nevertheless, there are still great challenges to exploring new-type cathode materials that suitable for Zn

Language: Английский

Citations

162

Rational design of ZnMn2O4 nanoparticles on carbon nanotubes for high-rate and durable aqueous zinc-ion batteries DOI
Fei Gao, Bing Mei,

Xiangyu Xu

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 448, P. 137742 - 137742

Published: June 23, 2022

Language: Английский

Citations

156

Porous Co2VO4 Nanodisk as a High-Energy and Fast-Charging Anode for Lithium-Ion Batteries DOI Creative Commons

Jinghui Ren,

Zhenyu Wang, Peng Xu

et al.

Nano-Micro Letters, Journal Year: 2021, Volume and Issue: 14(1)

Published: Dec. 2, 2021

High-energy-density lithium-ion batteries (LIBs) that can be safely fast-charged are desirable for electric vehicles. However, sub-optimal lithiation potential and low capacity of commonly used LIBs anode cause safety issues energy density. Here we hypothesize a cobalt vanadate oxide, Co2VO4, attractive material fast-charging due to its high (~ 1000 mAh g-1) safe 0.65 V vs. Li+/Li). The Li+ diffusion coefficient Co2VO4 is evaluated by theoretical calculation as 3.15 × 10-10 cm2 s-1, proving promising in LIBs. A hexagonal porous nanodisk (PCVO ND) structure designed accordingly, featuring specific surface area 74.57 m2 g-1 numerous pores with pore size 14 nm. This unique succeeds enhancing electron transfer, leading superior performance than current commercial anodes. As result, the PCVO ND shows initial reversible 911.0 at 0.4 C, excellent (344.3 10 C cycles), outstanding long-term cycling stability (only 0.024% loss per cycle confirming feasibility

Language: Английский

Citations

134

Ion migration and defect effect of electrode materials in multivalent-ion batteries DOI
Zhexuan Liu,

Liping Qin,

Xinxin Cao

et al.

Progress in Materials Science, Journal Year: 2021, Volume and Issue: 125, P. 100911 - 100911

Published: Dec. 2, 2021

Language: Английский

Citations

114

Suppressing vanadium dissolution by modulating aqueous electrolyte structure for ultralong lifespan zinc ion batteries at low current density DOI
Sucheng Liu,

Jiangfeng He,

Dao‐Sheng Liu

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 49, P. 93 - 101

Published: March 25, 2022

Language: Английский

Citations

99