Electrochemistry Enabled Heterostructure with High Tap Density for Ultrahigh Power Na‐Ion Capacitors DOI Open Access

Jieming Cai,

Linsong Wang,

Shusheng Tao

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(44)

Published: Oct. 3, 2023

Abstract Developing electrode materials with high tap density, low cost, and superior performance poses a formidable challenge in electrochemistry. The impressive exhibited by most electrodes comes at the expense of density severely limiting their practical applications. Here, combining computational experimental results, an approach for rich heterostructure (Cu 2 S/Na S n ) from cheap copper smelting slag enabled electrochemical process is proposed, reducing diffusion energy barrier 0.82 to 0.28 eV Na + , as well delivering impressively 3.32 g cm −3 . Furthermore, activation that irreversibly generates more stable Cu after first charge progress parent also revealed in/ex situ analytical techniques. As expected, assembled sodium ion capacitors (SICs) achieve (74.4 Wh kg −1 power (20 000 W outstanding capacity retention 81.5% 10 cycles, over 76% its 13.4 s, which surpasses achieved state‐of‐the‐art SICs. This work not only provides novel insights into conversion‐type anodes but introduces method efficient value‐added utilization slag.

Language: Английский

Strongly Coupled Interfacial Engineering Inspired by Robotic Arms Enable High‐Performance Sodium‐Ion Capacitors DOI

Zirui Song,

Guiyu Zhang,

Xinglan Deng

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(38)

Published: July 7, 2022

Abstract Interfacial coupling strategy has allured extensive attention for the possibility to endow active electrode materials with superior performance. However, design of strong engineering interfacial evolution during electrochemical processes is very challenging. Herein, inspired by powerful robotic arms and density functional theory calculations, multiple groups identified intense affinity V atom are successfully grafted on carbon nanotubes (CNTs), thereby in situ building robust bonds (VOC VC) tightly anchor VS 4 particles. The largely decreased band gaps energy barriers show fortified conductivity ‐CNT heterostructure. Besides, spacial confinement effect induced linkages substantively enhances mechanical properties inhibit structural collapse, restrains dissolution polysulfides as verified molecular dynamics simulations, thus prolonging life span. Excellent 105.5 Wh kg –1 can be delivered after assembling full sodium‐ion capacitors (activated carbon//VS ‐CNT). Significantly, reversible confirmed various ex characteristics discharge/charge hold key remarkable sodium storage ability prominent initial coulombic efficiency. More impressively, establish synergistic soft‐rigid integrated solid‐electrolyte interphase film, which conducive elevating performance electrodes, convincingly constructing advanced capacitors.

Language: Английский

Citations

131
Metal–Organic Framework Materials for Electrochemical Supercapacitors DOI Creative Commons
Ziwei Cao, Roya Momen,

Shusheng Tao

et al.

Nano-Micro Letters, Journal Year: 2022, Volume and Issue: 14(1)

Published: Sept. 1, 2022

Abstract Exploring new materials with high stability and capacity is full of challenges in sustainable energy conversion storage systems. Metal–organic frameworks (MOFs), as a type porous material, show the advantages large specific surface area, porosity, low density, adjustable pore size, exhibiting broad application prospect field electrocatalytic reactions, batteries, particularly supercapacitors. This comprehensive review outlines recent progress synthetic methods electrochemical performances MOF materials, well their applications Additionally, superiorities MOFs-related are highlighted, while major or opportunities for future research on them supercapacitors have been discussed displayed, along extensive experimental experiences.

Language: Английский

Citations

128
Progress of synthetic strategies and properties of heteroatoms-doped (N, P, S, O) carbon materials for supercapacitors DOI

Yufei Zheng,

Kongmei Chen,

Kunpeng Jiang

et al.

Journal of Energy Storage, Journal Year: 2022, Volume and Issue: 56, P. 105995 - 105995

Published: Nov. 7, 2022

Language: Английский

Citations

117
Reversible Oxygen-Rich Functional Groups Grafted 3D Honeycomb-Like Carbon Anode for Super-Long Potassium Ion Batteries DOI Creative Commons
Na Cheng, Wang Zhou, Jilei Liu

et al.

Nano-Micro Letters, Journal Year: 2022, Volume and Issue: 14(1)

Published: July 21, 2022

Studies have found that oxygen-rich-containing functional groups in carbon-based materials can be used as active sites for the storage performance of K+, but basic mechanism is still unclear. Herein, we construct and optimize 3D honeycomb-like carbon grafted with plentiful COOH/C = O (OFGC) anodes potassium ion batteries. The OFGC electrode steady structure rich effectively contribute to capacity enhancement formation stable solid electrolyte interphase (SEI) film, achieving a high reversible 230 mAh g-1 at 3000 mA after 10,000 cycles (almost no decay) an ultra-long cycle time over 18 months 100 g-1. study results revealed between K+ by forming C-O-K compounds. Meanwhile, situ electrochemical impedance spectroscopy proved highly rapid de/intercalation kinetics electrode, growth process SEI films. In particular, full cells assembled Prussian blue cathode exhibit energy density 113 Wh kg-1 800 (calculated total mass anode cathode), get light-emitting diodes lamp ear thermometer running.

Language: Английский

Citations

100
Natural Stibnite for Lithium-/Sodium-Ion Batteries: Carbon Dots Evoked High Initial Coulombic Efficiency DOI Creative Commons

Yinger Xiang,

Laiqiang Xu, Yang Li

et al.

Nano-Micro Letters, Journal Year: 2022, Volume and Issue: 14(1)

Published: June 17, 2022

The chemical process of local oxidation-partial reduction-deep coupling for stibnite reduction carbon dots (CDs) is revealed by in-situ high-temperature X-ray diffraction. Sb2S3@xCDs anode delivers high initial coulombic efficiency in lithium ion batteries (85.2%) and sodium (82.9%), respectively. C-S bond influenced oxygen-rich matrix can restrain the conversion sulfur to sulfite, well confirmed photoelectron spectroscopy characterization solid electrolyte interphase layers helped with density functional theory calculations. CDs-induced Sb-O-C proved effectively regulate interfacial electronic structure. application Sb2S3 marvelous theoretical capacity alkali metal-ion seriously limited its poor electrical conductivity low (ICE). In this work, natural modified (Sb2S3@xCDs) elaborately designed ICE. Greatly, processes CDs are clearly demonstrated, situ More impressively, ICE lithium-ion (LIBs) enhanced 85%, through effect on bonds which inhibit supported Not than less, it found that existed interface promote expedite transmission reducing bandgap restraining slip dislocation. As a result, optimal sample tremendous reversible 660 mAh g-1 LIBs at current rate 5 A g-1. This work provides new methodology enhancing electrochemical energy storage performance metal sulfides, especially improving

Language: Английский

Citations

81
Insight into the self-discharge suppression of electrochemical capacitors: Progress and challenges DOI Creative Commons

Wenxu Shang,

Wentao Yu, Xu Xiao

et al.

Advanced Powder Materials, Journal Year: 2022, Volume and Issue: 2(1), P. 100075 - 100075

Published: July 31, 2022

The ever-growing demands for renewable energy sources motivate the development of storage systems. Among them, supercapacitors are received increasing attention due to their high power density, long cycle life, fast recharge rate, and almost no maintenance. Nevertheless, application is hindered by severe self-discharge behaviors, especially in wearable devices. In recent years, tremendous excellent works have been reported conquer this shortcoming through various creative strategies. Herein, we gives a timely spotlight on breakthroughs mechanism investigations corresponding suppression mechanisms were introduced first, followed summary strategies from materials (i.e., electrode, electrolyte, separator) system protocol optimization, furthermore, connection between existing issues, possible directions future research discussed.

Language: Английский

Citations

78
Carbonyl Chemistry for Advanced Electrochemical Energy Storage Systems DOI
Kang‐Yu Zou, Wentao Deng, Debbie S. Silvester

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(31), P. 19950 - 20000

Published: July 29, 2024

On the basis of sustainable concept, organic compounds and carbon materials both mainly composed light C element have been regarded as powerful candidates for advanced electrochemical energy storage (EES) systems, due to theie merits low cost, eco-friendliness, renewability, structural versatility. It is investigated that carbonyl functionality most common constituent part serves a crucial role, which manifests respective different mechanisms in various aspects EES systems. Notably, systematical review about concept progress chemistry beneficial ensuring in-depth comprehending functionality. Hence, comprehensive has summarized based on state-of-the-art developments. Moreover, working principles fundamental properties unit discussed, generalized three aspects, including redox activity, interaction effect, compensation characteristic. Meanwhile, pivotal characterization technologies also illustrated purposefully studying related structure, mechanism, performance profitably understand chemistry. Finally, current challenges promising directions are concluded, aiming afford significant guidance optimal utilization moiety propel practicality

Language: Английский

Citations

33
Biomass-Derived Hard Carbon for Sodium-Ion Batteries: Basic Research and Industrial Application DOI

Biao Zhong,

Chang Liu,

Dengyi Xiong

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(26), P. 16468 - 16488

Published: June 20, 2024

Sodium-ion batteries (SIBs) have significant potential for applications in portable electric vehicles and intermittent renewable energy storage due to their relatively low cost. Currently, hard carbon (HC) materials are considered commercially viable anode SIBs advantages, including larger capacity, cost, operating voltage, inimitable microstructure. Among these materials, biomass-derived anodes commonly used SIBs. However, the reports about biomass from basic research industrial very rare. In this paper, we focus on progress of following perspectives: (1) sodium mechanisms carbon; (2) optimization strategies encompassing design, synthesis, heteroatom doping, material compounding, electrolyte modulation, presodiation; (3) classification different based precursor source, a comparison properties, discussion effects sources properties; (4) challenges practical SIBs; (5) an overview current industrialization anodes. Finally, present challenges, strategies, prospects future development materials.

Language: Английский

Citations

32
Lignin derived hard carbon for sodium ion batteries: Recent advances and future perspectives DOI
Ao Wang, Gaoyue Zhang, Meng Li

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101452 - 101452

Published: Feb. 1, 2025

Language: Английский

Citations

2
Carbon-Based Materials for Supercapacitors: Recent Progress, Challenges and Barriers DOI Creative Commons
A.G. Olabi, Qaisar Abbas, Mohammad Ali Abdelkareem

et al.

Batteries, Journal Year: 2022, Volume and Issue: 9(1), P. 19 - 19

Published: Dec. 27, 2022

Swift developments in electronic devices and future transportation/energy production directions have forced researchers to develop new contemporary with higher power capacities, extended cycle lives, superior energy densities. Supercapacitors are promising excellent densities exceptionally long lives. However, commercially available supercapacitors, which commonly use high-surface-area carbon-based electrodes organic solutions as electrolytes, suffer from inferior due the limited accessibility of surface area constrained operating potential window electrolytes. To address issue densities, high-capacity electrode materials new/state-of-the-art such ionic liquids, gel polymers, or even solid-state been developed evaluated vigorously recent years. In this brief review, different types according their charge storage mechanisms, discussed detail. Since active key focus synthesis parameters, carbonisation, activation, functionalisation, can impact a material’s physiochemical characteristics, ultimately affecting performance also discussed. Finally, applications materials, i.e., carbon nanotubes, graphene, activated carbon, reviewed, followed by conclusions outlook.

Language: Английский

Citations

68