Cited by A universal route to graft highly dispersed Cobalt Phthalocyanine on porous carbon for efficient CO2 Electroreduction

Atomically Integration of O-Bridged Co-Fe Hetero-Pairs as Tandem Photocatalyst Towards Highly Efficient Hydroxyl Radicals Production DOI

Yali Luo,

Yang Deng, Pengfei Li

et al.

Published: Jan. 1, 2024

Photocatalytic Fenton-coupled oxygen reduction reaction (ORR) is a promising strategy for •OH production. Single-atom catalysts (SACs), featuring high atom utilization, exhibit superior catalytic activity. However, it remains challenge to synchronously achieve efficient catalysis of both steps on one active site. Herein, novel Co-Fe hetero-atom pair tandem photocatalyst was precisely constructed by pre-designing the structure covalent organic frameworks (COFs) and introduction strategies sites. Thanks synergism neighboring atoms, Co-Fe-COF presents highly hydroxyl radicals production following process O2+H2O→H2O2→•OH. Additionally, immobilization pairs pore walls COF can boost enrichment contaminants, thus increasing utilization •OH. Theoretical simulations reveal proximity electronic effect O-bridged not only thermodynamically promotes formation OOH*, but also dynamically activates self-healing cycle Fe(II)/Fe(III). This work provides routine designing high-performance catalysts.

Language: Английский

Citations

P-tuned FeN2 binuclear sites for boosted CO2 electro-reduction DOI

Cao Guo,

Sanshuang Gao,

Jun Li

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 1, 2024

Language: Английский

Citations

Boosting Electrocatalytic Carbon Dioxide Reduction via Self‐Relaxation of Asymmetric Coordination in Fe‐Based Single Atom Catalyst DOI

Zhaoyong Jin,

Dongxu Jiao,

Yilong Dong

et al.

Angewandte Chemie, Journal Year: 2023, Volume and Issue: 136(6)

Published: Dec. 16, 2023

Abstract Addressing the limitations arising from consistent catalytic behavior observed for various intermediates during electrochemical carbon dioxide reduction reaction (CO 2 RR) poses a significant challenge in optimization of activity. In this study, we aimed to address by constructing an asymmetric coordination Fe single atom catalyst (SCA) with dynamically evolved structure. Our catalyst, consisting coordinated one S and three N atoms (Fe−S 1 3 ), exhibited exceptional selectivity Faradaic efficiency 99.02 %) demonstrated high intrinsic activity (TOF 7804.34 h −1 remarkable stability. Using operando XAFS spectra Density Functional Theory (DFT) calculations, elucidated self‐relaxation geometric distortion dynamic evolution bond lengths within catalyst. These structure changes enabled independent regulation *COOH *CO intermediate adsorption energies, effectively breaking linear scale relationship enhancing CO RR. This study provides valuable insights into SACs paves way targeted designs disrupt scaling relationships.

Language: Английский

Citations

Defect anchored single atomic Tin-nitrogen sites on graphene nanomesh for enhanced CO2 electroreduction to CO DOI

Jianguo Wu,

Guiyue Bi,

Tianyu Zhang

et al.

Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: unknown

Published: June 1, 2024

Language: Английский

Citations

A universal route to graft highly dispersed Cobalt Phthalocyanine on porous carbon for efficient CO2 Electroreduction DOI

Shide Wu,

Mengjin Gao,

Dan Ping

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A promising catalyst for dispersing CoPc on three-dimensional porous carbon was prepared and showed impressive performance CO 2 electroreduction to CO.

Language: Английский

Citations