Gradient sulfide Ti3(PO4)4 buffer layer enables highly stable NCM811/Li5.3PS4.3Cl1.7 interface for all-solid-state lithium batteries DOI
Xiaodong Wang, Miaomiao Zhou, Zijun Liu

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: June 1, 2025

Language: Английский

Carbon-Supported Hyperbranched Polyethyleneimines: Exploring into Polyamine/Anion Interactions to Design Efficient Polymer-Based Energy and Scavenger Materials DOI Open Access
Antonio Peñas, Celeste García-Gallarín, M.L. Godino-Salido

et al.

Polymers, Journal Year: 2025, Volume and Issue: 17(6), P. 786 - 786

Published: March 15, 2025

The anion-complexation mechanism and anion-adsorption capacity of a hybrid material based on hyperbranched polyethyleneimine (HBPEI) covalently bonded onto an activated carbon (AC) is presented. anion-scavenger behavior this toward CrO42−, PO43−, AsO43− HgCl42− was explored by direct potentiometric adsorption measurements, which revealed novel approach to predict the interactions between supported polymeric complexing units different anions. results were analyzed considering reactivity data HBPEI/anion (HBPEI free in solution) AC-HBPEI/anion systems. corroborated that AC-HBPEI excellent anion-complexing material, whose anion ability defined properties HBPEI molecules This assessment provides straightforward tool determine type strength involved polymer-based/anion systems, can provide valuable information for predicting designing efficient energy scavenger materials.

Language: Английский

Citations

0

In Situ Polymerization in COF Boosts Li-Ion Conduction in Solid Polymer Electrolytes for Li Metal Batteries DOI Creative Commons

Junchen Meng,

Mengjia Yin,

Kairui Guo

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: May 6, 2025

Abstract Solid polymer electrolytes (SPEs) have garnered considerable interest in the field of lithium metal batteries (LMBs) owing to their exceptional mechanical strength, excellent designability, and heightened safety characteristics. However, inherently low ion transport efficiency poses a major challenge for application LMBs. To address this issue, covalent organic framework (COF) with ordered channels, chemical stability, large specific surface area, designable multifunctional sites has shown promising potential enhance lithium-ion conduction. Here, we prepared an anionic COF, TpPa-COOLi, which can catalyze ring-opening copolymerization cyclic lactone monomers situ fabrication SPEs. The design leverages high area COF facilitate absorption polymerization precursor within pores, forming additional COF-polymer junctions that pathways. partial exfoliation achieved through these improved its dispersion matrix, preserving channels facilitating across grain boundaries. By controlling variables alter crystallinity TpPa-COOLi presence –COOLi substituents, long-range order substituents exhibited superior electrochemical performance. This research demonstrates constructing high-performance SPEs

Language: Английский

Citations

0

Electrolytes with competitive Na+-anion coordination for high-voltage sodium-ion batteries DOI
Yongsheng Huang,

Weili Sun,

Mingyu Zhi

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: 106, P. 951 - 960

Published: May 14, 2025

Language: Английский

Citations

0

FePS3 derived ion-conductive interfacial layers enabling dendrite-free lithium metal anodes DOI
Ying Luo,

Wen Pan,

Shaozhen Huang

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: unknown, P. 101922 - 101922

Published: May 1, 2025

Language: Английский

Citations

0

Historical dimensions and directions on energy storage: unique perspectives DOI Creative Commons
Doğan Erdemir, İbrahim Dinçer

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 128, P. 117199 - 117199

Published: May 30, 2025

Citations

0

Gradient sulfide Ti3(PO4)4 buffer layer enables highly stable NCM811/Li5.3PS4.3Cl1.7 interface for all-solid-state lithium batteries DOI
Xiaodong Wang, Miaomiao Zhou, Zijun Liu

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: June 1, 2025

Language: Английский

Citations

0