Carbon, Journal Year: 2024, Volume and Issue: 226, P. 119216 - 119216
Published: May 4, 2024
Language: Английский
Carbon, Journal Year: 2024, Volume and Issue: 226, P. 119216 - 119216
Published: May 4, 2024
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115802 - 115802
Published: Feb. 1, 2025
Language: Английский
Citations
0Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106050 - 106050
Published: Feb. 1, 2025
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: 13(2), P. 115945 - 115945
Published: Feb. 25, 2025
Language: Английский
Citations
0ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 25, 2025
Language: Английский
Citations
0Acta Physico-Chimica Sinica, Journal Year: 2025, Volume and Issue: unknown, P. 100074 - 100074
Published: March 1, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: March 1, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: March 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: March 18, 2025
Abstract Frontier orbital hybridization plays a vital role in the initial adsorption and activation process during catalysis. A formidable challenge is precise determination of active orbitals/sites. Herein, 2D Bi 3 O 4 Br nanosheets are adopted as an operable platform for heteroatom doping various transition metals (Fe, Ni, Zn/Cd). As atom number dopants increases, capability selective CO 2 photoconversion continuously amplified. The intrinsic nature variation functional indicated from band center distance (Δ d/p‐p ) indicators. calculated charge transfer ‐bound geometries further demonstrates p‐p interaction overwhelms d‐p interaction. X‐ray photoelectron spectroscopy absorption results verify charged sites with 6p orbitals not fully filled by electrons. In situ diffuse reflectance infrared Fourier transform (DRIFTS) analysis Gibbs free energy change profile suggest rapid emergence critical * COOH intermediate thermodynamically preferred pathway.
Language: Английский
Citations
0ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(11)
Published: March 1, 2025
Abstract MOF‐based composites with semiconductors offer synergistic effects, such as broader light absorption, improved charge carrier separation, and more active catalytic sites, all of which enhance the overall performance MOFs in CO 2 reduction. This study presents development characterization a Ni‐BDC MOF/MnO composite for photocatalytic reduction under visible light. The MOF bandgap 3.16 eV was integrated γ‐MnO , light‐absorbing semiconductor to improve separation extend absorption. resulting exhibited reduced 2.7 eV, enabling efficient CH 4 . Structural, optical, electrochemical analyses confirmed intimate interaction between MnO enhancing dynamics. optimized achieved high yields (56.97 µmol g⁻¹) (23.5 after 6 h irradiation, enhanced stability minimal electron‐hole recombination. mechanistic revealed multiple intermediates involved reduction, providing insights into pathways formation. work offers sustainable approach conversion potential applications greenhouse gas mitigation energy production.
Language: Английский
Citations
0The Journal of Physical Chemistry C, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Language: Английский
Citations
0