Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3639 - 3639
Published: Jan. 1, 2024
Language: Английский
Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3639 - 3639
Published: Jan. 1, 2024
Language: Английский
Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123512 - 123512
Published: Jan. 1, 2025
Language: Английский
Citations
2The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 10, 2025
We have developed an umpolung method utilizing the Tf2O/DMSO-based system for C(sp2)-P bond or C(sp3)-P formation. This employs both P(O)-H and P(O)-OH compounds as phosphorus sources demonstrates excellent compatibility with a wide range of Grignard reagents. Without requirement precious transition metals additives, this one-pot protocol provides practical efficient synthetic pathway to variety aryl alkyl phosphine oxides. The broad substrate scope diverse applications highlight utility method.
Language: Английский
Citations
0Organic Letters, Journal Year: 2025, Volume and Issue: unknown
Published: May 12, 2025
A novel copper-catalyzed approach for the stereoselective cyanation and phosphorylation of formamides has been developed. This protocol enables direct conversion a broad range agents, including H-phosphonates, H-phosphinates, H-phosphine oxides, into target cyanation/phosphorylation products with good to excellent yields. Notably, when optically active H-phosphinates are employed, transformation exhibits exceptional stereoselectivity. In combination DFT calculation systematic step-by-step control experiments, possible reaction mechanism is proposed.
Language: Английский
Citations
0Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: May 27, 2025
Comprehensive Summary An innovative approach to synthesizing pyrrole‐functionalized phosphorodithioates via a copper‐catalyzed cascade phosphorodithiolation/cyclization of β‐ketodinitriles is disclosed. This method employs tetraphosphorus decasulfide (P 4 S 10 ) as phosphorus source, activated by alcohols under mild conditions. A wide range and are well‐tolerated, affording the desired products with good excellent yields, underscoring broad functional group compatibility. Notably, this process eschews need for noble metal catalysts, aligning green chemistry principles enabling direct sustainable transformation from inorganic organic phosphorus. Furthermore, synthesized demonstrate potent antibacterial properties against Staphylococcus aureus .
Language: Английский
Citations
0Tetrahedron, Journal Year: 2024, Volume and Issue: 168, P. 134352 - 134352
Published: Nov. 1, 2024
Language: Английский
Citations
3Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3639 - 3639
Published: Jan. 1, 2024
Language: Английский
Citations
0