Progress in the P(III)→P(V) Rearrangement Reaction of Phosphine Chlorides and Hydroxyl Containing Compounds DOI
Lulu Yang, Yi Cui, Jiale Wu

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3639 - 3639

Published: Jan. 1, 2024

Language: Английский

Copper catalysed construction of C-P bond: C-H functionalization DOI

Rajnikant N. Ghoghari,

Kishor H. Chikhalia

Journal of Organometallic Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 123512 - 123512

Published: Jan. 1, 2025

Language: Английский

Citations

2
Tf2O/DMSO-Promoted Umpolung Phosphorylation for C(sp2)–P or C(sp3)–P Bond Formation DOI
Dawei Shi, Ming Li, R. X. Yang

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 10, 2025

We have developed an umpolung method utilizing the Tf2O/DMSO-based system for C(sp2)-P bond or C(sp3)-P formation. This employs both P(O)-H and P(O)-OH compounds as phosphorus sources demonstrates excellent compatibility with a wide range of Grignard reagents. Without requirement precious transition metals additives, this one-pot protocol provides practical efficient synthetic pathway to variety aryl alkyl phosphine oxides. The broad substrate scope diverse applications highlight utility method.

Language: Английский

Citations

0
Copper-Catalyzed Stereoselective Cyanation/Phosphorylation of Formamides with TMSCN and P(O)–H Bonds DOI
Weifeng Xu,

Liyong Fan,

Zikang Li

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: May 12, 2025

A novel copper-catalyzed approach for the stereoselective cyanation and phosphorylation of formamides has been developed. This protocol enables direct conversion a broad range agents, including H-phosphonates, H-phosphinates, H-phosphine oxides, into target cyanation/phosphorylation products with good to excellent yields. Notably, when optically active H-phosphinates are employed, transformation exhibits exceptional stereoselectivity. In combination DFT calculation systematic step-by-step control experiments, possible reaction mechanism is proposed.

Language: Английский

Citations

0
Copper‐Catalyzed Cascade Phosphorodithiolation/Cyclization of β‐Ketodinitriles: Organic Transformation of P4S10 DOI

Minjing Yuan,

Longzhi Zhu, Weifeng Xu

et al.

Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 27, 2025

Comprehensive Summary An innovative approach to synthesizing pyrrole‐functionalized phosphorodithioates via a copper‐catalyzed cascade phosphorodithiolation/cyclization of β‐ketodinitriles is disclosed. This method employs tetraphosphorus decasulfide (P 4 S 10 ) as phosphorus source, activated by alcohols under mild conditions. A wide range and are well‐tolerated, affording the desired products with good excellent yields, underscoring broad functional group compatibility. Notably, this process eschews need for noble metal catalysts, aligning green chemistry principles enabling direct sustainable transformation from inorganic organic phosphorus. Furthermore, synthesized demonstrate potent antibacterial properties against Staphylococcus aureus .

Language: Английский

Citations

0
Recent Progress in Metal-Catalyzed C(sp³)-P Bond Formation DOI
Jia‐Lin Tu, Zhengjia Shen, Binbin Huang

et al.

Tetrahedron, Journal Year: 2024, Volume and Issue: 168, P. 134352 - 134352

Published: Nov. 1, 2024

Language: Английский

Citations

2
Progress in the P(III)→P(V) Rearrangement Reaction of Phosphine Chlorides and Hydroxyl Containing Compounds DOI
Lulu Yang, Yi Cui, Jiale Wu

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3639 - 3639

Published: Jan. 1, 2024

Language: Английский

Citations

0