ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(48), P. 47729 - 47738
Published: Oct. 31, 2024
One
of
the
main
challenges
in
animal
breeding
systems
is
determining
estradiol
(E2)
livestock
samples
as
simple
and
minimally
invasive
possible,
Thus,
a
nonenzymatic
biosensor
screen-printed
electrode
(SPE)
was
developed
by
modifying
nanohybrid
palladium
nanoparticles
(PdNPs),
carbon
dots
anchored
on
nanosilica
particle
(PdNPs/C.dots/SiO
Glyphosate
is
a
widely
used
broad-spectrum
herbicide
for
controlling
grassy
weeds,
but
its
potential
hazards
remain
topic
of
significant
debate.
Despite
concerns,
glyphosate
still
commonly
highlighting
that
methods
rutine
detection
in
environmental
samples
are
imperatively
required.
Herein,
we
report
on
solid-state
electrochemical
sensor
based
ZnO
nanoparticles
(ZnO
NPs)
on-site
glyphosate.
Accordingly,
NPs
was
drop-cast
the
surface
disposable
screen-printed
carbon
electrode.
Eco-friendly
only
7
nm
crystallite
sizes
were
obtained
by
green
sol-gel
synthesis
using
lemon
(Citrus
limon)
waste
aqueous
extract
as
reducing
and
capping/stabilizing
agent
Zn
nitrate
precursor.
Scanning
electron
microscopy
confirmed
successful
electrode
functionalization
with
synthesized
nanoparticles.
Under
laboratory
conditions
acetate
buffer
(pH
5),
demonstrated
excellent
selectivity
sensitivity,
limit
0.648
µM,
wide
linear
range
(0.5
µM
to
7.5
mM),
rapid
time
30
minutes.
When
tested
river
water,
achieved
0.96
differential
pulse
voltammetry.
It
also
exceptionally
tolerated
interference
from
similar
organophosphorus
compounds
ions
found
water.
The
performance
attributed
strong
coordination
interactions
between
atoms
phosphonate/carboxylate
groups
enhanced
hydrogen
bond
at
acidic
pH,
determined
chemical
calculations.
This
offers
cost-effective,
efficient,
environmentally
friendly
solution
monitoring
water
systems.
Analytical Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
approach
utilizes
the
antibody-conjugated
silver
nanoparticle
complex
as
an
alternative
to
natural
enzymes
for
signal
generation,
overcoming
structural
instability
and
environmental
susceptibility
inherent
enzymes.
Environmental Science Water Research & Technology,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
The
study
aimed
to
develop
a
new
electrochemical
sensor
based
on
screen-printed
carbon
electrode
modified
with
copper
nanoparticles
(SPE/CuNPs)
determine
imidacloprid
(IMI)
pesticide
in
environmental
samples.