Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 137016 - 137016
Published: April 1, 2025
Language: Английский
Nano Energy, Journal Year: 2024, Volume and Issue: 127, P. 109774 - 109774
Published: May 21, 2024
Language: Английский
Citations
5
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 677, P. 459 - 469
Published: July 31, 2024
Language: Английский
Citations
5
Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 35(1)
Published: Oct. 31, 2024
Abstract The use of all‐solid‐state lithium metal batteries (ASSLMBs) has garnered significant attention as a promising solution for advanced energy storage systems. By employing non‐flammable solid electrolytes in ASSLMBs, their safety profile is enhanced, and the anode allows higher density compared to traditional lithium‐ion batteries. To fully realize potential solid‐state (SSEs) must meet several requirements. These include high ionic conductivity Li + transference number, smooth interfacial contact between SSEs electrodes, low manufacturing cost, excellent electrochemical stability, effective suppression dendrite formation. This paper delves into essential requirements enable successful implementation ASSLMBs. Additionally, representative state‐of‐the‐art examples developed past 5 years, showcasing latest advancements SSE materials highlighting unique properties are discussed. Finally, provides an outlook on achieving balanced improved addressing failure mechanisms solutions, critical challenges such reversibility plating/stripping thermal runaway, characterization techniques, composite SSEs, computational studies, ASS lithium–sulfur lithium–oxygen With this consideration, ASSLMBs can be realized.
Language: Английский
Citations
5
Energy Materials, Journal Year: 2024, Volume and Issue: 4(6)
Published: Dec. 13, 2024
Lithium metal batteries (LMBs), the energy conversion and storage technologies that have been thoroughly investigated, are utilized in various areas. Most current commercial LMBs use liquid electrolytes, but their safety cannot be guaranteed. In contrast, all-solid-state with solid-state electrolytes (SSEs) regarded as next-generation systems owing to enhanced safety. examination of SSEs, benefits composite SSEs (CSSEs) particularly prominent. CSSEs relying on multiphase composites better flexibility tailor electrolyte performance based demand and, thus, design components. Based existing research presentations, we herein review development CSSEs. Firstly, essential components introduced, focusing explaining transport channel Li ions within polymer matrix impact fillers this channel. The key parameters described detail. Subsequently, meticulously classified; critical roles played by different clarified, hotspots summarized. Furthermore, prevalent structural methodologies examined, structures battery is elucidated. Finally, problems future prospects This significant because it provides ideas for contributes realize wide application.
Language: Английский
Citations
4
The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 917 - 923
Published: Jan. 20, 2025
In traditional operations of all-solid-state lithium metal batteries (ASSLMBs), a small thin circular disk is employed as anode (LMA). However, ASSLMBs with circular-disk LMA often fail in <150 cycles low capacity retention. this work, we developed new ring-shaped to improve cyclability. Full cells consisting LMA, LiCoO2 cathode, and Li6PS5Cl electrolyte maintain good retention 83.65% at 0.3C after 300 cycles. Moreover, situ L-band electron paramagnetic resonance imaging (EPRI) showed that fewer Li dendrites are formed on LMA. This work highlights the importance design shape mitigate growth shows EPRI useful technique for ASSLMBs.
Language: Английский
Citations
0
Battery energy, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 26, 2025
ABSTRACT Fluorides are commonly regarded as interfacial additives that enhance the electrochemical stability of solid‐state battery electrolytes. In this study, we synthesized lithium borate glassy solid electrolytes and investigated effect adding aluminum fluoride (AlF 3 ) on its against metal electrodes. Samples maintained their amorphous nature, with up to 9.20 wt.% fluorine in glass. Lithium glasses, without AlF , demonstrated an excellent performance, sustaining a stable voltage profile at current densities from 0.01 1 mA cm⁻² 160°C. Notably, glass highest ion content achieved relative ionic conductivity cycled stably for 500 h 160°C symmetric LiǀglassǀLi cells. However, addition significantly compromises stability. long‐term symmetrical cell tests, ‐containing exhibited short‐circuiting under 0.3 cm⁻², revealing unexpectedly poor These findings offer valuable insights evaluating impact incorporation performance
Language: Английский
Citations
0
Advanced Intelligent Systems, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 28, 2025
As nations worldwide intensify their efforts to achieve environmental goals and reduce carbon emissions, as the energy landscape continues evolve, importance of advanced battery technology becomes increasingly critical. Despite significant advancements, persistent challenges at interfaces—where electrode electrolyte interactions occur—are particular concern. These interfaces play pivotal roles in phenomena such dendrite growth formation solid–electrolyte interphases (SEI), which are crucial for performance, longevity, safety batteries. Machine learning (ML), a vital subset artificial intelligence, offers robust capabilities by autonomously identifying patterns complex datasets, thereby enhancing understanding these intricate interfacial processes. This review highlights recent progress ML‐assisted simulations predictions interfaces, illustrating how ML accelerates research development trajectory. By employing algorithms machine vision, lithium growth, SEI formation, dynamics can be performed. not only deepen comprehension but also serve foundation further material optimization predication property enhancement. The aim this is spur ongoing application address existing challenges, advancing state‐of‐the‐art technologies.
Language: Английский
Citations
0
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 6, 2025
Abstract Sulfide electrolytes are considered the most promising technique for all‐solid‐state lithium–sulfur batteries (ASLSBs) due to relatively high ionic conductivity and superior chemical compatibility with composite sulfur cathodes. However, cathodes based on sulfide feature large volume expansion, unstable interfacial contact, inherent insulating nature, which impedes practical application of ASLSBs. Therefore, a systematic design cathode side ASLSBs is crucial ensuring well‐contacted, electrochemically stable cathode–electrolyte interface, an effective ion‐electron transfer network. Here, comprehensive discussion latest strategies will be delivered, highlighting their effectiveness in improving performances First, major challenges including slow oxidation kinetics significant expansion dissected. Then, focus shifted degradation processes at interface between electrolyte. Subsequently, improvement stability by structural modulation elaborated. Finally, progress, we present new perspective constructing efficient transport network cathode‐electrolyte offers insights directions achieving future.
Language: Английский
Citations
0
International Journal of Electrochemical Science, Journal Year: 2025, Volume and Issue: unknown, P. 101006 - 101006
Published: March 1, 2025
Language: Английский
Citations
0
Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 120, P. 116512 - 116512
Published: April 5, 2025
Language: Английский
Citations
0