Soot formation and laminar combustion characteristics of anisole: ReaxFF MD simulation and kinetic analysis DOI Creative Commons

Wenlong Dong,

Run Hong,

Jinfang Yao

et al.

Carbon Neutrality, Journal Year: 2024, Volume and Issue: 3(1)

Published: Oct. 31, 2024

Abstract The application of biomass energy is one the important ways to achieve carbon neutrality and deal with global warming. study on combustion mechanism anisole, an oxygen-containing fuel, helpful for biofuel large-scale application. In this study, soot formation laminar characteristics anisole were analyzed by reactive force field molecular dynamics (ReaxFF MD) kinetic simulation, respectively. ReaxFF MD simulation studies had shown that occurred in three stages, stage 1 (0–1 ns), 2 (1–2.5 3 (2.5–6 ns). stages represented pyrolysis developmental soot, graphitization During primary mechanisms as follows: H-abstraction-C H -addition, carbon-addition-hydrogen-addition, internal ring long chain link. exhibited different morphologically behaviors: from flakes onions spheres fewer branched chains. From it can be found burning velocities increased along increase temperature, while opposite trend was pressure. sensitivity coefficient naphthalene, main precursor, revealed promotional reactions R5 (O + < = > O OH), R36 (CO OH CO H).

Language: Английский

Effects of ammonia and carbon dioxide concentration variation on ammonia-diesel blended fuel combustion in CO2/O2 atmosphere DOI

Yongfeng Liu,

Chenyang Yin,

Jiaying Pan

et al.

Fuel, Journal Year: 2025, Volume and Issue: 389, P. 134474 - 134474

Published: Feb. 10, 2025

Language: Английский

Citations

0

An experimental and numerical investigation of the ion current and relevant ion species in premixed ammonia-air flames DOI
Dhaminda Hewavitarane,

Sadami Yoshiyama

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 109, P. 335 - 343

Published: Feb. 12, 2025

Language: Английский

Citations

0

Improving the combustion performance of ammonia in a spark-ignition engine by mixing methane coupled with multiple spark ignition: An optical study DOI Creative Commons
Kalim Uddeen, Qinglong Tang,

Hao Shi

et al.

International Journal of Engine Research, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 26, 2025

Ammonia (NH 3 ) has recently emerged as a promising alternative fuel for both internal and external combustion engines. The of pure ammonia does not produce unwanted pollutant emissions such oxides carbon, total unburned hydrocarbon (THC), particulates. Additionally, contains 17.8% by mass hydrogen (H 2 ), making it potential storage. However, its narrow flammability range, low reactivity, flame propagation speed have limited engine performance. To address these issues, this study was conducted to explore the use multiple generation ammonia-methane blend approaches enhance improve utilized novel metal liner generate flames inside chamber installed four spark plugs, well an additional plug at top cylinder head, similar spark-ignition engine. Furthermore, investigated effect adding methane combustion, with fractions ranging from 30% 60% in terms energy fraction. process initiated various ignition cases, high-speed natural flame-luminosity (NFL) technique capture cases. results showed that led stable resulting better efficiency due faster rate. found increasing fraction mixture increased in-cylinder pressure heat release rate (HRR), improving performance significantly. higher NO x were observed mixture, fuel-bound thermal caused temperatures. also THC CO while mixture. Moreover, cases produced lower than single case because burned air-fuel rapidly.

Language: Английский

Citations

0

Evaluating Coal, RDF, and Ammonia Blends in Power Plants: Techno-Economic Insights and Coal Phase-Out Implications DOI Creative Commons

Antonio Chavando,

Valter Silva, João Cardoso

et al.

Energies, Journal Year: 2025, Volume and Issue: 18(6), P. 1524 - 1524

Published: March 19, 2025

This comprehensive techno-economic analysis focuses on a proposed power plant that uses cleaner alternatives to traditional combustion methods. The study meticulously examines ternary blends of ammonia, refuse-derived fuels (RDFs), and coal. Utilizing an Aspen Plus simulation equilibrium model, thorough review the relevant literature, evaluation reports biomass-to-energy plants ammonia combustion, spans 20 years. It considers vital financial metrics such as net present value (NPV), internal rate return (IRR), payback period (PBP). findings indicate pure coal is most energy-efficient but has highest global warming potential (GWP). In contrast, RDF significantly reduce GWP, with showing 3215% lower GWP than Economically, remains attractive option. However, 80% coal, 10% also show promise PBP 11.20 years at 15% discount rate. These results highlight balance environmental economic considerations in generation.

Language: Английский

Citations

0

Advancements in Bioelectrocatalysis for Electrochemical Ammonia Production: Integrating Enzyme‐Based Catalysis DOI
Kumarasamy Jayakumar,

Dharmalingam Sakthilatha,

Raja Venkatesan

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(12)

Published: March 1, 2025

Abstract Bioelectrocatalysis has advanced ammonia production by integrating enzyme‐based processes into electrochemical methods, providing chemical manufacturers with a distinct alternative to the traditional Haber–Bosch process. The review discusses latest developments in catalysis that have been shown enhance synthesis, efficiency, and sustainability. We also discuss development of designed bioelectrocatalysts, including nitrogenase‐inspired enzymes engineered microbes, which enable reduction atmospheric nitrogen under mild conditions. Also study highlights most recent e‐BNF advancements, focusing on innovations efficiency scalability. Nanomaterial integration simplifies ATP‐independent fixation, enhancing electron transfer normal conditions, while exploring its scalability implications for green chemistry industrial applications as sustainable Eventually, these technologies their applications, comprehensive overview current advancements future research directions.

Language: Английский

Citations

0

Time-resolved NH2 radical detection using 1.5 μm DFB laser DOI
D.M. Plastinina, Е. Н. Чесноков

Chemical Physics Letters, Journal Year: 2025, Volume and Issue: unknown, P. 142068 - 142068

Published: March 1, 2025

Language: Английский

Citations

0

Genetic Algorithm-Assisted Multi-Objective Optimization for Developing a Multi-Wiebe Combustion Model in Ammonia-Diesel Dual Fuel Engines DOI Creative Commons
Yan Zhang, Dawei Wu, Ebrahim Nadimi

et al.

Energy, Journal Year: 2025, Volume and Issue: unknown, P. 136181 - 136181

Published: April 1, 2025

Language: Английский

Citations

0

Measuring Ammonia Concentration Distributions with Passive Samplers to Evaluate the Impact of Vehicle Exhaust on a Roadside Environment in Tokyo, Japan DOI Creative Commons
Hiroyuki Hagino

Atmosphere, Journal Year: 2025, Volume and Issue: 16(5), P. 519 - 519

Published: April 29, 2025

Evaluating the impact on roadside environments of NH3 from vehicle emissions is important for protecting ecosystem air pollution by fine particulate matter and nitrogen deposition. This study used passive samplers to measure NOX at multiple points near a major road observe distribution these gases in area. The emitted vehicles environmental concentration different distances was found be similar that NO2. rapidly decreased due dilution diffusion within approximately 50 m road, after 100 remained almost same or slowly. Furthermore, CO2 observations taken period along background yielded vehicular emission factor 4–50 mg/km NH3, which comparable with previous research. level contributes 4–11 ppb concentrations through process. A correlation between factors trade-off relationship seen when single-vehicle exhaust measured.

Language: Английский

Citations

0

Additive effect of alkaline earth metal on hydrogen production via catalytic ammonia decomposition over Co/CeO2 catalysts DOI
Wenshuo Zhang, Weili Zhou, Yangfeng Li

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 94, P. 697 - 705

Published: Nov. 16, 2024

Language: Английский

Citations

2

Hydrogen Production From Methanol Reforming Processes DOI
G. Abdulkareem-Alsultan, N. Asikin-Mijan, Maadh Fawzi Nassar

et al.

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Language: Английский

Citations

0