COF and MOF Hybrids: Advanced Materials for Wastewater Treatment

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(43)

Published: Oct. 12, 2023

Abstract Recent advances in ordered porous materials, including metal‐organic (MOF) and covalent organic frameworks (COF), are set to revolutionize the strategies used for wastewater treatment. This is attributed large surface area, high crystallinity, structural tunability, thermal chemical stability, well‐defined structures of MOF COF. Despite distinctive properties exhibited by single system (either or COF), combination COF MOF, as a hybrid construct, offers remarkable opportunity achieve superior functionality performance. The favorable features COF–MOF hybrids different treatment sectors have opened new venues effective environmental remediation. review presents state‐of‐the‐art design, synthesis, application hybrids. synthesis principles, MOF‐first, COF‐first, post‐synthetic linkage pre‐synthesized COFs MOFs summarized. potential these novel materials evaluated considering contaminant sensing, adsorptive removal, catalytic photodegradation.The conclusion drawn assessing existing hurdles opportunities development COF‐MOF an innovative yet viable approach addressing

Language: Английский

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Advanced materials in sorbent-based analytical sample preparation

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 506, P. 215680 - 215680

Published: Feb. 13, 2024

Language: Английский

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Anticancer Drug Extraction from Plasma Samples Using Three-Dimensional Polyoxometalate-Based Supramolecular Frameworks as Sorbents

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(6), P. 2877 - 2887

Published: Jan. 29, 2024

Four self-assembled inorganic–organic hybrid materials, namely, H{Na(H2O)3[Gd(PDA)(H2O)2]3[BW12O40]}·4H2O (1), H{Na(H2O)3[Tb(PDA)(H2O)2]3[BW12O40]}·3H2O (2), H{Na(H2O)3[Er(PDA)(H2O)3]3[BW12O40]}·H2O (3) (PDA = 1,10-phenanthroline-2,9-dicarboxylate), and [Pr3(H2O)13(pydc–OH)2][BW12O40]·12H2O (4) (pydc–OH 4-hydroxy-2,6-pyridinedicarboxylate), were hydrothermally synthesized structurally characterized. Hybrids 1–3 are isostructural contain a Keggin unit, which is linked to lanthanoids produce distinct trinuclear lanthanoid building blocks. The fragments connected by anion−π hydrogen bonding interactions create 3D networks. In 4, trimeric Pr-organic species bearing unit forms 2D coordination polymer, then between layers lead the formation of structure. These polyoxometalate-based frameworks used as sorbents for dispersive microsolid-phase extraction (D-μSPE) two anticancer drugs (doxorubicin epirubicin) in human plasma samples. Analytes quantified separated using high-performance liquid chromatography with fluorescence detection (HPLC-FLD). method's linearity was 0.8–500 ng mL–1 1.0–500 antineoplastic doxorubicin epirubicin, respectively. limits (S/N 3) range 0.2–0.3 mL–1, while precision 3.5–4.3%. Finally, samples from patients treated or epirubicin analyzed D-μSPE-HPLC-FLD method.

Language: Английский

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A miniaturized stir bar sorptive dispersive microextraction method for the determination of bisphenols in follicular fluid using a magnetic covalent organic framework

Analytica Chimica Acta, Journal Year: 2024, Volume and Issue: 1289, P. 342215 - 342215

Published: Jan. 4, 2024

Bisphenols, particularly bisphenol A (BPA), are the primary monomers used as additives in manufacturing of many consumer products. The exposure to these compounds is related endocrine-disrupting and reproductive effects, among others. For this reason, development analytical methods for their determination biological matrixes needed monitor population compounds. Their quantification at ovarian level (i.e., follicular fluid) interesting assessment content draw conclusions about infertility problems. However, background does not meet all requirements by focusing mainly on BPA.

Language: Английский

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Porous materials in analytical sample preparation: Current status and future perspectives

TrAC Trends in Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 118193 - 118193

Published: Feb. 1, 2025

Language: Английский

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In-situ synthesis of amine-functionalized ZIF-8/COF hybrid composite reinforced hollow fiber for solid-phase microextraction of pesticides besides their quantification via HPLC-UV

Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113075 - 113075

Published: Feb. 1, 2025

Language: Английский

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Recent progress of covalent organic frameworks as attractive materials for solid-phase microextraction: A review

Analytica Chimica Acta, Journal Year: 2023, Volume and Issue: 1287, P. 341953 - 341953

Published: Oct. 23, 2023

Language: Английский

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Highly defective copper-based metal-organic frameworks for the efficient adsorption and detection of organophosphorus pesticides: An experimental and computational investigation

Food Chemistry, Journal Year: 2023, Volume and Issue: 423, P. 136319 - 136319

Published: May 10, 2023

Language: Английский

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Applications of covalent organic frameworks for the elimination of dyes from wastewater: A state-of-the-arts review

Chemosphere, Journal Year: 2023, Volume and Issue: 343, P. 140223 - 140223

Published: Sept. 19, 2023

Language: Английский

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Fabrication of a magnetic metal-organic framework/covalent organic framework composite for simultaneous magnetic solid-phase extraction of seventeen trace quinolones residues in meats

Journal of Chromatography A, Journal Year: 2023, Volume and Issue: 1709, P. 464403 - 464403

Published: Sept. 20, 2023

Language: Английский

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