The Journal of Physical Chemistry C,
Journal Year:
2024,
Volume and Issue:
128(24), P. 10065 - 10074
Published: June 10, 2024
The
detection
of
bisphenol
A
(BPA)
in
wastewater
is
imperative
due
to
its
significant
environmental
impact.
In
this
research,
we
devised
an
electrochemical
sensor
utilizing
photoinduced
calcium
deposition
on
molecularly
imprinted
TiO2
(MI–Ca–TiO2)
for
the
sensitive
and
selective
BPA.
This
novel
approach
combines
Ca-doping
molecular
imprinting
TiO2,
achieving
enhanced
conductivity
binding
sites
MI–Ca–TiO2
demonstrated
linear
ranges
from
0.01
20
μM
a
low
limit
6.0
nM.
Consistent
repeatability
was
observed
across
various
batches
MI–Ca–TiO2,
indicated
by
relative
standard
deviation
0.8%.
Notably,
maintained
high
differential
pulse
voltammetry
response
even
after
prolonged
storage
refrigerator.
Moreover,
presence
100-fold
higher
concentration
analogous
or
interfering
ions,
nanosheets
exhibited
marked
current
response,
affirming
their
efficacy
BPA
detection.
These
findings
indicate
potential
as
simple,
cost-effective,
efficient
tool
detecting
water.
The Journal of Physical Chemistry C,
Journal Year:
2024,
Volume and Issue:
128(24), P. 10065 - 10074
Published: June 10, 2024
The
detection
of
bisphenol
A
(BPA)
in
wastewater
is
imperative
due
to
its
significant
environmental
impact.
In
this
research,
we
devised
an
electrochemical
sensor
utilizing
photoinduced
calcium
deposition
on
molecularly
imprinted
TiO2
(MI–Ca–TiO2)
for
the
sensitive
and
selective
BPA.
This
novel
approach
combines
Ca-doping
molecular
imprinting
TiO2,
achieving
enhanced
conductivity
binding
sites
MI–Ca–TiO2
demonstrated
linear
ranges
from
0.01
20
μM
a
low
limit
6.0
nM.
Consistent
repeatability
was
observed
across
various
batches
MI–Ca–TiO2,
indicated
by
relative
standard
deviation
0.8%.
Notably,
maintained
high
differential
pulse
voltammetry
response
even
after
prolonged
storage
refrigerator.
Moreover,
presence
100-fold
higher
concentration
analogous
or
interfering
ions,
nanosheets
exhibited
marked
current
response,
affirming
their
efficacy
BPA
detection.
These
findings
indicate
potential
as
simple,
cost-effective,
efficient
tool
detecting
water.