Tuning the hydrogen storage properties of Ti-V-Nb-Cr alloys by controlling the Cr/(TiVNb) ratio DOI Creative Commons
Renato Belli Strozi,

B.H. Silva,

Daniel Rodrigo Leiva

et al.

Journal of Alloys and Compounds, Journal Year: 2022, Volume and Issue: 932, P. 167609 - 167609

Published: Oct. 17, 2022

Language: Английский

Research progress and development tendency on storage mechanism of multi-principal element alloys for hydrogen/tritium storage DOI
Yijie Chen, Jianwei Zhang,

Can-Hui Xu

et al.

Rare Metals, Journal Year: 2024, Volume and Issue: 43(11), P. 5549 - 5572

Published: July 5, 2024

Language: Английский

Citations

9
Microstructural Characterization and Hydrogen Storage Properties at Room Temperature of Ti21Zr21Fe41Ni17 Medium Entropy Alloy DOI Creative Commons
Gaspar Andrade, Payam Edalati, Shivam Dangwal

et al.

ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

This study presents the design and evaluation of a medium entropy alloy (MEA), Ti21Zr21Fe41Ni17, for hydrogen storage at room temperature (30 °C), employing an integrated approach that combines CALPHAD calculations with semiempirical rules. The was developed based on four specific criteria: (1) valence electron concentration (VEC) between 6.2 6.5, (2) atomic size mismatch (δ) least 9.7%, (3) radius ratio hydride-forming to non-hydride-forming elements (rA/rB) ranging from 1.149 1.219, (4) stability C14 Laves phase as primary phase, confirmed by CALPHAD. resulting crystallized predominantly in (92.8 wt %), minor body-centered cubic (BCC) phase. Transmission microscopy (TEM) results revealed coherent nanograin boundaries, particularly C14/BCC interphase, facilitating rapid hydrogenation kinetics. After one-step simple thermal activation, reversibly absorbed 1.4 % relatively low hysteresis fast kinetics, attributed preferential hydride nucleation grain boundaries. In terms thermodynamic properties, chemical composition, designed according aforementioned criteria, should be considered, high iron content (41%) playing critical role. percentage iron, element, stabilizes due significant negative contribution interaction parameter (Ωij) Fe–Zr pair (Ωij = −118.4 kJ/mol), which enthalpy mixing structure. work underscores utility combining methods while outlining challenges future directions optimizing MEAs storage.

Language: Английский

Citations

1
Recent advances in substitutional doping of AB5 and AB2 type hydrogen storage metal alloys for Ni-MH battery applications DOI
Golap Kalita,

Ryo Otsuka,

Takashi Endo

et al.

Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 179352 - 179352

Published: Feb. 1, 2025

Language: Английский

Citations

1
Metal hydrides for solid hydrogen storage: Experimental insights, suitability evaluation, and innovative technical considerations for stationary and mobile applications DOI

Ahmad Alobaid,

Mohammed Kamil,

Khalil Abdelrazek Khalil

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 128, P. 432 - 456

Published: April 17, 2025

Language: Английский

Citations

1
Tuning the hydrogen storage properties of Ti-V-Nb-Cr alloys by controlling the Cr/(TiVNb) ratio DOI Creative Commons
Renato Belli Strozi,

B.H. Silva,

Daniel Rodrigo Leiva

et al.

Journal of Alloys and Compounds, Journal Year: 2022, Volume and Issue: 932, P. 167609 - 167609

Published: Oct. 17, 2022

Language: Английский

Citations

37