Unlocking Spatially Constrained Photogenerated Charge via Dimension Regulation in Metal Halide Perovskite Nanowires for Enhanced Photocatalytic CO2 Reduction DOI
Heng Shi, Huiyu Liu, Chenyu Du

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(15), P. 11617 - 11625

Published: July 21, 2024

Language: Английский

Halide perovskite quantum dots for photocatalytic CO2reduction DOI Open Access
Wentao Song, Guobin Qi, Bin Liu

et al.

Journal of Materials Chemistry A, Journal Year: 2023, Volume and Issue: 11(24), P. 12482 - 12498

Published: Jan. 1, 2023

This review focuses on halide perovskite quantum dots (QDs) for photocatalytic CO 2 reduction, discussing the structures and properties of QDs, mechanism photocatalyst design, challenges directions future research.

Language: Английский

Citations

51
A roadmap of recent advances in MXene@MOF hybrids, its derived composites: Synthesis, properties, and their utilization as an electrode for supercapacitors, rechargeable batteries and electrocatalysis DOI
Narasimharao Kitchamsetti, Jung Sang Cho

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 80, P. 110293 - 110293

Published: Jan. 5, 2024

Language: Английский

Citations

32
Recent Advances in Diverse MXenes‐Based Structures for Photocatalytic CO2 Reduction into Renewable Hydrocarbon Fuels DOI
Qijun Tang, Tianhao Li, Wenguang Tu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(19)

Published: Jan. 17, 2024

Abstract Photocatalytic CO 2 reduction into renewable hydrocarbon fuels is a green solution to address emission and energy issues simultaneously. However, the fast recombination of photogenerated charge carriers sluggish surface reaction kinetics restrict efficiency photocatalytic reduction. The emergence 2D MXenes has potential in improving reduction, owing their high electrical conductivity, flexible structural properties, abundant active sites. Hence, this review will concisely summarize highlight recent advances MXenes‐based photocatalysts used First, synthesis properties briefly introduced. Second, mechanism photoreduction along with roles are summarized, including promoting adsorption , enhancing separation photo‐induced carriers, acting as robust support, photothermal effect. Third, different kinds such MXenes/metal oxides, MXenes/nitrides, MXenes/LDH, MXenes/perovskite, MXene‐derived for classified via type semiconductors. Finally, challenges perspectives also presented, exploring suitable machine learning, uncovering structure‐activity relationship by situ, time‐ space‐resolved characterization techniques, anti‐oxidization ability, scale‐up applications.

Language: Английский

Citations

23
Photocontrolled heterojunctions constructed from holmium single atom modified Mg1.2Ti1.8O5/g-C3N4 with enhanced photocatalytic CO2 conversion DOI
Jing An, Shuang Ge, Guofeng Wang

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(14), P. 5039 - 5047

Published: Jan. 1, 2024

This work is the first to introduce photocontrolled catalysts into CO 2 RR, and further RE single atom catalysts, aiming optimize photocatalytic performance by utilizing synergistic effect of composites.

Language: Английский

Citations

23
Recent advances in novel materials for photocatalytic carbon dioxide reduction DOI Creative Commons

Shanyue Lu,

Shengwei Zhang, Qi Liu

et al.

Carbon Neutralization, Journal Year: 2024, Volume and Issue: 3(1), P. 142 - 168

Published: Jan. 1, 2024

Abstract The conversion of CO 2 into chemical fuels, which can be stored and utilized through photocatalysis, represents an effective, environmentally friendly, sustainable means to address both environmental concerns energy shortages. , as a stable oxidation product, poses challenges for reduction light alone, necessitating the use catalysts. Thus, crucial aspect photocatalytic technology lies in development effective photocatalysts. Based on basic principle PCRR (photocatalytic reaction), review provides detailed introduction core issues process, including relationship between band gap catalyst performance, utilization photogenerated carriers, product selectivity, methods analysis. Then, recent research progresses various photocatalysts are reviewed form examples combined with above principles. Finally, this summarizes insights techniques enhancing activity while also offering future prospects field.

Language: Английский

Citations

17
A versatile strategy for broadening light absorption to ultraviolet–visible region on Zr-based MOF photocatalysts for efficient CO2 reduction DOI
Xin Huang,

Zuoyi Wang,

Yao Zhong

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160812 - 160812

Published: Feb. 1, 2025

Language: Английский

Citations

3
Surface and Defect Engineering Coupling of Halide Double Perovskite Cs2NaBiCl6 for Efficient CO2 Photoreduction DOI
Jiacheng Pi, Xiaofang Jia,

Zhangwen Long

et al.

Advanced Energy Materials, Journal Year: 2022, Volume and Issue: 12(43)

Published: Sept. 11, 2022

Abstract Non‐toxic halide double perovskite materials have many advantages of lead perovskite. Whereas, they usually exhibit poor stability and very low intrinsic photocatalytic CO 2 reduction activity due to the insufficient separation photogenerated charges lack active sites. In this work, stable chlorine‐deficient 3D hierarchical Cs NaBiCl 6 porous microspheres assembled by highly crystalline nanoflakes were prepared a simple grinding method. An unprecedented yield 30.22 µmol g −1 h was achieved in gas‐solid without sacrificial agents, which is highest value among lead‐free photocatalysts. Experimental results density‐functional theory calculations show that chlorine vacancy plays triple role suppressing electron‐holes recombination, enhancing adsorption, significantly reducing free energy barrier for key intermediate COOH* generation. comparison with pristine , coupling surface defect engineering sample brings 12.34 times enhancement photoreduction activity. This work proposes method synthesize chlorine‐vacancy rich offers new design idea substantially enhance activity, opening door prospective contribution these carbon neutralization.

Language: Английский

Citations

69
Assembly of MXene/ZnO heterojunction onto electrospun poly(arylene ether nitrile) fibrous membrane for favorable oil/water separation with high permeability and synergetic antifouling performance DOI
Ao Sun, Yingqing Zhan,

Qingying Feng

et al.

Journal of Membrane Science, Journal Year: 2022, Volume and Issue: 663, P. 120933 - 120933

Published: Aug. 20, 2022

Language: Английский

Citations

65
In-situ assembling 0D/2D Z-scheme heterojunction of Lead-free Cs2AgBiBr6/Bi2WO6 for enhanced photocatalytic CO2 reduction DOI

Lijun Wu,

Song Zheng,

Heng Lin

et al.

Journal of Colloid and Interface Science, Journal Year: 2022, Volume and Issue: 629, P. 233 - 242

Published: Aug. 27, 2022

Language: Английский

Citations

62
Recent Advances in Lead-Free Halide Perovskites for Photocatalysis DOI
Pengfei Cheng, Keli Han, Junsheng Chen

et al.

ACS Materials Letters, Journal Year: 2022, Volume and Issue: 5(1), P. 60 - 78

Published: Dec. 1, 2022

Metal halide perovskites have attracted extensive attention in the field of photocatalysis, because their excellent photophysical properties, including high optical absorption coefficients, tunable band structures, and long carrier diffusion lengths. The application prospect conventional lead-based is restricted by toxicity instability issues. Therefore, it imperative to develop environmentally friendly stable lead-free (LFHPs) for photocatalysis. In recent years, rapid development LFHPs has provided new opportunities photocatalytic applications, ranging from solar-to-chemical energy conversion organic reactions. this Review, we summarize progresses with an emphasis on strategies available improve performance stability. Furthermore, present outlook future directions challenges emerging field.

Language: Английский

Citations

54