N, O trans-coordinating silver single-atom catalyst for robust and efficient ammonia electrosynthesis from nitrate DOI
Zhen Shen,

Yingsong Yu,

Zhiwei Zhao

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 331, P. 122687 - 122687

Published: March 24, 2023

Language: Английский

Self-enhanced localized alkalinity at the encapsulated Cu catalyst for superb electrocatalytic nitrate/nitrite reduction to NH 3 in neutral electrolyte DOI Creative Commons
Zhen Shen,

Guanghai Chen,

Xueyi Cheng

et al.

Science Advances, Journal Year: 2024, Volume and Issue: 10(28)

Published: July 10, 2024

The electrocatalytic nitrate/nitrite reduction reaction (eNO

Language: Английский

Citations

21
Effects of Ionic Interferents on Electrocatalytic Nitrate Reduction: Mechanistic Insight DOI

Jinling Fan,

Leslie Arrazolo,

Jiaxin Du

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(29), P. 12823 - 12845

Published: July 2, 2024

Nitrate, a prevalent water pollutant, poses substantial public health concerns and environmental risks. Electrochemical reduction of nitrate (eNO

Language: Английский

Citations

16
Heterointerface-triggered electronic structure reformation: Pd/CuO nano-olives motivate nitrite electroreduction to ammonia DOI

Songliang Liu,

Lin Cui,

Shuli Yin

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2022, Volume and Issue: 319, P. 121876 - 121876

Published: Aug. 22, 2022

Language: Английский

Citations

69
Enhancement of Nitrate‐to‐Ammonia on Amorphous CeOx‐Modified Cu via Tuning of Active Hydrogen Supply DOI
Yufeng Li, Chaochen Wang,

Lekuan Yang

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 14(7)

Published: Dec. 22, 2023

Abstract The electrochemical nitrate reduction reaction (NO 3 RR) is an environment‐friendly and promising alternative to the conventional Haber–Bosch ammonia synthesis process, which a complex process of proton‐coupled electron transfer. Hereon, amorphous CeO x support introduced construct Cu/a‐CeO heterostructure prepared provide sufficient *H synergistically catalyze NO RR. achieves maximum yield 1.52 mmol h −1 mg cat . In flow cell, NH reaches 17.93 at 1 A cm −2 , exceeds most state‐of‐the‐art catalysts. situ X‐ray diffraction (XRD) in Raman observe that catalyst undergoes structural reconfiguration under operating conditions, thus confirming Cu 2 O not true active center catalytic process. Furthermore, characterizations density functional theory (DFT) calculations demonstrate modulates electronic structure overcomes higher potential barrier required for decomposition water on Cu, greatly facilitates hydrolysis provides H‐coverage rate hydrogenation − realizing dynamic equilibrium between production consumption hydrogen. This component design strategy centered opens up new pathway

Language: Английский

Citations

41
N, O trans-coordinating silver single-atom catalyst for robust and efficient ammonia electrosynthesis from nitrate DOI
Zhen Shen,

Yingsong Yu,

Zhiwei Zhao

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 331, P. 122687 - 122687

Published: March 24, 2023

Language: Английский

Citations

38