Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125193 - 125193
Published: Feb. 1, 2025
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125193 - 125193
Published: Feb. 1, 2025
Language: Английский
Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 62(5)
Published: Dec. 5, 2022
We propose the pseudobrookite Fe2 TiO5 nanofiber with abundant oxygen vacancies as a new electrocatalyst to ambiently reduce nitrate ammonia. Such catalyst achieves large NH3 yield of 0.73 mmol h-1 mg-1cat. and high Faradaic Efficiency (FE) 87.6 % in phosphate buffer saline solution 0.1 M NaNO3 , which is lifted 1.36 96.06 at -0.9 V vs. RHE for nitrite conversion ammonia NaNO2 . It also shows excellent electrochemical durability structural stability. Theoretical calculation reveals enhanced conductivity this an extremely low free energy -0.28 eV adsorption presence vacant oxygen.
Language: Английский
Citations
116Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 452, P. 139327 - 139327
Published: Sept. 21, 2022
Language: Английский
Citations
74Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 467, P. 143385 - 143385
Published: May 9, 2023
Language: Английский
Citations
71Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 325, P. 124636 - 124636
Published: July 20, 2023
Language: Английский
Citations
64Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 14(1)
Published: Nov. 13, 2023
Abstract The development of industry and agriculture has been accompanied by an artificially imbalanced nitrogen cycle, which threatens human health ecological environments. Electrocatalytic systems have emerged as a sustainable way converting nitrogen‐containing molecules into high value‐added chemicals. However, the construction high‐performance electrocatalysts remains challenging. oxygen vacancy engineering strategy promoted more research efforts to explore structure‐activity relationship between catalytic activity vacancies. This review systematically summarizes recent vacancies‐rich metal oxides for electro‐catalyzing cycling systems, involving electrocatalytic nitrate reduction reaction, nitric oxide C─N coupling, urea oxidation reaction. First, methods characterization vacancies are summarized. Then, effect on is discussed in terms regulating electronic structures electrocatalysts, improving electroconductivity catalysts, lowing energy barrier, strengthening adsorption activation intermediate species. Finally, future directions cycle anticipated.
Language: Английский
Citations
61Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 351, P. 124007 - 124007
Published: April 24, 2024
Language: Английский
Citations
60Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 338, P. 123041 - 123041
Published: June 24, 2023
Language: Английский
Citations
52Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 324, P. 124628 - 124628
Published: July 20, 2023
Language: Английский
Citations
50Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 343, P. 123464 - 123464
Published: Nov. 4, 2023
Language: Английский
Citations
43Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148789 - 148789
Published: Jan. 18, 2024
Language: Английский
Citations
35