Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 29 - 37
Published: Jan. 15, 2025
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 29 - 37
Published: Jan. 15, 2025
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 338, P. 123061 - 123061
Published: June 30, 2023
Language: Английский
Citations
34Molecules, Journal Year: 2023, Volume and Issue: 28(8), P. 3622 - 3622
Published: April 21, 2023
Metal–organic framework (MOF) materials possess a large specific surface area, high porosity, and atomically dispersed metal active sites, which confer excellent catalytic performance as peroxide (peroxodisulfate (PDS), peroxomonosulfate (PMS), hydrogen (H2O2)) activation catalysts. However, the limited electron transfer characteristics chemical stability of traditional monometallic MOFs restrict their large-scale application in advanced oxidation reactions. Furthermore, single-metal site uniform charge density distribution result fixed reaction path Fenton-like process. To address these limitations, bimetallic have been developed to improve activity, stability, controllability Compared with MOFs, enhance material, promote internal transfer, even alter through synergistic effect bimetals. In this review, we systematically summarize preparation methods mechanism activating different systems. Moreover, discuss factors that affect process activation. This report aims expand understanding MOF synthesis mechanisms processes.
Language: Английский
Citations
31Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 476, P. 146769 - 146769
Published: Oct. 20, 2023
Language: Английский
Citations
30Inorganic Chemistry, Journal Year: 2023, Volume and Issue: 62(34), P. 13722 - 13730
Published: Aug. 4, 2023
Carbon dioxide cycloaddition into fine chemicals is prospective technology to solve energy crisis and environmental issues. However, high temperature pressure are usually required in the conventional reactions of CO2 with epoxides. Moreover, metal active sites play a vital role cycloaddition, but it still unclear. Herein, we select isostructural MOF-919-Cu-Fe MOF-919-Cu-Al as models promote performance clarify effects type on cycloaddition. The exposed Fe Cu Lewis acid reaches over 99.9% conversion selectivity at room 1 bar atmosphere, 3.0- 52.6-fold higher than those Al (33.8%) 1H-pyrazole-4-carboxylic acid, Fe, mixed system (1.9%), respectively. proposed mechanism demonstrated that Fe3+ facilitate ring opening epoxide activation boost reaction. This work provides new insight tune catalytic MOFs achieve for fixation.
Language: Английский
Citations
28Journal of Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 649, P. 10 - 21
Published: June 15, 2023
Language: Английский
Citations
27Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 470, P. 144250 - 144250
Published: June 19, 2023
Language: Английский
Citations
25Nano Research, Journal Year: 2023, Volume and Issue: 16(12), P. 12919 - 12935
Published: Aug. 8, 2023
Language: Английский
Citations
25Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 469, P. 143922 - 143922
Published: June 3, 2023
Language: Английский
Citations
23Environmental Research, Journal Year: 2024, Volume and Issue: 257, P. 119293 - 119293
Published: June 4, 2024
Language: Английский
Citations
14Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 349, P. 127841 - 127841
Published: May 6, 2024
Language: Английский
Citations
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