Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2023, Volume and Issue: 340, P. 123223 - 123223
Published: Sept. 1, 2023
Language: Английский
Citations
44Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)
Published: Aug. 15, 2024
A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation and transfer hydrogenation. C-alkylation nitriles, ketones, N-heterocycles, amides, keto acids, esters, N-alkylation amines amides all go smoothly developed method. Taking α-alkylation nitriles alcohols as an example, starts (1) nitrogen-doped carbon support catalyzed dehydrogenation into aldehydes, which further condensed to give vinyl followed by (2) hydrogenation C=C bonds in on sites. The experimental results DFT calculations reveal that Lewis acidic Zn-N4 sites promote step activating alcohols. This first example highly catalysts various organic transformations biomass-derived alkylating reagents hydrogen donors. Using carbonyl compounds or synthesis α-alkylated appealing a sustainability perspective. Here, acting acid effectively activates thus promoting reactions using both
Language: Английский
Citations
12Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 151199 - 151199
Published: April 10, 2024
Language: Английский
Citations
6Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 351, P. 123958 - 123958
Published: April 24, 2024
Language: Английский
Citations
6Sustainable Energy & Fuels, Journal Year: 2023, Volume and Issue: 7(8), P. 1855 - 1869
Published: Jan. 1, 2023
Formic acid-mediated levulinic acid valorization was conducted using a CoPd nanoalloy embedded N-doped carbon catalyst for the production of γ-valerolactone and pyrrolidones.
Language: Английский
Citations
13Green Chemistry, Journal Year: 2023, Volume and Issue: 25(17), P. 6869 - 6880
Published: Jan. 1, 2023
The H 2 -free reductive cleavage of inert aryl ethers has been achieved at room temperature via photocatalytic transfer hydrogenolysis combined with acid catalysis.
Language: Английский
Citations
13Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 29, 2025
Abstract The hydroaminomethylation of alkenes using CO and H 2 proceeds efficiently in the presence a heterogeneous Co−N/C catalyst with highly dispersed metal centers. Various secondary tertiary amines can be effectively synthesized from cyclic linear aliphatic this specific material. active sites optimal result synergistic effect atomically Co their surrounding N atoms, high surface area as well structural defects NC support. broad applicability (>54 examples), including pharmaceutically relevant molecules, together activity reusability, underline general catalytic system.
Language: Английский
Citations
0Angewandte Chemie, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 29, 2025
Abstract The hydroaminomethylation of alkenes using CO and H 2 proceeds efficiently in the presence a heterogeneous Co−N/C catalyst with highly dispersed metal centers. Various secondary tertiary amines can be effectively synthesized from cyclic linear aliphatic this specific material. active sites optimal result synergistic effect atomically Co their surrounding N atoms, high surface area as well structural defects NC support. broad applicability (>54 examples), including pharmaceutically relevant molecules, together activity reusability, underline general catalytic system.
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 686, P. 990 - 999
Published: Feb. 7, 2025
Language: Английский
Citations
0Sustainable materials and technologies, Journal Year: 2025, Volume and Issue: unknown, P. e01304 - e01304
Published: Feb. 1, 2025
Language: Английский
Citations
0