Tuning Dynamic Structural Evolution of Bi24O31Cl10 for Enhancing Piezo-Photocatalytic Nitrogen Oxidation to Nitrate DOI
Yi Wang,

Haiyan Peng,

Meiyang Song

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(26), P. 8038 - 8045

Published: June 17, 2024

Direct nitrogen oxidation into nitrate under ambient conditions presents a promising strategy for harsh and multistep industrial processes. However, the dynamic structural evolution of active sites in surface reactions constitutes highly intricate endeavor remains its nascent stage. Here, we constructed Bi

Language: Английский

Precise regulation of built-in electric field over NH2-MIL-125-Ti/WO3-x S-scheme heterojunction for achieving simultaneous formation of CO and H2O2 from CO2 and H2O DOI
Haopeng Jiang, Lele Wang, Xiaohui Yu

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 466, P. 143129 - 143129

Published: April 24, 2023

Language: Английский

Citations

114
Stacking Engineering of Heterojunctions in Half‐Metallic Carbon Nitride for Efficient CO2 Photoreduction DOI Creative Commons
Xingwang Zhu,

Hangmin Xu,

Jinyuan Liu

et al.

Advanced Science, Journal Year: 2023, Volume and Issue: 10(36)

Published: Dec. 1, 2023

Enhancing charge separation in semiconductor photocatalysts is a major challenge for efficient artificial photosynthesis. Herein, compact heterojunction designed by embedding half-metallic C(CN)3 (hm-CN) hydrothermally BiOBr (BOB) as the backbone. The interface between hm-CN and BOB seamless formed covalent bonding to facilitate transmission of photoinduced electrons from hm-CN. transient photocurrents electrochemical impedance spectra reveal that modified composite catalyst exhibits larger electron transfer rate. photocatalytic activity hm-CN/BOB increases significantly indicated CO yield about four times higher than individual components. Density-functional theory calculations verify improves transport decreases reaction energy barrier, thus promoting overall CO2 conversion efficiency. half-metal nitride coupled heterojunctions might have large potential photosynthesis related applications.

Language: Английский

Citations

57
Construction of Z-Scheme MnO<sub>2</sub>/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO<sub>2</sub> Reduction DOI Open Access
Jintao Dong,

Sainan Ji,

Yi Zhang

et al.

Acta Physico-Chimica Sinica, Journal Year: 2023, Volume and Issue: 0(0), P. 2212011 - 2212011

Published: Jan. 1, 2023

Abstract: Rapid increase in energy shortage and ecological environmental pollution has become a major issue that been continuously drawing global attention, because it severely affects human health limits sustainable social development. Various technologies have developed used to rationalize the utilization of new sources control. Among these technologies, photocatalysis research priority field governance Advantages such as low consumption, no secondary pollution, simple operation methods, mild reaction conditions make an attractive choice. Notably, although is promising approach for enhancing antibiotic removal CO2 reduction efficiency, industrialization large-scale application photocatalysts limited issues photo-absorption redox capacity, photogenerated electron separation or migration efficiency. The progress current on regulation composition/structure performance promoted exploration efficient practical modification strategies construct photocatalyst composites with improved by facilitating light absorption/utilization photocatalytic surface/interface performance. many common strategies, construction Z-scheme heterojunction can enhance absorption ability significantly reduce recombination rate electron-hole pairs. Additionally, this strategy maintains strong reduction/oxidation electrons/holes facilitate oxidation pollutants conversion clean energy. In study, MnO2/BiOBr (MO/BiOBr) were effectively constructed using mechanically assisted ball-milling process. situ X-ray photoelectron spectroscopy under dark confirmed photoexcited electrons MnO2 migrate directionally BiOBr through Mn3+/Mn4+ couple create transfer path. A similar conclusion also be deduced from results spin-resonance band structure analysis. formation between BiOBr, attributed staggered band, enabled space centers. Furthermore, compared MO/BiOBr exhibited enhanced markedly reduced photoinduced pair rate, ultraviolet-visible diffuse reflectance photoluminescence spectroscopy. Thus, exceptional toward ciprofloxacin (CIP) CO evolution. CIP efficiency reached 77.3% just 60 min, which 1.28 times higher than (60.2%). Simultaneously, CO2-to-CO (20.02 µmol·g-1·h-1) was found 2.20-fold (9.08 µmol·g-1·h-1). Photocurrent measurement electrochemical impedance indicated interfacial pure BiOBr. liquid chromatograph mass spectrometry Fourier transform infrared conducted study generation intermediates during toxicity corresponding after degradation evaluated estimation software (T.E.S.T.) analyze actual physiological toxicity, based indexes Daphnia Magna lethal concentration 50% (LC50, 48 h), Fathead Minnow dose (LD50, 96 mutagenicity, bioaccumulation factor. proposed novel simplified constructing solar-derived fuel synthesis.

Language: Английский

Citations

52
Semimetallic Bismuthene with Edge‐Rich Dangling Bonds: Broad‐Spectrum‐Driven and Edge‐Confined Electron Enhancement Boosting CO2 Hydrogenation Reduction DOI Creative Commons
Bin Wang, Hailong Chen,

Wei Zhang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(19)

Published: Jan. 31, 2024

Broad-spectrum-driven high-performance artificial photosynthesis is quite challenging. Herein, atomically ultrathin bismuthene with semimetallic properties designed and demonstrated for broad-spectrum (ultraviolet-visible-near infrared light) (UV-vis-NIR)-driven photocatalytic CO

Language: Английский

Citations

32
Modulating charge oriented accumulation via interfacial chemical-bond on In2O3/Bi2MoO6 heterostructures for photocatalytic nitrogen fixation DOI
Xin Huang, Rui Du, Yuanyuan Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 664, P. 33 - 44

Published: March 4, 2024

Language: Английский

Citations

29
Multidimensional carbon-based polymer/Bi2O2CO3 S-scheme heterojunction boosting carrier separation in efficient photocatalytic seawater purification DOI
Shihao Jia, Huimin Han, Bin Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 353, P. 124050 - 124050

Published: April 24, 2024

Language: Английский

Citations

21
Endowing polymeric carbon nitride photocatalyst with CO2 activation sites by anchoring atomic cobalt cluster DOI

Yaru Shang,

Yijie Hou,

Xun Cao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 486, P. 150306 - 150306

Published: March 11, 2024

Language: Английский

Citations

19
Mofs-based S-scheme heterojunction photocatalysts: Challenges and prospects to break the selectivity limitation for intensified C1 products in CO2 photoreduction DOI

Monika Malhotra,

Vatika Soni,

Rohit Kumar

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160238 - 160238

Published: Feb. 1, 2025

Language: Английский

Citations

3
Mn/S co-doped BiOCl regulated with a hydrophobic-to-superhydrophilic transition and oxygen-vacancy defects for assisting photocatalytic hydrogen evolution DOI

Zhengjie Su,

Binghong Wu,

C. Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161621 - 161621

Published: March 1, 2025

Language: Английский

Citations

3
Piezo-photocatalysis for efficient charge separation to promote CO2 photoreduction in nanoclusters DOI Creative Commons
Xingwang Zhu,

Hangmin Xu,

Chuanzhou Bi

et al.

Ultrasonics Sonochemistry, Journal Year: 2023, Volume and Issue: 101, P. 106653 - 106653

Published: Oct. 20, 2023

The substantial emissions of CO

Language: Английский

Citations

35