Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 467, P. 143464 - 143464
Published: May 12, 2023
Language: Английский
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 467, P. 143464 - 143464
Published: May 12, 2023
Language: Английский
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 313 - 322
Published: March 19, 2024
Language: Английский
Citations
19Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown
Published: June 4, 2024
Abstract The heteroatom substitution is considered as a promising strategy for boosting the redox kinetics of transition metal compounds in hybrid supercapacitors (HSCs) although dissimilar identification and essential mechanism that dominate remain unclear. It presented d‐p orbital hybridization between electrolyte ions can be utilized descriptor understanding kinetics. Herein, series Co, Fe Cu heteroatoms are respectively introduced into Ni 3 Se 4 cathodes, among them, only moderate Co‐substituted hold optimal resulted from formed more unoccupied antibonding states π*. inevitably enhances interfacial charge transfer ensures balanced OH − adsorption‐desorption to accelerate validated by lowest reaction barrier (0.59 eV, matching well with theoretical calculations). Coupling lower diffusion energy barrier, prepared cathode delivers ultrahigh rate capability (~68.7 % capacity retention even current density increases 200 times), an assembled HSC also presents high energy/power density. This work establishes principles determining deciphers underlying effects on improving performance battery‐type electrodes novel perspective orbital‐scale manipulation.
Language: Английский
Citations
19Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 187, P. 123 - 140
Published: Jan. 4, 2024
Language: Английский
Citations
17Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216190 - 216190
Published: Sept. 5, 2024
Language: Английский
Citations
17Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 467, P. 143464 - 143464
Published: May 12, 2023
Language: Английский
Citations
40