In situ Doping Coupling With Vacancy Regulation Induced Strong Metal‐Support Interaction in Ni/CaTiO3 to Boost Supercharged Photothermal CO2 Methanation DOI Open Access

Zhimin Yuan,

Baokun Zhang, Xianglin Zhu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Abstract The “Solar Sabatier” reaction has emerged as a promising sustainable method for the CO 2 hydrogenation. development of advanced metal‐support catalysts based on Strong Metal‐Support Interaction (SMSI) offers significant advantages in activation and regulation selectivity. Herein, novel composite Ni/CaTiO 3 catalyst consisting Ni Ni‐doped CaTiO is synthesized utilized methanation. A noteworthy finding that incorporation into matrix instrumental formation oxygen vacancies establishment SMSI between . enhanced resulting from surface‐doped atoms not only facilitated effective interface contact metallic surface but also significantly improved migration efficiency hydrogen reduced barrier methanation optimized rate‐limiting step, all which are advantageous Consequently, exhibited extraordinary performance, achieving conversion rate 87.77%, CH 4 generation 3.12 mol g −1 h , ≈100% selectivity under ambient pressure conditions. This investigation lays groundwork design highly active understanding mechanisms underlying SMSI.

Language: Английский

Developing indium-oxide based catalysts for efficient hydrogenation of carbon dioxide to methanol: a mini-review DOI

Yuxin Wang,

Na Yang,

Wang Ze-shan

et al.

Frontiers of Chemical Science and Engineering, Journal Year: 2025, Volume and Issue: 19(3)

Published: Jan. 13, 2025

Language: Английский

Citations

0
Structure Sensitivity of an Atomic Co-Promoted In2O3 Catalyst toward CO2 Hydrogenation to Methanol DOI
Shanshan Dang,

Xiaoya Ding,

Jinying Li

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3967 - 3979

Published: Feb. 20, 2025

Language: Английский

Citations

0
Recent progress of photothermal catalysts for carbon dioxide conversion DOI Open Access

Sang Hun Choi,

Inhak Song, Wan Jae Dong

et al.

Energy Materials, Journal Year: 2025, Volume and Issue: 5(6)

Published: Feb. 28, 2025

Photothermal catalysis has emerged as a promising strategy for converting carbon dioxide (CO2) into value-added chemicals and fuels, offering dual-energy approach that combines light thermal energy to drive reactions under mild conditions. effects are usually demonstrated by using plasmonic nanoparticles, which generate hot carriers localized heating through absorption. These facilitate chemical lowering activation barriers increasing reaction rates. The synergy between carrier-induced redox thermocatalytic processes driven allows the of challenging with reduced inputs. balance these pathways can be optimized rational design photothermal catalysts. In this review, we highlight recent advancements in catalyst materials, especially emphasizing importance achieve higher efficiencies CO2 conversion such hydrogenation dry reforming methane, both vital reducing greenhouse gases producing clean fuels. Finally, current challenges, outlook, new strategies optimization will discussed realize full potential creating sustainable low-carbon future.

Language: Английский

Citations

0
Ru-In2O3/g-C3N4 photothermal coupling catalyzed boosted carbon dioxide hydrogenation to methanol DOI

Qi Zhang,

Guolin Zhang, Liangyun Yu

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162872 - 162872

Published: March 1, 2025

Language: Английский

Citations

0
In situ Doping Coupling With Vacancy Regulation Induced Strong Metal‐Support Interaction in Ni/CaTiO3 to Boost Supercharged Photothermal CO2 Methanation DOI Open Access

Zhimin Yuan,

Baokun Zhang, Xianglin Zhu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 7, 2025

Abstract The “Solar Sabatier” reaction has emerged as a promising sustainable method for the CO 2 hydrogenation. development of advanced metal‐support catalysts based on Strong Metal‐Support Interaction (SMSI) offers significant advantages in activation and regulation selectivity. Herein, novel composite Ni/CaTiO 3 catalyst consisting Ni Ni‐doped CaTiO is synthesized utilized methanation. A noteworthy finding that incorporation into matrix instrumental formation oxygen vacancies establishment SMSI between . enhanced resulting from surface‐doped atoms not only facilitated effective interface contact metallic surface but also significantly improved migration efficiency hydrogen reduced barrier methanation optimized rate‐limiting step, all which are advantageous Consequently, exhibited extraordinary performance, achieving conversion rate 87.77%, CH 4 generation 3.12 mol g −1 h , ≈100% selectivity under ambient pressure conditions. This investigation lays groundwork design highly active understanding mechanisms underlying SMSI.

Language: Английский

Citations

0