Pt0-MnSO4 active centers on modified SmMn2O5 mullite oxides for efficient propane oxidation DOI

Yaohui Dun,

Yanfei Liu,

Jie Xu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125223 - 125223

Published: March 1, 2025

Language: Английский

Mn/Co bimetallic MOF-derived hexagonal multilayered oxide catalysts with rich interface defects for propane total oxidation: Characterization, catalytic performance and DFT calculation DOI
Chuanqiang Li,

Qianqian Chai,

Xiang Liu

et al.

Applied Catalysis A General, Journal Year: 2023, Volume and Issue: 668, P. 119449 - 119449

Published: Oct. 21, 2023

Language: Английский

Citations

11
Modulating Coordination Environment of Cobalt-Based Spinel Octahedral Metal Sites to Boost Metal–Oxygen Bond Covalency for Reversible Lithium–Oxygen Batteries DOI

Yu Pan,

Anjun Hu,

Ruizhe Xu

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(47), P. 17177 - 17189

Published: Nov. 13, 2024

The intrinsic catalytic activity of conventional spinel electrocatalysts hinders their electrocatalytic outcomes in lithium–oxygen batteries (LOBs), despite appeal due to compositional variety and structural adaptability. In this work, we reveal that the activities these catalysts can be inherently enhanced by modulating metal–oxygen (M–O) bond covalency interactions through introduction Cr element into MnCo2O4 octahedral sites (MnCr0.5Co1.5O4). Cr3+ directly alters coordination structure Co sites, which increases Co3+–O distance reduces lattice symmetry, resulting M–O bond. Computational analysis supports effectiveness altering electronic active site, narrowing energy gap between 3d O 2p orbitals, evidencing enhancement covalency. addition, increased accelerates charge transfer oxygen-related reactions, thereby facilitating reversible formation decomposition discharge products LOBs. As a proof concept, MnCr0.5Co1.5O4 catalyzed LOBs exhibit large capacity 16 388.3 mAh g–1 maintain stability over 329 cycles. This work paves way for progression manipulating catalysts.

Language: Английский

Citations

4
In-situ synthesized Co3O4/Mn3O4 on monolithic nickel foam: Enhanced CO oxidation via MOF-74 derivation DOI
Zihao Hu, Xiaoying Zhou, Tiantian Zhang

et al.

Fuel, Journal Year: 2025, Volume and Issue: 388, P. 134504 - 134504

Published: Jan. 28, 2025

Language: Английский

Citations

0
The Comprehensive Review of Catalysts for Catalytic Oxidation of Volatile Organic Compounds DOI
Ji-Hyun Yi, Jiadong Liu, Bo Gao

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115691 - 115691

Published: Feb. 1, 2025

Language: Английский

Citations

0
Pt0-MnSO4 active centers on modified SmMn2O5 mullite oxides for efficient propane oxidation DOI

Yaohui Dun,

Yanfei Liu,

Jie Xu

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125223 - 125223

Published: March 1, 2025

Language: Английский

Citations

0