Magnetic Field‐Driven NiCo‐3DOMC Modified Separators for Effective Lithium Polysulfide Mitigation and Catalysis DOI Open Access
Jianli Zhang, Qinghui Ai, Yang Wang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 30, 2024

Lithium-sulfur batteries (LSBs) face challenges from the shuttle effect of lithium polysulfides (LiPSs) and slow redox kinetics. In this study, a NiCo-Doped 3D Ordered Mesoporous Carbon (NiCo-3DOMC) composite material is synthesized using gel-crystalline template sol-gel method to modify polypropylene separators in LSBs. Density Functional Theory calculations experiment results demonstrate that under magnetic field, NiCo-3DOMC enhances adsorption catalyzes conversion LiPSs, effectively mitigating boosting This improvement due material's porous structure active catalytic sites. Enhanced by magnetohydrodynamic effects NiCo spin polarization, modified LSBs deliver high initial capacity 1544.21 mAh g

Language: Английский

Bioinspired construction of histidine-doped porphyrin covalent organic framework nanozyme with enhanced peroxidase-like activity for sensitive uric acid detection DOI
Chao Zhong,

Cong Hu,

Dan Ouyang

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 477, P. 146979 - 146979

Published: Oct. 28, 2023

Language: Английский

Citations

44

Nitrogen‐Rich Carbon Dot‐Mediated n→π* Electronic Transition in Carbon Nitride for Superior Photocatalytic Hydrogen Peroxide Production DOI
Huazhang Guo, Zhou Li, Kai Huang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(38)

Published: May 7, 2024

Abstract Solar‐driven synthesis of hydrogen peroxide (H 2 O ) through photocatalysis stands out as a promising avenue for sustainable energy generation, marked by environmental friendliness and industrial feasibility. However, the inherent limitations carbon nitride (CN) in photocatalytic H production significantly impede their performance. Herein, novel 0D/2D dots‐modified CN nanosheet heterojunction (CDsMCN) is introduced, synthesized hydrothermal‐calcination tandem strategy induced CDs derived from melamine. This innovative technique enhances n→π* electronic transition CDsMCN, accelerating separation efficiency electron‐hole pairs, boosting oxygen adsorption, promoting highly selective 2e − ORR. Comparative to pristine CN, 10 MCN exhibited remarkable tenfold increase production, reaching an impressive 1.48 mmol L −1 . Furthermore, demonstrates exceptional stability, maintaining its catalytic at initial level over four consecutive cycles. The notable achievement molar selectivity ≈80% onset potential 0.6 V (vs RHE) underscores ability produce desired product selectively. Advanced situ characterization together with DFT calculations revealed that ultrathin enhanced improves optical properties, reduces bandgap, facilitates fast charge migration, increases performance, thereby serving candidate advanced applications.

Language: Английский

Citations

34

Recent Advances in Enzyme Immobilisation Strategies: An Overview of Techniques and Composite Carriers DOI Open Access
Nur Atikah Mohidem, Mardawani Mohamad, Muhammad Usman Rashid

et al.

Journal of Composites Science, Journal Year: 2023, Volume and Issue: 7(12), P. 488 - 488

Published: Nov. 26, 2023

For over a century, enzyme immobilisation has been proven to be superior strategy improve catalytic activity and reusability ensure easy separation, operation, reduced cost. Enzyme allows for an easier separation of the from reaction mixture, thus simplifying downstream processing. This technology protects degradation or inactivation by harsh conditions, making it more robust suitable used in various applications. Recent strategies methods, such as adsorption, cross-linking, entrapment encapsulation, covalent bonding, were critically reviewed. These have shown promising results improving stability, activity, A recent development nanomaterials agrowaste renewable carriers is underlined current review. Furthermore, use gained significant attention due their unique properties, high surface area, mass transfer, biocompatibility, sustainability. materials offer outcomes developing efficient sustainable immobilised enzymes. state-of-the-art better control reactions enhances reusability, leading cost-effective environmentally friendly processes. The also helps reduce waste generation promote utilisation resources, further contributing circular economy.

Language: Английский

Citations

37

Promoting CO2 and H2O activation on O-vacancy regulated In-Ti dual-sites for enhanced CH4 photo-production DOI Open Access
Cong Chen, Liang Chen, Yangguang Hu

et al.

Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 86, P. 599 - 608

Published: Aug. 2, 2023

Language: Английский

Citations

32

Reactive natural deep eutectic solvents increase selectivity and efficiency of lipase catalyzed esterification of carbohydrate polyols DOI
Alina Ramona Buzatu, Miguel A. Soler, Sara Fortuna

et al.

Catalysis Today, Journal Year: 2023, Volume and Issue: 426, P. 114373 - 114373

Published: Sept. 14, 2023

Language: Английский

Citations

24

Exploring the green technique based on photocatalysis to produce hydrogen peroxide: Progress and challenge DOI
Xiaoran Wang,

Yifan Shao,

Jialu Pan

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 490, P. 151923 - 151923

Published: May 5, 2024

Language: Английский

Citations

12

Ca and Sr co-doping induced oxygen vacancies in 3DOM La2−Sr Ce2−Ca O7− catalysts for boosting low-temperature oxidative coupling of methane DOI
Tongtong Wu, Yuechang Wei, Jing Xiong

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 91, P. 331 - 344

Published: Jan. 4, 2024

Language: Английский

Citations

10

A Wooden Carbon-Based Photocatalyst for Water Treatment DOI Open Access

Chang Zhang,

Shangjie Ge‐Zhang, Yudong Wang

et al.

International Journal of Molecular Sciences, Journal Year: 2024, Volume and Issue: 25(9), P. 4743 - 4743

Published: April 26, 2024

Due to a large number of harmful chemicals flowing into the water source in production and life, quality deteriorates, use value is reduced or lost. Biochar has strong physical adsorption effect, but it can only separate pollutants from cannot eliminate fundamentally. Photocatalytic degradation technology using photocatalysts uses chemical methods degrade mineralize organic pollutants, difficult recover reuse. Woody biomass advantages huge reserves, convenient access low price. Processing woody biochar then combining with played complementary role. In this paper, shortcomings photocatalyst treatment are introduced, respectively, biochar-based made by them summarized. The preparation assembly starting listed, efficiency different listed. Finally, future development summarized prospected.

Language: Английский

Citations

8

Engineering high-activity crosslinked enzyme aggregates via SpyCatcher/SpyTag-mediated self-assembly DOI

Xueliang Ma,

Yu Yang,

Manzhu Wang

et al.

International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 295, P. 139591 - 139591

Published: Jan. 7, 2025

Language: Английский

Citations

1

Enhanced electroenzymatic CO2 reduction by a multifunctional ZIF-8 layer on silica nanoflower with immobilized enzyme DOI

Yaoxuan Li,

Lihang Yan,

Guanhua Liu

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 466, P. 143198 - 143198

Published: April 26, 2023

Language: Английский

Citations

21