Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177883 - 177883
Published: Nov. 1, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177883 - 177883
Published: Nov. 1, 2024
Language: Английский
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(17)
Published: March 1, 2024
Abstract Traditional H 2 O cleavage mediated by macroscopic electron transfer (MET) not only has low utilization of , but also sacrifices the stability catalysts. We present a non‐redox hydroxyl‐enriched spinel (CuFe 4 ) catalyst with dual Lewis acid sites to realize homolytic . The results systematic experiments, in situ characterizations, and theoretical calculations confirm that tetrahedral Cu optimal acidity strong delocalization can synergistically elongate O−O bonds (1.47 Å → 1.87 Å) collaboration adjacent bridging hydroxyl (another site). As result, free energy is decreased (1.28 eV 0.98 eV). be efficiently split into ⋅OH induced CuFe without MET, which greatly improves (65.2 %, nearly times than traditional catalysts). system assembled affords exceptional performance for organic pollutant elimination. scale‐up experiment using continuous flow reactor realizes long‐term (up 600 mL), confirming tremendous potential practical applications.
Language: Английский
Citations
36Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: 366, P. 125043 - 125043
Published: Jan. 8, 2025
Language: Английский
Citations
3Rare Metals, Journal Year: 2024, Volume and Issue: 43(9), P. 4344 - 4355
Published: May 29, 2024
Language: Английский
Citations
12Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(17)
Published: March 1, 2024
Abstract Traditional H 2 O cleavage mediated by macroscopic electron transfer (MET) not only has low utilization of , but also sacrifices the stability catalysts. We present a non‐redox hydroxyl‐enriched spinel (CuFe 4 ) catalyst with dual Lewis acid sites to realize homolytic . The results systematic experiments, in situ characterizations, and theoretical calculations confirm that tetrahedral Cu optimal acidity strong delocalization can synergistically elongate O−O bonds (1.47 Å → 1.87 Å) collaboration adjacent bridging hydroxyl (another site). As result, free energy is decreased (1.28 eV 0.98 eV). be efficiently split into ⋅OH induced CuFe without MET, which greatly improves (65.2 %, nearly times than traditional catalysts). system assembled affords exceptional performance for organic pollutant elimination. scale‐up experiment using continuous flow reactor realizes long‐term (up 600 mL), confirming tremendous potential practical applications.
Language: Английский
Citations
6Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 353, P. 128368 - 128368
Published: June 9, 2024
Language: Английский
Citations
6Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 686, P. 970 - 977
Published: Feb. 3, 2025
Language: Английский
Citations
0Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125162 - 125162
Published: Feb. 1, 2025
Language: Английский
Citations
0Applied Surface Science, Journal Year: 2025, Volume and Issue: 695, P. 162891 - 162891
Published: March 5, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132958 - 132958
Published: April 1, 2025
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(4), P. 113252 - 113252
Published: June 4, 2024
Language: Английский
Citations
3