Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 23, 2025
Abstract
Constructing
heterojunctions
between
phase
interfaces
represents
a
crucial
strategy
for
achieving
excellent
photocatalytic
performance,
but
the
absence
of
sufficient
interface
driving
force
and
limited
charge
transfer
pathway
leads
to
unsatisfactory
separation
processes.
Herein,
doping‐engineering
is
introduced
construct
In─N
bond‐bridged
In
2
S
3
nanocluster
modified
doped
carbon
nitride
(CN)
nanosheets
Z‐Scheme
van
der
Waals
(VDW)
(In
/CNS)
photocatalyst,
preparation
process
just
by
one‐step
pyrolysis
using
pre‐coordination
confinement
method.
Specifically,
atoms
doping
enhances
bond
strength
forms
high‐quality
interfacial
linkage
which
serves
as
atomic‐level
“highway”
improving
electrons
migration,
decreasing
recombination
probability.
The
detailed
characterization
results,
along
with
theoretical
calculations,
confirm
that
both
atom
incorporation
formation
VDW
synergistically
improve
internal
electric
field.
This,
in
turn,
accelerates
simultaneously
light
absorption
capacity.
Consequently,
optimal
hydrogen
evolution
performance
In₂S₃/CNS2
160.8
times
greater
than
In₂S₃,
8.2
higher
CNS.
This
study
emphasizes
role
atomic‐scale
regulation
intrinsic
fields
heterojunctions,
contributing
ameliorative
performance.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(15)
Published: Feb. 14, 2024
The
development
of
photocatalysts
with
continuous
electron
extraction
and
rapid
proton
transfer
could
kinetically
accelerate
the
artificial
photosynthesis,
but
remains
a
challenge.
Herein,
we
report
topology-guided
synthesis
high-crystalline
triazine
covalent
organic
framework
(COF)
decorated
by
uniformly
distributed
polar
oxygen
functional
groups
(sulfonic
group
or
carboxyl)
as
strong
electron/proton
extractor
for
efficient
photocatalytic
H
Advanced Energy Materials,
Journal Year:
2024,
Volume and Issue:
14(39)
Published: July 22, 2024
Abstract
Graphitic
carbon
nitride
(g‐C
3
N
4
)
assisted
photocatalytic
production
of
hydrogen
peroxide
(H
2
O
has
already
attracted
the
interest
many
researchers
due
to
its
environmental
sustainability.
Nevertheless,
inherent
drawbacks
g‐C
limit
progress.
Metal‐free
modification
strategies,
including
nanostructure
design,
defect
introduction,
doping,
and
heterojunction
construction,
have
been
developed
improve
efficiency
H
production.
Compared
metal
modification,
metal‐free
strategies
avoid
use
precious
metals
leaching
heavy
ions,
which
advantages
good
stability
friendliness.
However,
a
comprehensive
review
from
modified
by
is
still
lacking.
This
first
recaps
mechanism
,
photoexcitation,
carrier
separation
redox
reactions.
Then,
perspective
advances
in
photocatalysts
are
presented,
with
special
focus
on
kernel
connection
between
different
based
pivotal
stages
Subsequently,
recent
applications
‐based
for
situ
generated
mainly
water
purification
organic
synthesis,
briefly
discussed.
Finally,
prospects
envisioned
hope
that
it
will
“something
do”
field
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 20, 2024
Crafting
semiconducting
heterojunctions
represents
an
effective
route
to
enhance
photocatalysis
by
improving
interfacial
charge
separation
and
transport.
However,
lattice
mismatch
(δ)
between
different
semiconductors
can
significantly
hinder
dynamics.
Here,
meticulous
tailoring
is
reported
create
a
covalent
heterointerface
with
built-in
electric
field
(BIEF),
imparting
markedly
improved
hydrogen
peroxide
(H
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 23, 2025
Abstract
In
the
face
of
escalating
antibiotic
resistance
crisis,
world
is
embroiled
in
a
silent
“antibacterial
war”.
Scientists
are
actively
searching
for
innovative
antibacterial
materials
that
can
be
used
as
effective
weapons
against
bacterial
infections.
As
promising
new
crystalline
porous
polymer
materials,
covalent
organic
frameworks
(COFs)
gradually
revealing
their
vast
potential
applications.
This
study
investigates
classification
COF‐based
agents,
provides
comprehensive
overview
applications
and
research
advancements,
explores
strategies
employed
by
COF
materials.
Furthermore,
challenges
outlined
lie
ahead
future
application
agents
insights
into
prospects
within
field
offered.
Through
these
efforts,
aim
to
accelerate
advancements
COFs
manufacturing
technology,
promote
innovation
applications,
contribute
public
health.
