Metal single-atom catalysts derived from silicon-based materials for advanced oxidation applications DOI
Hanghang Zhao, Wenbo Qi, Xin Tan

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110898 - 110898

Published: Jan. 1, 2025

Language: Английский

Were Persulfate-Based Advanced Oxidation Processes Really Understood? Basic Concepts, Cognitive Biases, and Experimental Details DOI
Xiaonan Hu, Mingshan Zhu

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(24), P. 10415 - 10444

Published: June 7, 2024

Persulfate (PS)-based advanced oxidation processes (AOPs) for pollutant removal have attracted extensive interest, but some controversies about the identification of reactive species were usually observed. This critical review aims to comprehensively introduce basic concepts and rectify cognitive biases appeals pay more attention experimental details in PS-AOPs, so as accurately explore reaction mechanisms. The scientifically summarizes character, generation, different species. It then highlights complexities analysis electron paramagnetic resonance, uncertainties use probes scavengers, necessities determination scavenger concentration. importance choice buffer solution, operating mode, terminator, filter membrane is also emphasized. Finally, we discuss current challenges future perspectives alleviate misinterpretations toward mechanisms PS-AOPs.

Language: Английский

Citations

79
ZIF-8/balsa wood derived N-doped porous carbon as self-supporting electro-Fenton cathode for efficient antibiotics degradation DOI

Li Zhao,

Ruiying Zhu,

Hong Ma

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 347, P. 127596 - 127596

Published: April 21, 2024

Language: Английский

Citations

16
Single-atom Co-N3 sites induce peroxymonosulfate activation for acetaminophen degradation via nearly 100% internal electron transfer process DOI
Hong Meng, Junhui Zhou, Yongqing Zhang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125038 - 125038

Published: Jan. 1, 2025

Language: Английский

Citations

6
High‐Throughput Screening and General Synthesis Strategy of Single‐Atom Nanozymes for Oral Squamous Cell Carcinoma Therapy DOI Open Access

Ji Shen,

Guan-Meng Zhang,

Zedong Zhang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 5, 2025

Abstract Single‐atom nanozymes (SAzymes), with their superior enzyme‐like catalytic activity, have emerged as promising candidates for oncology therapeutics. The well‐defined structures of SAzymes make them well predictable by experiences and theoretical calculation. However, the effects metal center species coordination environments on activity are variable, screening artificial experiments is challenging. High‐throughput can rapidly select optimal thus better application in tumor therapy highly desirable. Herein, a “high‐throughput screening‐SAzymes structures” system established efficient drug preparation density functional theory oxidase‐like processes screened differences brought about different metals environments. Through this process, transition (Mn, Fe, Co, Ni) active centers synthesized then tested multi‐enzyme activities. It found that SAzyme Co exhibited best further showed good anti‐oral squamous cell carcinoma properties both vitro vivo. This study opens up new avenue rational design oral cancer combining computational experimental validation.

Language: Английский

Citations

2
Activating peroxymonosulfate by high nitrogen-doped biochar from lotus pollen for efficient degradation of organic pollutants from water: Performance, kinetics and mechanism investigation DOI
Ziling Zhu,

Xiaoben Yang,

Xing Ye

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 346, P. 127456 - 127456

Published: April 14, 2024

Language: Английский

Citations

13
Stabilizing atomic Co on 2D ordered mesoporous carbon sandwiched MXene for peroxymonosulfate activation: Enhanced performance and electron-transfer mechanism DOI
Xin Guo, Hao Zhang,

Yiyuan Yao

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 358, P. 124432 - 124432

Published: July 23, 2024

Language: Английский

Citations

13
Dual-functional electrocatalyst of defective cobalt-nitrogen-doped porous carbon for enhanced in-situ hydrogen peroxide generation and electro-Fenton tetracycline degradation DOI
Xuan Luo,

Ruiying Zhu,

Li Zhao

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 346, P. 127451 - 127451

Published: April 10, 2024

Language: Английский

Citations

10
Pore modulation of single atomic Fe sites for ultrafast Fenton-like chemistry with amplified electron migration oxidation DOI

Kexin Yin,

Xing Xu, Qinyan Yue

et al.

Water Research, Journal Year: 2024, Volume and Issue: 268, P. 122545 - 122545

Published: Sept. 30, 2024

Language: Английский

Citations

10
Boosting catalytic activity of Fe-based perovskite by compositing with Co oxyhydroxide for peroxymonosulfate activation and ofloxacin degradation DOI
Yin Wang,

Wannan Xia,

Guanhao Jiao

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 705, P. 135706 - 135706

Published: Nov. 6, 2024

Language: Английский

Citations

10
Insight into the performance and mechanism of N,O,S-codoped porous carbon based CO single-atom catalysts in organic oxidation through peroxymonosulfate activation DOI

Xijun Fu,

Qingming Zeng,

Song Lu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154668 - 154668

Published: Aug. 8, 2024

Language: Английский

Citations

9