Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216652 - 216652
Published: April 3, 2025
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216652 - 216652
Published: April 3, 2025
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 353, P. 124098 - 124098
Published: April 19, 2024
Language: Английский
Citations
62Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 19, 2025
Abstract Efficient charge separation at the semiconductor/cocatalyst interface is crucial for high‐performance photoelectrodes, as it directly influences availability of surface charges solar water oxidation. However, establishing strong molecular‐level connections between these interfaces to achieve superior interfacial quality presents significant challenges. This study introduces an innovative electrochemical etching method that generates a high concentration oxygen vacancy sites on BiVO 4 surfaces (Ov‐BiVO ), enabling interactions with oxygen‐rich ligands MIL‐101. reduces formation energy and promotes conformal growth . The Ov‐BiVO /MIL‐101 composite exhibits ideal interface, achieving impressive photocurrent density 5.91 mA cm −2 1.23 V RHE , along excellent stability. high‐performing photoanode enables unbiased tandem device /MIL‐101‐Si cell system, solar‐to‐hydrogen efficiency 4.33%. integration mitigates states enhances internal electric field, facilitating migration photogenerated holes into MIL‐101 overlayer. process activates highly efficient Fe catalytic sites, which effectively adsorb molecules, lowering barrier oxidation improving kinetics. Further studies confirm broad applicability vacancy‐induced molecular epitaxial in various MOFs, offering valuable insights defect engineering optimizing enhancing photocatalytic activity.
Language: Английский
Citations
4Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125098 - 125098
Published: Jan. 1, 2025
Language: Английский
Citations
3Inorganic Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The well-designed catalyst structure can significantly enhance the efficiency of photocatalytic H 2 , O and degradation TC. This study offers novel insights into constructing a visible photothermal assisted reaction system.
Language: Английский
Citations
2Applied Surface Science, Journal Year: 2024, Volume and Issue: 663, P. 160206 - 160206
Published: May 3, 2024
Language: Английский
Citations
12Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 156725 - 156725
Published: Oct. 1, 2024
Language: Английский
Citations
11Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124747 - 124747
Published: Oct. 1, 2024
Language: Английский
Citations
10Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 358, P. 124430 - 124430
Published: July 21, 2024
Language: Английский
Citations
9Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 356, P. 130010 - 130010
Published: Oct. 6, 2024
Language: Английский
Citations
9Molecules, Journal Year: 2024, Volume and Issue: 29(10), P. 2294 - 2294
Published: May 13, 2024
With the rising incidence of various diseases in China and constant development pharmaceutical industry, there is a growing demand for floxacin-type antibiotics. Due to large-scale production high cost waste treatment, parent drug its metabolites constantly enter water environment through domestic sewage, wastewater, other pathways. In recent years, pollution aquatic by floxacin has become increasingly serious, making technology degrade research hotspot field environmental science. Metal-organic frameworks (MOFs), as new type porous material, have attracted much attention years. this paper, four photocatalytic materials, MIL-53(Fe), NH
Language: Английский
Citations
5