RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(44), P. 32328 - 32338
Published: Jan. 1, 2024
The
EDTA-2Na
additive
can
be
efficiently
adsorbed
onto
the
Al
electrode
surface
to
provide
a
shielding
layer.
This
decreased
occurrence
of
hydrogen
evolution
side
reactions
and
improved
battery
performance.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 4, 2025
Abstract
Photocatalytic
reduction
of
CO
2
to
high‐value‐added
chemicals
represents
a
promising
strategy
for
effective
utilization,
and
rationally
regulating
the
electronic
structure
catalyst
is
key
enhancing
photocatalytic
performance.
Herein,
it
demonstrated
that
in
situ
doping
atomic
indium
into
lattice
Cu
MoS
4
results
remarkable
enhancements
A
record
gas
product
yield
104.1
µmol·g
−1
·h
achieved
under
visible
light
irradiation
(>420
nm),
accompanied
by
generation
rate
35.3
ethylene.
Detailed
experimental
analyses
density
functional
theory
(DFT)
calculations
reveal
low
electronegativity
atoms
induces
asymmetric
charge
redistribution
near
sites.
This
effect
facilitates
adsorption
dissociation
molecules
at
charge‐enriched
Mo
sites,
as
well
subsequent
intermediates
(
*
COCOH)
toward
ethylene
formation.
work
advances
understanding
potential
mechanism
between
active
site
performance,
providing
valuable
insights
fabricating
advanced
materials
conversion
solar
fuels.